Comparison of heat and bromide as ground water tracers near streams

Heat and bromide were compared as tracers for examining stream/ground water exchanges along the middle reaches of the Santa Clara River, California, during a 10-hour surface water sodium bromide injection test. Three cross sections that comprise six shallow (<1 m) piezometers were installed at the upper, middle, and lower sections of a 17 km long study reach, to monitor temperatures and bromide concentrations in the shallow ground water beneath the stream. A heat and ground water transport simulation model and a closely related solute and ground water transport simulation model were matched up for comparison of simulated and observed temperatures and bromide concentrations in the streambed. Vertical, one-dimensional simulations of sediment temperature were fitted to observed temperature results, to yield apparent streambed hydraulic conductivities in each cross section. The temperature-based hydraulic conductivities were assigned to a solute and ground water transport model to predict sediment bromide concentrations, during the sodium bromide injection test. Vertical, one-dimensional simulations of bromide concentrations in the sediments yielded a good match to the observed bromide concentrations, without adjustment of any model parameters except solute dispersivities. This indicates that, for the spatial and temporal scales examined on the Santa Clara River, the use of heat and bromide as tracers provide comparable information with respect to apparent hydraulic conductivities and fluxes for sediments near streams. In other settings, caution should be used due to differences in the nature of conservative (bromide) versus nonconservative (heat) tracers, particularly when preferential flowpaths are present.     

Progress towards better weather forecasts for city dwellers: from short range to climate change

Summary The current resolution of operational weather forecast model is not sufficient in general to explicitly resolve even the major cities of the World. As a consequence, urban areas have traditionally been neglected in such models. The introduction of tiled land surface models has enabled sub-gridscale landuse to be modelled, and hence has provided the opportunity to model cities within weather forecast models. However, to date there has been little effort made within the operational weather forecast community. At present there is only one operational centre that explicitly resolves urban areas. This centre includes a simple urban scheme within its mesoscale and global models, which has been shown to have a positive impact on the forecast. However, with the recent developments within urban meteorology there are now a variety of urban schemes, which vary in their complexity and parameter requirements, that would be suitable for operational weather forecast models. So it is likely that more operational models, and in particular mesoscale models, will include urban areas in the near future. With the majority of the World‘s population living in cities, the resilience of these cities to the impacts of climate change is also becoming of increasing interest. This means that urban areas will have to be included within climate change simulations, as well as weather forecast simulations, in the future. At present, only one climate change model has included a parametrisation for urban areas. However, this is likely to increase if work in this area grows rapidly.     

Discussion of: Ortega-Flores et al. (2018) Provenance analysis of Oligocene sandstone from the Cerro Pelón area,southern Gulf of Mexico.https://doi.org/10.1080/00206814.2018.1476922

ABSTRACT

We discuss the 2018 publication that reports petrographic, heavy mineral data, mineral chemistry, and zircon geochronology for Oligocene sandstones in the Cerro Pelón area in southern Mexico Sureste basin. As the title of their paper says, the goal of their study is to establish the source (s) of the voluminous Cenozoic section in this region, reaching several kilometres in thickness and important as a petroleum system. These authors conclude that Oligocene sandstones of La Laja Formation were mostly sourced from eclogite- to greenschist-facies metasedimentary, metaigneous, and ultramafic rocks of the Guatemala suture complex. Minor contributions from the Chiapas Massif Complex, exposed directly to the south ~60 km of the Cerro Pelón area, were also suggested by the authors. They thus conclude that the Palaeogene stratigraphic record in southeastern Mexico was mostly controlled by the development of the Caribbean–North America plate boundary rather than by orogenic processes at the Pacific margin of North America. Presently, we do not agree with the conclusions of Ortega Flores and colleagues who studied the Cerro Pelón section, thus some discussion is required. Serpentinite bearing Nanchital Conglomerate is well exposed in the Cerro Pelón area, and high- to low-grade metamorphic rocks experienced an uplift in the vicinity of the Cerro Pelón area at the time of deposition of the La Laja Formation. We believe the data are better explained by multiple local sources in southern and eastern Oaxaca as well as sources to the south and southwest, which include the Cenozoic coastal batholith, the Grenvillean/Guichicovi basement complexes, the Chiapas Massif, the Mazatlán schist and other units in the Cuicateco Belt, as well as the Mesozoic cover of these areas (Todos Santos Formation, Cretaceous carbonate rocks, and Paleogene strata such as the Soyaló and Bosque Formations).     

