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91.
Tidal Fluctuation Influenced Physicochemical Parameter Dynamics in Coastal Groundwater Mixing Zone 总被引:1,自引:0,他引:1
Tidal fluctuation could modify the physicochemical parameters in coastal groundwater mixing zone (CGMZ) notably, which in turn largely impacts on the reactive transport, discharge, and cycling of carbon, nutrients, trace metals, and other dissolved constituents. In this study, to capture the dynamic of groundwater physicochemical parameters (e.g., salinity, dissolved oxygen, pH, temperature, and oxidation/reduction potential) under the effect of tidal fluctuation, in situ measurement of groundwater is conducted along a 2D transection at different tidal stages. The results demonstrate visible periodic variations of parameters like salinity, temperature, DO, and pH, while the groundwater pH oscillation displays a phase lag behind the tidal fluctuation. Furthermore, the salinity variation at the near-surface area is mainly controlled by the mixing process between the infiltrated seawater and groundwater. Barring the mixing process, the groundwater temperature at the near-surface area is also affected by day and night air temperature difference. Meanwhile, the depleting DO and declining pH indicate that the biodegradation via aerobic respiration is highly active in CGMZ and acts as one of the major impact factors for the DO dynamic. The sharp contrast between the high removal rate of DO (7.25 mmol m?3 day?1) and relatively low production rate of H+ (9.38 μmol m?3 day?1) demonstrates the existence of the processes consuming H+ and DO besides aerobic respiration such as dissolution of carbonates, and respiration of microorganism and mangrove roots. Moreover, owing to the mixing process, the salinity transition zone overlaps with the oxidization/reduction potential transition zone. The enrichment of Fe2+ and Mn2+ could well explain the highly reducing saline groundwater observed in this study. In a nutshell, all physicochemical parameters are sensitive to tidal fluctuation, which provides implication for further study on the variation of biogeochemical process in CGMZ. 相似文献
92.
Solar influence and hydrological variability during the Holocene from a speleothem annual record (Molinos Cave,NE Spain) 总被引:1,自引:0,他引:1 下载免费PDF全文
Arsenio Muñoz Miguel Bartolomé Alicia Muñoz Carlos Sancho Ana Moreno John C. Hellstrom Mª Cinta Osácar Isabel Cacho 《地学学报》2015,27(4):300-311
We present a multi‐proxy approach to reconstructing Holocene climate conditions in northeastern Spain based on an excellent correlation among the lamina thickness, colour parameters and isotope (δ18O and δ13C) variations recorded in a speleothem. An age model constructed from five U/Th dates and annual lamina counting suggests that the uppermost 14.7 cm of the MO‐7 stalagmite grew between 7.2 and 2.5 ka before present but experienced a growth hiatus from 4.9 to 4.3 ka. Three spectral analysis methods were applied to 11 time series. The results reveal common solar periodicities on decennial (Gleissberg cycle) and centennial (De Vries‐Suess cycle) scales. The onset of Holocene carbonate precipitation in the MO‐7 stalagmite appears to be associated with a cold, wet period, whereas the hiatus and the end of growth are related to warm, dry periods. This environmental trend fits well within the regional Holocene climate. 相似文献
93.
Telm Bover‐Arnal Ramon Salas Joan Guimerà Josep Anton Moreno‐Bedmar 《Sedimentology》2014,61(6):1558-1593
Long‐term relative sea‐level cycles (0·5 to 6 Myr) have yet to be fully understood for the Cretaceous. During the Aptian, in the northern Maestrat Basin (Eastern Iberian Peninsula), fault‐controlled subsidence created depositional space, but eustasy governed changes in depositional trends. Relative sea‐level history was reconstructed by sequence stratigraphic analysis. Two forced regressive stages of relative sea‐level were recognized within three depositional sequences. The first stage is late Early Aptian age (intra Dufrenoyia furcata Zone) and is characterized by foreshore to upper shoreface sedimentary wedges, which occur detached from a highstand carbonate platform, and were deposited above basin marls. The amplitude of relative sea‐level drop was in the order of tens of metres, with a duration of <1 Myr. The second stage of relative sea‐level fall occurred within the Late Aptian and is recorded by an incised valley that, when restored to its pre‐contractional attitude, was >2 km wide and cut ≥115 m down into the underlying Aptian succession. With the subsequent transgression, the incision was backfilled with peritidal to shallow subtidal deposits. The changes in depositional trends, lithofacies evolution and geometric relation of the stratigraphic units characterized are similar to those observed in coeval rocks within the Maestrat Basin, as well as in other correlative basins elsewhere. The pace and magnitude of the two relative sea‐level drops identified fall within the glacio‐eustatic domain. In the Maestrat Basin, terrestrial palynological studies provide evidence that the late Early and Late Aptian climate was cooler than the earliest part of the Early Aptian and the Albian Stage, which were characterized by warmer environmental conditions. The outcrops documented here are significant because they preserve the results of Aptian long‐term sea‐level trends that are often only recognizable on larger scales (i.e. seismic), such as for the Arabian Plate. 相似文献
94.
