Metoz: Total ozone from meteorological parameters

Abstract

On the basis of two well‐known ozone‐weather relationships, an algorithm is proposed that estimates total ozone amounts using readily available meteorological information. The technique has been labelled METOZ from Meteorological Total Ozone. A rationale and derivation of the technique is presented.

METOZ total ozone amounts were generated for Toronto and Edmonton locations and compared with ground‐based Brewer spectrophotometer measures for these two stations in the Canadian ozone monitoring network for data from January to April 1989. Per cent differences between METOZ and Brewer total ozone measurements were calculated and are presented.

This mid‐latitude wînter metoz algorithm was also used to produce a hemispherical total ozone field for 16 March 1986, which was compared with the corresponding TOMS data to demonstrate other potential applications of the technique.     

Surface Energy Balance Measurements Above an Exurban Residential Neighbourhood of Kansas City,Missouri

Previous measurements of urban energy balances generally have been limited to densely built, central city sites and older suburban locations with mature tree canopies that are higher than the height of the buildings. In contrast, few data are available for the extensive, open vegetated types typical of low-density residential areas that have been newly converted from rural land use. We made direct measurements of surface energy fluxes using the eddy-covariance technique at Greenwood, a recently developed exurban neighbourhood near Kansas City, Missouri, USA, during an intensive field campaign in August 2004. Energy partitioning was dominated by the latent heat flux under both cloudy and near clear-sky conditions. The mean daytime Bowen ratio (β) values were 0.46, 0.48, and 0.47 respectively for the cloudy, near clear-sky and all-sky conditions. Net radiation (R _n ) increased rapidly from dawn (−34 and −58W m⁻²) during the night to reach a maximum (423 and 630W m⁻²) after midday for cloudy and near clear-sky conditions respectively. Mean daytime values were 253 and 370W m⁻², respectively for the cloudy and near clear-sky conditions, while mean daily values were 114 for cloudy and 171W m⁻² for near clear-sky conditions, respectively. Midday surface albedo values were 0.25 and 0.24 for the cloudy and near clear-sky conditions, respectively. The site exhibited an angular dependence on the solar elevation angle, in contrast to previous observations over urban and suburban areas, but similar to vegetated surfaces. The latent heat flux (Q _E ), sensible heat flux (Q _H ), and the residual heat storage ΔQ _s terms accounted for between 46–58%, 21–23%, and 18–31% of R _n , respectively, for all-sky conditions and time averages. The observed albedo, R _n , and Q _E values are higher than the values that have been reported for suburban areas with high summer evapotranspiration rates in North America. These results suggest that the rapidly growing residential areas at the exurban fringe of large metropolitan areas have a surface energy balance that is more similar to the rural areas from which they were developed than it is to the older suburbs and city centres that make up the urban fabric to which they are being joined.     

Numerical Modeling of Slug Tests with MODFLOW Using Equivalent Well Blocks

Slug tests are a widely used technique to estimate aquifer hydraulic parameters and the test data are generally interpreted with analytical solutions under various assumptions. However, these solutions are not convenient when slug tests are required to be analyzed in a three‐dimensional model for complex aquifer‐aquitard systems. In this study, equivalent well blocks (EWB) are proposed in numerical modeling of slug test data with MODFLOW. Multi‐well slug tests in partially penetrating wells with skin zones can be simulated. Accuracy of the numerical method is demonstrated by benchmarking with analytical solutions. The EWB method is applied in a case study on slug tests in aquitards in the Pearl River Delta, China.     

Satellite-Based Assessment of the Extent and Changes in the Mangrove Ecosystem of the Niger Delta

This study was carried out with the primary aim of understanding how the mangrove ecosystem in the Niger Delta has been altered recently. Specifically, we determined the spatial extent of the mangrove forest in the Niger Delta using remotely sensed satellite data and estimated changes in the spatial extent of the forest from the mid-1980s through 2003. Overall, about 21,340 hectares of Mangrove forest was lost over the study period. Fieldwork confirmed that these losses were primarily due to urbanization, dredging activities, activities of the oil and gas industries, and the spread of Nypa Palm (Nypa frutican) plant species.     