The Oligocene Lund Tuff, Great Basin, USA: a very large volume monotonous intermediate

Unusual monotonous intermediate ignimbrites consist of phenocryst-rich dacite that occurs as very large volume (>1000 km³) deposits that lack systematic compositional zonation, comagmatic rhyolite precursors, and underlying plinian beds. They are distinct from countless, usually smaller volume, zoned rhyolite–dacite–andesite deposits that are conventionally believed to have erupted from magma chambers in which thermal and compositional gradients were established because of sidewall crystallization and associated convective fractionation. Despite their great volume, or because of it, monotonous intermediates have received little attention. Documentation of the stratigraphy, composition, and geologic setting of the Lund Tuff – one of four monotonous intermediate tuffs in the middle-Tertiary Great Basin ignimbrite province – provides insight into its unusual origin and, by implication, the origin of other similar monotonous intermediates.The Lund Tuff is a single cooling unit with normal magnetic polarity whose volume likely exceeded 3000 km³. It was emplaced 29.02±0.04 Ma in and around the coeval White Rock caldera which has an unextended north–south diameter of about 50 km. The tuff is monotonous in that its phenocryst assemblage is virtually uniform throughout the deposit: plagioclase>quartz≈hornblende>biotite>Fe–Ti oxides≈sanidine>titanite, zircon, and apatite. However, ratios of phenocrysts vary by as much as an order of magnitude in a manner consistent with progressive crystallization in the pre-eruption chamber. A significant range in whole-rock chemical composition (e.g., 63–71 wt% SiO₂) is poorly correlated with phenocryst abundance.These compositional attributes cannot have been caused wholly by winnowing of glass from phenocrysts during eruption, as has been suggested for the monotonous intermediate Fish Canyon Tuff. Pumice fragments are also crystal-rich, and chemically and mineralogically indistinguishable from bulk tuff. We postulate that convective mixing in a sill-like magma chamber precluded development of a zoned chamber with a rhyolitic top or of a zoned pyroclastic deposit. Chemical variations in the Lund Tuff are consistent with equilibrium crystallization of a parental dacitic magma followed by eruptive mixing of compositionally diverse crystals and high-silica rhyolite vitroclasts during evacuation and emplacement. This model contrasts with the more systematic withdrawal from a bottle-shaped chamber in which sidewall crystallization creates a marked vertical compositional gradient and a substantial volume of capping-evolved rhyolite magma. Eruption at exceptionally high discharge rates precluded development of an underlying plinian deposit.The generation of the monotonous intermediate Lund magma and others like it in the middle Tertiary of the western USA reflects an unusually high flux of mantle-derived mafic magma into unusually thick and warm crust above a subducting slab of oceanic lithosphere.     

Modeling rhamnolipids production by Pseudomonas aeruginosa from immiscible carbon source in a batch system

A mathematical model to predict the rhamnolipids production by Pseudomonas aeruginosa from oleic acid in a two phase liquid-liquid batch reaction system, was developed in this study. The model was based on two theoretical assumptions: 1) the convective oleic acid mass transfer is coupled to a bioreaction in the aqueous liquid bulk, and 2) the volume of the immiscible oleic acid drops and the saturation concentration at the interface are a function of rhamnolipids production. The model was able to accurately predict the experimental growth of the Pseudomonas aeruginosa strain, and the rhamnolipids production data with oleic acid as carbon source. This mathematical approach indicated a high correspondence between the saturation dimensionless profiles of oleic acid at the interface and the experimental profiles of surface tension difference. This modeling approach may constitute a useful tool in the design and scaling-up of bioreactors applied to the production of biosurfactants with immiscible carbon sources.     

Managing reindeer and wildlife on Alaska's Seward Peninsula

When reindeer ( Rangifer tarandus tarandus ) were introduced to Alaska's Seward Peninsula between 1892 and 1902, other ungulates were not present and large predators were either absent or less abundant than after reindeer were established. During the next 100 years reindeer numbers and distribution increased and declined precipitously on the Seward Peninsula; wildlife species repopulated this region through natural processes or translocations by man; the non-Native human population of Alaska increased dramatically and wildlife management became an issue of national concern creating diverse public desires regarding resource use; and both range and wildlife became intensively managed through complex, politicized processes. This paper provides an historical overview of reindeer and wildlife abundance on the Seward Peninsula during the 20th century and describes the effects of wildlife on the reindeer industry. Cooperative public processes have been initiated to bring diverse public interests together; meld indigenous, scientific and local knowledge of resources; and supplement governmental wildlife management programmes. Even so, the Seward Peninsula reindeer industry has been severely impacted by wildlife, especially caribou ( R. t. granti ).     