João Moreno Francisco Fatela Eduardo Leorri José M. De la Rosa Inês Pereira M. Fátima Araújo M. Conceição Freitas D. Reide Corbett Ana Medeiros 《Quaternary Research》2014
A high-resolution study of a marsh sedimentary sequence from the Minho estuary provides a new palaeoenvironmental reconstruction from NW Iberian based on geological proxies supported by historical and instrumental climatic records. A low-salinity tidal flat, dominated by Trochamminita salsa, Haplophragmoides spp. and Cribrostomoides spp., prevailed from AD 140–1360 (Roman Warm Period, Dark Ages, Medieval Climatic Anomaly). This sheltered environment was affected by high hydrodynamic episodes, marked by the increase in silt/clay ratio, decrease of organic matter, and poor and weakly preserved foraminiferal assemblages, suggesting enhanced river runoff. The establishment of low marsh began at AD 1380. This low-salinity environment, marked by colder and wet conditions, persisted from AD 1410–1770 (Little Ice Age), when foraminiferal density increased significantly. Haplophragmoides manilaensis and Trochamminita salsa mark the transition from low to high marsh at AD 1730. Since AD 1780 the abundances of salt marsh species (Jadammina macrescens, Trochammina inflata) increased, accompanied by a decrease in foraminiferal density, reflecting climate instability, when droughts alternate with severe floods. SW Europe marsh foraminifera respond to the hydrological balance, controlled by climatic variability modes (e.g., NAO) and solar activity, thus contributing to the understanding of NE Atlantic climate dynamics. 相似文献
95.
Emilio Porcu Daryl J. Daley Martin Buhmann Moreno Bevilacqua 《Stochastic Environmental Research and Risk Assessment (SERRA)》2013,27(4):909-922
Matrix-valued radially symmetric covariance functions (also called radial basis functions in the numerical analysis literature) are crucial for the analysis, inference and prediction of Gaussian vector-valued random fields. This paper provides different methodologies for the construction of matrix-valued mappings that are positive definite and compactly supported over the sphere of a d-dimensional space, of a given radius. In particular, we offer a representation based on scaled mixtures of Askey functions; we also suggest a method of construction based on B-splines. Finally, we show that the very appealing convolution arguments are indeed effective when working in one dimension, prohibitive in two and feasible, but substantially useless, when working in three dimensions. We exhibit the statistical performance of the proposed models through simulation study and then discuss the computational gains that come from our constructions when the parameters are estimated via maximum likelihood. We finally apply our constructions to a North American Pacific Northwest temperatures dataset. 相似文献
96.
We present detailed pollen and charcoal records from Lago Pichilafquén (~ 41°S) to decipher the effects of climate change and varying disturbance regimes on the composition and structure of the vegetation on the Andean foothills of northwestern Patagonia during the last 2600 yr. Here, temperate rainforests have dominated the landscape since 2600 cal yr BP with variations ranging from cool-temperate and wet north Patagonian rainforests to relatively warm and summer-drought-resistant Valdivian rainforests. We interpret relatively warm/dry conditions between 1900–2600, 690–750 and 320–430 cal yr BP, alternating with cold/wet conditions between 1500–1900, 750–1100 and 430–690 cal yr BP. Rapid deforestation and spread of plants introduced by Europeans occurred at 320 and 140 cal yr BP. The record includes five tephras with ages of 2130, 1460, 1310, 1210, and 340 cal yr BP, all of which precede local fire events and increases in trees favored by disturbance by less than 100 yr. We conclude that centennial-scale changes in the southern westerlies were the primary driver of vegetation shifts in northwestern Patagonia over the last 2600 yr. Within this interval, local disturbance regimes altered the structure, composition, and dynamics of the lowland rainforest vegetation during several discrete, short-lived episodes. 相似文献
97.
