湖南毛易矿区及外围构造分带分段特征

毛易矿区位于湖南长邵断坳北段,属于涟源坳陷中部隔挡式褶皱带,区内逆冲推覆构造较为发育。通过野外观测及资料整理,分析了研究区构造几何形态,得出矿区及其外围构造具有明显分带分段特征的结论:以向斜为主体,向斜两翼发育逆冲推覆构造,自北向南可分为北段、中段、南段;根据褶皱展布特征,自西向东可分为西带,中带和东带。研究认为,西带构造变形强于东带,研究区构造演化为共轭逆冲断层模式,受后期构造影响,煤系不均匀分布于西带和东带,其中北段东带与南段东带逆冲构造下伏地层是有利的找煤区域。     

Zero-valent iron/persulfate(Fe0/PS) oxidation acetaminophen in water

Zero-valent iron (Fe⁰), as an alternative iron source, was evaluated to activate persulfate (PS) to degrade acetaminophen (APAP), a representative pharmaceutically active compound in water. Effects of key factors in the so-called Fe⁰/PS process, including Fe⁰ dosage, initial pH, temperatures and chelating agents, were studied. Under all the conditions tested, the APAP degradation followed a pseudo-first-order kinetics pattern. The degradation efficiency of APAP was highest when the Fe⁰ to PS molar ratio increased to 1:1, and the degradation rate constant and removal were 23.19 × 10^?3 min^?1 and 93.19 %, respectively. Comparing with Fe²⁺, Fe⁰ served as an alternative iron source that can gradually release Fe²⁺ into water, thereby consistently activating PS to produce sulfate radicals. The Fe⁰/PS system was effective in a broader pH range from 3 to 8.5. Heat could facilitate production of sulfate radicals and enhance the APAP degradation in the Fe⁰/PS system. High reaction temperature also improved the Fe²⁺/PS oxidation of APAP. Finally, sodium citrate (a chelating agent) at an appropriate concentration could improve the APAP degradation rate in the Fe²⁺/PS and Fe⁰/PS system. The optimal molar ratio of Fe⁰ to citrate depended on solution pH. Our results demonstrated that Fe⁰ was an alternative iron source to activate PS to degrade APAP in water.     

Landslide susceptibility mapping based on GIS and information value model for the Chencang District of Baoji,China

The main objective of this study was to apply a statistical (information value) model using geographic information system (GIS) to the Chencang District of Baoji, China. Landslide locations within the study area were identified using reports and aerial photographs, and a field survey. A total of 120 landslides were mapped, of which 84 (70 %) were randomly selected for building the landslide susceptibility model. The remaining 36 (30 %) were used for model validation. We considered a total of 10 potential factors that predispose an area to a landslide for the landslide susceptibility mapping. These included slope degree, altitude, slope aspect, plan curvature, geomorphology, distance from faults, lithology, land use, mean annual rainfall, and peak ground acceleration. Following an analysis of these factors, a landslide susceptibility map was produced using the information value model with GIS. The resulting landslide susceptibility index was divided into five classes (very high, high, moderate, low, and very low) using the natural breaks method. The corresponding distribution area percentages were 29.22, 25.14, 15.66, 15.60, and 14.38 %, respectively. Finally, landslide locations were used to validate the results of the landslide susceptibility map using areas under the curve (AUC). The AUC plot showed that the susceptibility map had a success rate of 81.79 % and a prediction accuracy of 82.95 %. Based on the results of the AUC evaluation, the landslide susceptibility map produced using the information value model exhibited good performance.     

Paragenesis and geochemistry of ore minerals in the epizonal gold deposits of the Yangshan gold belt,West Qinling,China

