Interaction of copper with fatty acids in Soxhlet extraction and its influence

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.     

GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea

The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward electric field, and are not associated with the increase of the O/N₂ ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically coupled upward to generate ionospheric perturbations and oscillations.     

GIS支持的城市固体废弃物规划管理信息系统构建

研究了基于组件式GIS平台MapX的城市固体废弃物规划管理信息系统的设计与实现;讨论了系统框架与系统功能设计、数据库设计和系统实现的关键技术。以昆明市为例,构建了基于MapX的城市固体废弃物规划管理信息系统。该系统能够实现城市固体废弃物各类数据的采集、表达和输出,提供与城市固体废弃物管理模型无缝集成的接口,可利用地图、文字、表格等多种手段为城市固体废弃物规划管理提供辅助决策。     

Study on Recovering the Earth＇s Potential Field Based on GOCE Gradiometry

Given the second radial derivative Vrr（P） ｜δs of the Earth＇s gravitational potential V（P） on the surface δS corresponding to the satellite altitude, by using the fictitious compress recovery method, a fictitious regular harmonic field rrVrr（P）^＊ and a fictitious second radial gradient field V：（P） in the domain outside an inner sphere Ki can be determined, which coincides with the real field V（P） in the domain outside the Earth. Vrr^＊（P）could be further expressed as a uniformly convergent expansion series in the domain outside the inner sphere, because rrV（P）^＊ could be expressed as a uniformly convergent spherical harmonic expansion series due to its regularity and harmony in that domain. In another aspect, the fictitious field V^＊（P） defined in the domain outside the inner sphere, which coincides with the real field V（P） in the domain outside the Earth, could be also expressed as a spherical harmonic expansion series. Then, the harmonic coefficients contained in the series expressing V^＊（P） can be determined, and consequently the real field V（P） is recovered. Preliminary simulation calculations show that the second radial gradient field Vrr（P） could be recovered based only on the second radial derivative V（P）｜δs given on the satellite boundary. Concerning the final recovery of the potential field V（P） based only on the boundary value Vrr （P）｜δs, the simulation tests are still in process.     

基于约束的城市街道网自动综合方法

近年来,基于约束的地图自动综合成为研究的热点。本研究在基于约束的地图自动综合理论的基础上,提出了一种城市街道网自动综合方法。该方法依赖于街道网综合中的约束和改进的动态决策树结构,它很好地将约束融入了特定的数据结构,实现了街道网的渐进式综合。实验证明了方法具备可行性。     

大巴山西段高川地体构造变形特征及其意义

勉略缝合带华北与华南大陆于印支期完成拼合的主要拼接带,在中国大陆的形成与演化中占据重要地位。但是,勉略带的东、西延伸,至今没有确定的结论,尤其陕西省勉县以东到湖北随州一带,还没有找到确凿的缝合带的证据。现今一些重要的文章多认为勉略带在勉县以东到达宁陕县两河口之后向南转折,沿着高川岩片的位置顺大巴山弧形构造带向东延伸到湖北随州一带。然而,本文的研究表明,高川岩片是一个独立于大巴山构造带的外来地质体,并称之为高川地体。高川地体是一个由近南北向右行走滑断层与轴向近南北向的走滑剪切褶皱构造组成的右行走滑构造系统,作者认为,它是大巴山冲断推覆构造向南推覆过程中,被从原勉略缝合带中挤过来的一片,它仅仅是被挟持在大巴山冲断—推覆构造带与大巴山前陆构造带之间的地壳浅层地质体,高川地体现在的位置不能代表勉略带向东的延伸。因此,大巴山弧形构造带也不是中国南北大陆最终碰撞拼贴的位置     

基于贡献权重迭加法的滑坡风险区划

贡献权重迭加法是对滑坡本底因子和承灾体因子在滑坡发育中的贡献率进行统计后,通过贡献率均值化、规一化处理,利用权重转换模型计算出每一个因子内部的权重——自权重W和因子相互之间的权重——互权重W＇。将滑坡因子、承灾体因子和两者的自权重、互权重分别相乘迭加,得到滑坡危险度和易损度区划结果,再将2项结果相乘得出滑坡风险区划。     

山西保德—静乐地区新近纪地层时代讨论

通过对山西保德-静乐地区新近纪地层的野外地质调查和实测剖面,对分布于该区的新近纪地层进行了详细的研究和划分,获得了新的ESR和古地磁测年数据,并结合生物地层序列确定了该区新近系地层的顺序为：新近系上新统静乐组（N2j）、新近系中新统上部保德组（N1^26）和中新统下部芦子沟组（N1^1l）。     

遥感技术在煤炭资源开发状况监督管理中的应用研究

利用高分辨率遥感图象可以快速查明煤炭资源开发状况以及煤炭资源开发的合法性（界内开采、界外开采、越界开采）等,对煤矿安全生产及维护矿业秩序具有重要意义。以我国中部某煤炭开采密集区为试验区,选择不同分辨率的遥感数据,从矿山铺助设施、道路、矿堆、矸石的特征出发,进行矿山开采状况遥感解译;以地理信息系统技术（GIS）为支撑实现采矿权数据、规划数据图层与遥感专题数据的叠加分析和相关分析,判断非法与越界矿山,评价矿产资源开发与保护规划执行情况。     

煤层气固井声幅测井方法探讨

影响煤层气固井声幅测井的因素较多,如地层软硬变化大、套管内径或壁厚不均、仪器不居中、发射能量不足、接收灵敏度不够等,这些因素的存在将会导致首波丢失、时差曲线产生周波跳跃或波动现象。为提高煤层气固井声幅测井质量,要尽量保证所用仪器外径接近套管内径,以减少无效传播和能量损失,另外需提高仪器的发射能量及接收灵敏度;在自由套管和声波强吸收地层,必须保证自由套管首波不限幅、声波强吸收地层首波不丢失。在现场解释时,一般以＂自由套管＂处的偏转幅度值A为标准,将固井声幅曲线幅度的20%A和40%A作为分界点,评价固井效果。