Surficial geophysical deduction of the geomaterial and aquifer distributions at Ngor-Okpala local government area of Imo State, South Eastern Nigeria

Twenty seven vertical electrical sounding (VES) profiles surrounding four known traverses were obtained in Ngor-Okpala local government area of Imo state to examine the subsurface geomaterials and the associated groundwater potential. The VES data, constrained by borehole data, provided useful information about the subsurface hydrogeologic and lithologic conditions. From the validated interpretation, the area assessed has loamy soil, medium grained sands, well-sorted medium-grained/gravelly sands and river sand as the lithologic succession from top to the bottom of the depth penetrated. The aquifers in the area were found in the medium-grained sands and well-sorted medium-coarse-grained sands. The aquifer depth for all-season groundwater that would be devoid of draw-down can be found at a depth range of 42–50 m. The resistivity maps of selected depths exhibit sharp resistivity changes at depth due mainly to undulating subsurface topography. A map of the distribution of the kσ-values shows that good quality groundwater can be found in most parts of the area.     

Weathering of ordinary chondrites from the Atacama Desert,Chile, by Mössbauer spectroscopy and synchrotron radiation X‐ray diffraction

Some terrestrial areas have climatic and geomorphologic features that favor the preservation, and therefore, accumulation of meteorites. The Atacama Desert in Chile is among the most important of such areas, known as DCA. This desert is the driest on Earth, one of the most arid, uninhabitable localities with semiarid, arid, and hyper‐arid conditions. The meteorites studied here were collected from within the DCA of San Juan and Pampa de Mejillones, located, respectively, in the Central Depression and the Coastal Range of the Atacama Desert. ⁵⁷Fe Mössbauer spectroscopy was used for quantitative analysis of the degree of weathering of the meteorites, through the determination of the proportions of the various Fe‐bearing phases and in particular the amount of oxidized iron in terrestrial alteration products. The abundance of ferric ions in weathered chondrites can be related to specific precursor compositions and to the level of terrestrial weathering. The aim of the study was the identification, quantification, and differentiation of the weathering products in the ordinary chondrites found in the San Juan and the Pampa de Mejillones areas of the Atacama Desert. The ⁵⁷Fe Mössbauer spectroscopy study was complemented by synchrotron radiation X‐ray diffraction and magnetic susceptibility measurements. The results allow a clear differentiation of the rate of weathering in meteorite samples collected from the San Juan versus the Pampa de Mejillones areas of the Atacama Desert.     

Spatio-temporal trends of heavy metals and source apportionment in Tolo Harbour,Hong Kong

This study provided a picture of the spatial and temporal distributions of Cr, Co, Ni Cu, Zn, As, Cd and Pb in bottom sediments of Tolo Harbour. The concentrations of the eight heavy metals differed significantly between sites due to the poor tidal flushing in Tolo Harbour. The levels of Cu, Zn, Cd and Pb were generally enriched in sediments from inner Tolo Harbour, while sediments from outer Tolo Harbour (Tolo Channel) had higher levels of Cr, Co and Ni. The redox sensitive element arsenic showed no distinct spatial pattern in Tolo Harbour. The decreasing levels of Cu, Zn, Pb and Cd in sediments with increasing distance from land demonstrated a typical diffusion pattern from land to the direction of sea. Two hot spots of Cu, Zn, Pb and Cd in sediments were located near Tai Po and Sha Tin new town, indicating that Cu, Zn, Pb and Zn were from land-derived sources. The sites with relatively high levels of Cr, Co and Ni in sediments were located in areas close to waste spoil in sea floor. The natural and anthropogenic inputs from Sha Tin and Tai Po to Tolo Harbour were mostly responsible for Cu, Zn, Cd and Pb enrichment in sediments from inner Tolo Harbour. The waste spoil in sea floor was believed to contribute to the Cr, Co and Ni in outer Tolo Harbour. The results of correlation coefficient between the eight heavy metals showed that Cu, Zn, Cd and Pb were strongly positively correlated, and Cr, Co and Ni were also significantly correlated with each other. The best explanation of strong correlation was their similar source. As, however, is not well correlated with the other seven heavy metals. The average concentrations of Cu and Zn displayed general increasing trends from 1978 to 2006 in Tolo Harbour, while the mean levels of Cr and Pb displayed a substantial decrease from 1978 to 1987, then a slight increase after 1987. No distinct temporal trends of the concentrations of Ni and As were observed from 1978 due to the inconsecutive data. On the other hand, the increasing trends of Cr, Cu, Zn, Cd and Pb were observed since 1996.