Using more than three million Landsat satellite images, this research developed the first global impervious surface area (GISA) dataset from 1972 to 2019. Based on 120,777 independent and random reference sites from 270 cities all over the world, the omission error, commission error, and F-score of GISA are 5.16%, 0.82%, and 0.954, respectively. Compared to the existing global datasets, the merits of GISA include: (1) It provided the global ISA maps before the year of 1985, and showed the longest time span (1972–2019) and the highest accuracy (in terms of a large number of randomly selected and third-party validation sample sets); (2) it presented a new global ISA mapping method including a semi-automatic global sample collection, a locally adaptive classification strategy, and a spatio-temporal post-processing procedure; and (3) it extracted ISA from the whole global land area (not from an urban mask) and hence reduced the underestimation. Moreover, on the basis of GISA, the long time series global urban expansion pattern (GUEP) has been calculated for the first time, and the pattern of continents and representative countries were analyzed. The two new datasets (GISA and GUEP) produced in this study can contribute to further understanding on the human’s utilization and reformation to nature during the past half century, and can be freely download from http://irsip.whu.edu.cn/resources/dataweb.php.
Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO2, Al2O3, and SiO2 are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts. 相似文献
Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na+ was considered to enhance the crystallization of zeolite, while F− favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na2SiO4 and Al(OH)3 changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible. 相似文献