Roger Kwok Jimmy C. H. Fung Alexis K. H. Lau Zion S. Wang 《Journal of Atmospheric Chemistry》2012,69(1):1-22
The Tagged Species Source Apportionment (TSSA) algorithm is applied to study contributions to pollutants PM sulfate, SO2 and elemental carbon (EC) in Hong Kong by emitting sectors as well as non-emitting sources within and beyond the Pearl River Delta (PRD) region. We look at three areas of Hong Kong: western new towns, central downtown, and eastern countryside. Pollutant transport from beyond the PRD influenced all three areas during January and October 2004 but the source sectors impacting the three areas were different. Specifically, power plant SO2 from Hong Kong and Shenzhen, and vehicle EC from Shenzhen contribute to 11?~?66?% of SO2 concentration, and 33?~?75?% of EC concentration in the western new towns, respectively. Ships in and around Hong Kong contribute 8?~?56?% to the sulfate concentration in the downtown area, while local moving vehicles take up 28?~?81?% of the EC concentration there. The study also shows that diurnal variation of planetary boundary layer (PBL) causes day-night difference in SO2 by as much as 50?%. In addition, 13?~?38?% of all SO2 emissions have been converted to PM sulfate. 相似文献
98.
Lateglacial and Holocene palaeohydrology in the western Mediterranean region: The Lake Estanya record (NE Spain) 总被引:3,自引:0,他引:3
Mario Morelln Blas Valero-Garcs Teresa Vegas-Vilarrúbia Penlope Gonzlez-Sampriz
scar Romero Antonio Delgado-Huertas Pilar Mata Ana Moreno Mayte Rico Juan Pablo Corella 《Quaternary Science Reviews》2009,28(25-26):2582-2599
The multi-proxy analysis of sediment cores recovered in karstic Lake Estanya (42°02′ N, 0°32′ E; 670 m a. s. l., NE Spain), located in the transitional area between the humid Pyrenees and the semi-arid Central Ebro Basin, provides the first high-resolution, continuous sedimentary record in the region, extending back the last 21 000 years. The integration of sedimentary facies, elemental and isotopical geochemistry and biogenic silica, together with a robust age model based on 17 AMS radiocarbon dates, enables precise reconstruction of the main hydrological and environmental changes in the region during the last deglaciation.Arid conditions, represented by shallow lake levels, predominantly saline waters and reduced organic productivity occurred throughout the last glacial maximum (21–18 cal kyrs BP) and the lateglacial, reaching their maximum intensity during the period 18–14.5 cal kyrs BP (including Heinrich event 1) and the Younger Dryas (12.9–11.6 cal kyrs BP). Less saline conditions characterized the 14.5–12.6 cal kyrs BP period, suggesting higher effective moisture during the Bölling/Allerød. The onset of more humid conditions started at 9.4 cal kyrs, indicating a delayed hydrological response to the onset of the Holocene which is also documented in several sites of the Mediterranean Basin. Higher, although fluctuating, Holocene lake levels were punctuated by a mid Holocene arid period between 4.8 and 4.0 cal kyrs BP. A major lake-level rise occurred at 1.2 cal kyrs BP, conducive to the establishment of conditions similar to the present and interrupted by a last major water level drop, occurring around 800 cal yrs BP, which coincides with the Medieval Climate Anomaly.The main hydrological stages in Lake Estanya are in phase with most Western Mediterranean and North Atlantic continental and marine records, but our results also show similarities with other Iberian and northern African reconstructions, emphasizing peculiarities of palaeohydrological evolution of the Iberian Peninsula during the last deglaciation. 相似文献
99.
The exposure time is a variable which is usually not incorporated into models for toxicity. However, with persistent organic pollutants (POPs) exhibiting a nonspecific mode of action and lipophilic properties this variable can be modeled by the usage of the internal concentrations as a measure of the toxicity with fish. The bioconcentration process with fish is a relatively well understood and predictable process which allows the calculation of the internal lethal concentration. When the exposure time is relatively short the critical internal lethal concentrations are relatively constant for the group of POPs whereaas the LC50 measured in the ambient water is quite variable. When the exposure time is relatively long, results on the measurement of the critical internal concentration with fish over different exposure times has demonstrated that the internal lethal concentration falls with increasing exposure times in a consistent and predictable manner. This reduction in life expectancy can be described in a model which can be used to estimate the critical internal concentration for any exposure time. It also provides information useful in assessing the risk to fish and potentially other species due to the occurrence of residues of POPs in natural aquatic systems. It is suggested that these relationships can be extended to other groups of organisms and chemicals. 相似文献
100.