Subaqueous pyroclastic flows and ignimbrites: an assessment

An assessment of the literature on subaqueous pyroclastic flows and their deposits shows that the term pyroclastic flow is frequently used loosely to describe primary, hot gas-rich pyroclastic flows, mass-flows which resulted from the transformation of gassupported flows into water-supported ones, and secondary mass-flows carrying redeposited pyroclastic debris. Based on subaerial pyroclastic flows, the term pyroclastic flow should be restricted to demonstrably hot, gas-rich mass-flows of pyroclastic debris. Using this definition, very few examples of subaqueous pyroclastic deposits with evidence for hot emplacement and of having been wholly submerged have been described. In the majority of these cases, the evidence for a hot state of emplacement and for the subaqueous nature of the host depositional environment is inadequate. The only unequivocal cases of hot pyroclastic flow deposits with adequate supporting evidence are the Ordovician nearshore, shallow marine ignimbrites of Ireland and Wales, and Miocene ignimbrites of southwest Japan, resulting from the passage of subaerially erupted pyroclastic flows into shallow water. Other possible examples are near-vent dense clast deposits in the Donzurobo Formation of Japan, possible submarine intra-caldera ponded ignimbrite successions in California and Wales, and near-vent pumiceous deposits of Ramsay Island, Wales. All other purported cases are either clearly the result of water-supported mass-flow transportation and deposition (debris avalanches, debris flows, turbidity currents), or lack adequate supporting evidence regarding the heat state or the palaeoenvironment. Only the shallow marine ignimbrites of Ireland and Wales show adequate evidence of welding, but even these could have been nearly wholly exposed above sea-level when welding occurred. We conclude that when pyroclastic flows enter water they are generally disrupted explosively and/or ingest water and transform into water-supported mass-flows, and we suggest the various scenarios in which this occurs. There is no evidence to suggest that welding in wholly subaqueous environments is common.     

Detecting Changes in Ground Water Quality at Regulated Facilities

The Resource Conservation and Recovery Act (PL 94–580) and related federal and state legislation have mandated routine monitoring of ground water quality at regulated facilities. The objective of the required monitoring activities is detection of adverse changes in ground water quality caused by the facilities.
Both failure to detect pollution and an incorrect determination of pollution can be very expensive. It is crucial, therefore, that monitoring programs be designed and operated to provide statistically sound information. It is equally important that users of ground water quality data understand the nature and limitations of information from monitoring.
To address the preceding issues, the authors present a general approach to analyzing ground water quality data in light of the stated monitoring objective. The suggested approach accounts for "natural" variation in background water quality through pairing of observations. The limitations of quarterly sampling for detecting small changes in quality over a short time frame are discussed.     

An analogue model study of electromagnetic induction in the eastern coastal region of North America

The behavior of electric and magnetic field variations over the eastern coastal region of North America is studied using a scaled laboratory electromagnetic analogue model. The model source frequency used simulates a period of 1 h in the geophysical scale. The results indicate that deflection and conductive channelling of induced electric current is important for both the E-polarization (northeast-southwest direction of the electric field of the source) and the H-polarization (northwest-southeast) of the source field. In the model, conductive channelling occurs through the Strait of Belle Isle, Cabot Strait, and in the St. Lawrence River. Current deflection is particularly prevalent around the southeast coast of Newfoundland for both E- and H-polarization, and around the northeast coastline of Nova Scotia for E-polarization. The model results also show current deflection by cape and bay coastal features, as well as by ocean depth contours.A comparison of model measurements for the cases of a uniform source field and a line current source indicate that the nature of the source field has a measurable but surprisingly small effect on the vertical to horizontal magnetic field ratio for both E- and H-polarizations, and negligible effect on the magnetotelluric ratio for coastal regions.The model fields in coastal regions were found to be strongly influenced by induced currents, deflected and channelled by the coastline and ocean bathymetry, and were dependent on the nature and particularly the polarization of the source field. Thus, along the complex coastline of eastern North America, a wide range of electric and magnetic field values should be expected. In some regions the coast effect, measured by the vertical to horizontal magnetic field ratio at the coast, could be expected to be extremely small or absent, while in other regions the ratio could approach a value as large as unity for variations of 1 h period.     

A method of searching for radial velocity anomalies in the lower mantle using interfering signals

Radial velocity anomalies in the lower mantle that give rise to triplications in the travel-time curve for short-periodP waves will produce arrivals havingdT/d values that differe by roughly 0.2–0.5 s/deg. The first two arrivals associated with such triplications will be separated by less than one second over a distance range of 4°–10° they may not, therefore, be separable visually on single seismograms, so that their presence can only be inferred from some measurable property that depends on their mutual interference. If there are lateral variations in the regions of anomalous velocity gradients, the interfering signals will also have different azimuths of arrival. Using two synthetic wavelets we have investigated the effect of interference on bothdT/d and azimuth measurements at the Yellowknife Array. We found that if the interfering pulses have a dominant frequencyv, there is a range of time separations (0.30/v0.55/v) over which the measureddT/d and azimuth values may fluctuate by much more than the differences indT/d and azimuth between the interfering signals. We have evaluated the following empirically defined functions for three different primary signals, and for three different relative amplitudes of the interfering signals:f (t), the drift function, which expresses how the measured slownesses,p, and azimuths, , differ from the slownesses and azimuths of the primary wavelets; f(), the range function, which describes the behaviour of the upper and lower bounds ofp and as a function of the difference in arrival times of the signals, andf , studied the properties of these functions, and have outlined how these properties provide criteria based on the numerical and statistical characteristics of the arrival vectors, and on the waveform of the signal that will enable small radial velocity anomalies to be more clearly delineated.Contribution No. 863 from the Earth Physics Branch.     