Secondary mineralization pathways induced by dissimilatory iron reduction of ferrihydrite under advective flow

Iron (hydr)oxides not only serve as potent sorbents and repositories for nutrients and contaminants but also provide a terminal electron acceptor for microbial respiration. The microbial reduction of Fe (hydr)oxides and the subsequent secondary solid-phase transformations will, therefore, have a profound influence on the biogeochemical cycling of Fe as well as associated metals. Here we elucidate the pathways and mechanisms of secondary mineralization during dissimilatory iron reduction by a common iron-reducing bacterium, Shewanella putrefaciens (strain CN32), of 2-line ferrihydrite under advective flow conditions. Secondary mineralization of ferrihydrite occurs via a coupled, biotic-abiotic pathway primarily resulting in the production of magnetite and goethite with minor amounts of green rust. Operating mineralization pathways are driven by competing abiotic reactions of bacterially generated ferrous iron with the ferrihydrite surface. Subsequent to the initial sorption of ferrous iron on ferrihydrite, goethite (via dissolution/reprecipitation) and/or magnetite (via solid-state conversion) precipitation ensues resulting in the spatial coupling of both goethite and magnetite with the ferrihydrite surface. The distribution of goethite and magnetite within the column is dictated, in large part, by flow-induced ferrous Fe profiles. While goethite precipitation occurs over a large Fe(II) concentration range, magnetite accumulation is only observed at concentrations exceeding 0.3 mmol/L (equivalent to 0.5 mmol Fe[II]/g ferrihydrite) following 16 d of reaction. Consequently, transport-regulated ferrous Fe profiles result in a progression of magnetite levels downgradient within the column. Declining microbial reduction over time results in lower Fe(II) concentrations and a subsequent shift in magnetite precipitation mechanisms from nucleation to crystal growth. While the initial precipitation rate of goethite exceeds that of magnetite, continued growth is inhibited by magnetite formation, potentially a result of lower Fe(III) activity. Conversely, the presence of lower initial Fe(II) concentrations followed by higher concentrations promotes goethite accumulation and inhibits magnetite precipitation even when Fe(II) concentrations later increase, thus revealing the importance of both the rate of Fe(II) generation and flow-induced Fe(II) profiles. As such, the operating secondary mineralization pathways following reductive dissolution of ferrihydrite at a given pH are governed principally by flow-regulated Fe(II) concentration, which drives mineral precipitation kinetics and selection of competing mineral pathways.     

Interrelations between socio-economic development and environmental quality: a simulation integrating system dynamics models with GIS

System dynamics (SD) theory has long been deployed in modeling complex non-linear interrelationships but, so far it has not been common to do the kind of modeling in support of bringing environmental sustainability policies to practice. This is largely because the challenge of including spatial data has not yet been well met. Potential for adoption of SD and GIS methods in combination is exemplified with the results of a decision-support exercise designed for simulation and prediction of the dynamic inter-relationships between socio-economic development and environmental quality for the “Wen, Pi, Du” county in Sichuan province, southwestern China.     

Seismic activity related to the 1991 eruption of Colima Volcano,Mexico

Ten years after the last effusive eruption and at least 15 years of seismic quiescence, volcanic seismic activity started at Colima volcano on 14 February 1991, with a seismic crisis which reached counts of more than 100 per day and showed a diversity of earthquake types. Four other distinct seismic crises followed, before a mild effusive eruption in April 1991. The second crisis preceded the extrusion of an andesitic scoriaceous lava lobe, first reported on 1 March; during this crisis an interesting temporary concentration of seismic foci below the crater was observed shortly before the extrusion was detected. The third crisis was constituted by shallow seismicity, featuring possible mild degassing explosion-induced activity in the form of hiccups (episodes of simple wavelets that repeat with diminishing amplitude), and accompanied by increased fumarolic activity. The growth of the new lava dome was accompanied by changing seismicity. On 16 April during the fifth crisis which consisted of some relatively large, shallow, volcanic earthquakes and numerous avalanches of older dome material, part of the newly extruded dome, which had grown towards the edge of the old dome, collapsed, producing the largest avalanches and ash flows. Afterwards, block lava began to flow slowly along the SW flank of the volcano, generating frequent small incandescent avalanches. The seismicity associated with the stages of this eruptive activity shows some interesting features: most earthquake foci were located north of the summit, some of them relatively deep (7–11 km below the summit level), underneath the saddle between the Colima and the older Nevado volcanoes. An apparently seismic quiet region appears between 4 and 7 km below the summit level. In June, harmonic tremors were detected for the first time, but no changes in the eruptive activity could be correlated with them. After June, the seismicity decreasing trend was established, and the effusive activity stopped on September 1991.     

ASPI experiment: measurements of fields and waves on board the INTERBALL-1 spacecraft

The plasma-wave experiment ASPI (analysis of spectra of plasma waves and instabilities) on board the INTERBALL spacecraft is a combined wave diagnostics experiment. It performs measurements of the DC and AC magnetic field vector by flux-gate and searchcoil sensors, the DC and AC electric field vector by Langmuir double probes and the plasma current by Langmuir split probe. Preliminary data analysis shows the low noise levels of the sensors and the compatibility of new data with the results of previous missions. During several months of in-orbit operation a rich collection of data was acquired, examples of which at the magnetopause and plasma sheet are presented in second part of the paper.