招平断裂带留仙庄空白区成矿远景预测

留仙庄空白区位于招(远)-平(度)断裂带中南段,道北庄子金矿东侧。招平带中南段已发现大、中型金矿3处,由南向北依次为夏甸、姜家窑、道北庄子金矿。通过收集分析已知金矿床最新矿床地质特征及成矿规律,总结招平断裂带中南段矿体控矿围岩、控矿构造、矿体赋存的基本规律,对留仙庄空白区进行远景预测,认为该区找矿潜力巨大。     

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

Involvement of cyclic electron flow in irradiance stress responding and its potential regulation of the mechanisms in <Emphasis Type="Italic">Pyropia yezoensis</Emphasis>

Pyropia yezoensis, belongs to the genus of Porphyra before 2011, inhabit on intertidal zone rocks where irradiation changes dramatically, implying that the seaweed has gained certain mechanisms to survive a harsh environment. Based on the photosynthetic parameters with or without the inhibitors determined by a Dual-PAM-100 apparatus, we investigated the photosynthetic performance and the changes in electron flow that occurred during the algae were stressed with different light intensities previously. When the irradiation saturation was approaching, the CEF around PS I became crucial since the addition of inhibitors usually led to an increase in non-photochemical quenching. The inhibitor experiments showed that there were at least three different CEF pathways in Py. yezoensis and these pathways compensated each other. In addition to maintaining a proper ratio of ATP/NAD(P)H to support efficient photosynthesis, the potential roles of CEF might also include the regulation of different photoprotective mechanisms in Py. yezoensis. Under the regulation of CEF, chlororespiration is thought to transport electrons from the reduced plastoquinone (PQ) pool to oxygen in order to mitigate the reduction in the electron transfer chain. When irradiation was up to the high-grade stress conditions, the relative value of CEF began to decrease, which implied that the NADP⁺ pool or PQ⁺ pool was very small and that the electrons were transferred from reduced PS I to oxygen. The scavenging enzymes might be activated and the water-water cycle probably became an effective means of removing the active oxygen produced by the irradiation stressed Py. yezoensis. We believe that the different mechanisms could make up the photoprotective network to allow Py. yezoensis for survival in a highly variable light stress habitat, which may enlighten scientists in future studies on irradiance stress in other algae species.     

四川西昌盆地白垩纪恐龙足迹群的新发现

四川西昌盆地白垩系小坝组尚未发现骨骼化石记录,其白垩系恐龙动物群的信息全赖于足迹化石。2017年,在喜德县洛甘发现小坝组迄今最大型的恐龙足迹群。该足迹点保存了大量的兽脚类足迹。足迹保存条件较差,但具备了基本的形态学特征。总体来看,兽脚类足迹具有尺寸较小(8~13cm),中等中趾前凹(0.5~0.6)和第Ⅱ趾和第Ⅳ趾间较宽趾间角(70°~100°)的特征;少量足迹保存了跖骨垫。初步分析认为,洛甘兽脚类足迹与四川盆地夹关组的兽脚类足迹Eubrontes和Grallator形态类型相似,为两地在白垩纪中期具有类似的恐龙动物群的观点提供了新的证据。该发现对于西昌盆地的古气候、古地理和地层对比都具有重要的意义,足迹详细分类还有待进一步研究。     

黔东松桃地区燕山期构造特征研究——以高地超大型锰矿床为例

黔东松桃地区构造格局主要是受到燕山运动影响形成。燕山早期,区内处于SEE—NWW向区域挤压收缩,形成了NNE—SSW向褶皱和断裂。下寒武统杷榔组—变马冲组地层和南华系下统大塘坡组地层作为两套滑脱层,在构造变形过程中起到滑脱作用,滑脱层内褶皱变形强烈,以大量紧闭、顶厚不协调褶皱为主要构造样式,而其上、下岩层则以断块或宽缓褶皱变形为主,以软弱层为界面,其上、下岩层发生逆冲滑脱作用,形成了区内隔槽式褶皱的构造样式。燕山晚期,区内处于NNE—SSW挤压为主,形成了区内NWW向小型褶皱和断裂,同时燕山晚期构造横跨叠加在早期变形之上,导致早期NNE向褶皱枢纽呈波状起伏,轴迹弯曲,部分地区形成了构造穹窿和构造盆地,部分早期断层呈左行走滑性质。在燕山早、晚两期构造作用下,高地矿区含锰岩系作为软弱滑脱层,向猴子坳向斜的核部进行滑脱聚集,使其在向斜的核部富集,翼部相对减薄。同时,由于犁式正断层的存在,也影响了锰矿层的保存与破坏。     

河西走廊疏勒河流域水资源管理问题分析

从水资源管理体制、配置程序、市场化管理等方面探讨了河西走廊疏勒河流域水资源管理及存在的问题。目前流域已建成较健全的用水者协会体系,水价和水权在不断调整以适应水资源管理的需求。其管理存在以下问题：受地方行政、企业等多方权力博弈的影响,地表水和地下水处于双线管理状态,未能实现流域水资源的全面统一管理;用水者协会的职能未得到充分发挥,公众参与水资源管理不积极;流域内水价、水权制度不完善。建议如下：应在甘肃省水利厅和酒泉市政府之间形成协调机制,以协调各相关方的权益,完善流域管理局和地方政府统一协调的水资源管理体系,实现流域水资源的集成管理;加强流域机构立法,实现流域水资源的统一管理与调配;将协会的职责和义务融入到村委会的职务中,并完善水价制度,建立水权交易市场,以调动公众的自我管理和实现水资源的高效利用。     

黄河口清水沟河道的冲淤过程与模拟

为揭示黄河口清水沟河道长时段的冲淤演变规律并建立其冲淤计算方法,分析了清水沟1976—2015年的时空冲淤演变过程,采用河床演变的滞后响应模型,考虑河口来水来沙及河道延伸与蚀退的影响,建立了清水沟累计冲淤量的计算方法。结果表明:1976—1980年改道初期清水沟改道点上游先冲后淤,改道点下游淤滩塑槽,淤积量随着下游河道展宽而增加,1980年后改道点上、下游河道冲淤过程趋于一致;受水沙条件等因素影响,1980—1986年清水沟主槽冲刷展宽,之后主槽淤积萎缩;1996年清八改汊和2002年小浪底水库"调水调沙"原型试验以来,河道转淤为冲,2002年后河道冲刷速率随时间指数衰减;河床演变的滞后响应模型可计算清水沟长时段的冲淤过程,该方法可为预测未来清水沟冲淤演变趋势提供科学参考。     

地震叠前反演方法预测页岩脆性指数在南川地区的应用

页岩气的有效开发依赖水平井的压裂效果,而页岩脆性是影响页岩压裂的关键因素。通过对比分析现有的3种脆性指数计算方法,即矿物脆性指数计算法、岩石力学脆性指数计算法、基于多元回归脆性指数计算法,优选基于多元回归的脆性指数计算法计算五峰—龙马溪组(简称龙马溪组)页岩储层脆性指数。以四川盆地东部南川地区龙马溪组海相页岩气为例,利用南川地区三维地震资料叠前反演方法,获取多元回归脆性指数计算方程所需的参数,预测页岩脆性指数。结果表明,在已有钻井矿物脆性指标约束下,叠前反演法计算的脆性指数平面预测效果较好,且与实际压裂数据具有较好的一致性,能够满足南川地区页岩气勘探开发的需要。