Adsorption of cobalt by using inorganic components of sediment samples from water bodies

The adsorption of cobalt ions was evaluated using sediment samples from water bodies to investigate the adsorption properties of sediment and the behavior of these natural materials in the presence of nuclear and industrial waste.The two sediments(S1 and S2)were treated to eliminate humic and fulvic acids and then they were characterized by several techniques.The minerals found in both the sediments(X-ray diffraction)were quartz and albite;plus,goethite and muscovite in S1,and kaolinite and montmorillonite in S2.Point of zero charge(PZC)of S1 and S2 was 6.00 and 5.22,respectively.The specific area of S1(63.3 m²/g)is higher than S2(1.5 m²/g).Adsorption kinetics data for S1 and S2 were best fitted to the pseudo second-order model.The removal efficiency of S1 for cobalt was 96%with an adsorption capacity(qe)of 0.93 mg/g,and for S2 was 45%with a qeof 0.40 mg/g.The experimental data of the adsorption isotherms were adjusted to Langmuir and Freundlich models for S1 and S2,respectively.The thermodynamic parameters(enthalpy,entropy,and Gibb’s free energy)indicated that the adsorption processes were endothermic,spontaneous,and chemisorption mechanism.The results show that the adsorption capacities of the sediments depend on their composition.These water sediments have important adsorption properties for cobalt,and they can be used in the treatment of nuclear and industrial aqueous wastes.     

Analysis of tracer tomography using temporal moments of tracer breakthrough curves

Hydraulic/partitioning tracer tomography (HPTT) was recently developed by Yeh and Zhu [Yeh T-CJ, Zhu J. Hydraulic/partitioning tracer tomography for characterization of dense nonaqueous phase liquid source zones, Water Resour Res 2007;43:W06435. doi:10.1029/2006WR004877.] for estimating spatial distribution of dense nonaqueous phase liquids (DNAPLs) in the subsurface. Since discrete tracer concentration data are directly utilized for the estimation of DNAPLs, this approach solves the hyperbolic convection–dispersion equation. Solution to the convection–dispersion equation however demands fine temporal and spatial discretization, resulting in high computational cost for an HPTT analysis. In this work, we use temporal moments of tracer breakthrough curves instead of discrete concentration data to estimate DNAPL distribution. This approach solves time independent partial differential equations of the temporal moments, and therefore avoids solving the convection–dispersion equation using a time marching scheme, resulting in a dramatic reduction of computational cost. To reduce numerical oscillations associated with convection dominated transport problems such as in inter-well tracer tests, the approach uses a finite element solver adopting the streamline upwind Petrov–Galerkin method to calculate moments and sensitivities. We test the temporal moment approach through numerical simulations. Comparing the computational costs between utilizing moments and discrete concentrations, we find that temporal moments significantly reduce the computation time. We also find that tracer moment data collected through a tomographic survey alone are able to yield reasonable estimates of hydraulic conductivity, as indicated by a correlation of 0.588 between estimated and true hydraulic conductivity fields in the synthetic case study.     

Seismic activity related to the 1991 eruption of Colima Volcano,Mexico

Ten years after the last effusive eruption and at least 15 years of seismic quiescence, volcanic seismic activity started at Colima volcano on 14 February 1991, with a seismic crisis which reached counts of more than 100 per day and showed a diversity of earthquake types. Four other distinct seismic crises followed, before a mild effusive eruption in April 1991. The second crisis preceded the extrusion of an andesitic scoriaceous lava lobe, first reported on 1 March; during this crisis an interesting temporary concentration of seismic foci below the crater was observed shortly before the extrusion was detected. The third crisis was constituted by shallow seismicity, featuring possible mild degassing explosion-induced activity in the form of hiccups (episodes of simple wavelets that repeat with diminishing amplitude), and accompanied by increased fumarolic activity. The growth of the new lava dome was accompanied by changing seismicity. On 16 April during the fifth crisis which consisted of some relatively large, shallow, volcanic earthquakes and numerous avalanches of older dome material, part of the newly extruded dome, which had grown towards the edge of the old dome, collapsed, producing the largest avalanches and ash flows. Afterwards, block lava began to flow slowly along the SW flank of the volcano, generating frequent small incandescent avalanches. The seismicity associated with the stages of this eruptive activity shows some interesting features: most earthquake foci were located north of the summit, some of them relatively deep (7–11 km below the summit level), underneath the saddle between the Colima and the older Nevado volcanoes. An apparently seismic quiet region appears between 4 and 7 km below the summit level. In June, harmonic tremors were detected for the first time, but no changes in the eruptive activity could be correlated with them. After June, the seismicity decreasing trend was established, and the effusive activity stopped on September 1991.