Six epizonal gold deposits in the 30-km-long Yangshan gold belt, Gansu Province are estimated to contain more than 300 t of gold at an average grade of 4.76 g/t and thus define one of China's largest gold resources. Detailed paragenetic studies have recognized five stages of sulfide mineral precipitation in the deposits of the belt. Syngenetic/diagenetic pyrite (Py₀) has a framboidal or colloform texture and is disseminated in the metasedimentary host rocks. Early hydrothermal pyrite (Py₁) in quartz veins is disseminated in metasedimentary rocks and dikes and also occurs as semi-massive pyrite aggregates or bedding-parallel pyrite bands in phyllite. The main ore stage pyrite (Py₂) commonly overgrows Py₁ and is typically associated with main ore stage arsenopyrite (Apy₂). Late ore stage pyrite (Py₃), arsenopyrite (Apy₃), and stibnite occur in quartz ± calcite veins or are disseminated in country rocks. Post-ore stage pyrite (Py₄) occurs in quartz ± calcite veins that cut all earlier formed mineralization. Electron probe microanalyses and laser ablation-inductively coupled plasma mass spectrometry analyses reveal that different generations of sulfides have characteristic of major and trace element patterns, which can be used as a proxy for the distinct hydrothermal events. Syngenetic/diagenetic pyrite has high concentrations of As, Au, Bi, Co, Cu, Mn, Ni, Pb, Sb, and Zn. The Py₀ also retains a sedimentary Co/Ni ratio, which is distinct from hydrothermal ore-related pyrite. Early hydrothermal Py₁ has high contents of Ag, As, Au, Bi, Cu, Fe, Sb, and V, and it reflects elevated levels of these elements in the earliest mineralizing metamorphic fluids. The main ore stage Py₂ has a very high content of As (median value of 2.96 wt%) and Au (median value of 47.5 ppm) and slightly elevated Cu, but relatively low values for other trace elements. Arsenic in the main ore stage Py₂ occurs in solid solution. Late ore stage Py₃, formed coevally with stibnite, contains relatively high As (median value of 1.44 wt%), Au, Fe, Mn, Mo, Sb, and Zn and low Bi, Co, Ni, and Pb. The main ore stage Apy₂, compared to late ore stage arsenopyrite, is relatively enriched in As, whereas the later Apy₃ has high concentrations of S, Fe, and Sb, which is consistent with element patterns in associated main and late ore stage pyrite generations. Compared with pyrite from other stages, the post-ore stage Py₄ has relatively low concentrations of Fe and S, whereas As remains elevated (2.05～3.20 wt%), which could be interpreted by the substitution of As^? for S in the pyrite structure. These results suggest that syngenetic/diagenetic pyrite is the main metal source for the Yangshan gold deposits where such pyrite was metamorphosed at depth below presently exposed levels. The ore-forming elements were concentrated into the hydrothermal fluids during metamorphic devolatilization, and subsequently, during extensive fluid–rock interaction at shallower levels, these elements were precipitated via widespread sulfidation during the main ore stage.     

芦山地震同震和震后地表形变及重力变化的理论模拟

为了研究芦山地震的孕震过程和震源区的长期构造过程以及解释实测的震后形变和重力资料, 采用分层介质模型, 利用数值模拟的方法, 考虑区域流变系数, 计算了地震引起的地表同震、震后的形变和重力变化以及区域内部分GPS与重力连续观测台站的震后形变和重力变化的时间序列.结果表明: 芦山地震的地表同震形变显示出发震断层明显的逆冲特性; 粘弹性松弛效应引起的震后地表形变和重力变化比同震形变和重力变化的范围明显扩大, 但随着粘滞系数的增加, 变化量明显减小; 观测台站的震后变化时变曲线显示震后形变和重力变化在震后50 a间变化显著, 100 a后基本平缓, 趋于稳定; 模拟计算的GPS台站中除了MEIG台和MYAN台以外, 其余台站的震后观测必须考虑粘弹性松弛的影响.      

Health risk assessment for typical and abandoned chromium-contaminated sites

Chromium pollution were investigated by sampling the abandoned chromium contaminated sites in Chongqing. Its health risk was assessed following the procedures made by USEPA. The results showed that the most seriously polluted land was found at the former production area （G4） with average Cr（VI） concentration of 3369.2 mg kg-1 on the surface soil. The assessment indicated that there was high risk of non-carcinogens for children. The assessed risk of the first layer of office area （G1） for children, chromium slag transition （G2）, drainage pipeline chromium slag transition （G3） and production area （G4） for both children and adults were not acceptable （〉1.00× 106）. It was strongly suggested that the accessible measures of remediation should be taken for a portion of contaminated sites before the reuse of abandoned lands.     

广西国土空间格局演变特征与形成机理

国土空间格局演化与形成机理是人地系统交互关系研究的科学问题和国土空间规划的关键前提。采用地学图谱、标准差椭圆和空间自相关方法,分析2000—2018年广西国土空间格局演变特征,并运用地理探测器揭示其形成机理。结果表明：① 广西城镇空间加速挤占农业、生态空间形成了“一增双减”的面积变化特征,国土空间动态变化速度加快;② 广西国土空间相互转化频繁,转移轨迹多样性特征明显,农业空间与生态空间加速互换以及生态空间内部结构加快重组;③ 城镇空间与农业空间互竞主导了广西国土空间的迁移路径,城镇、农业空间存在“南高北低”和生态空间存在“北高南低”的集聚特征;④ 广西国土空间格局演变受自然地理与社会经济因素的共同作用影响,自然环境条件的限制作用减弱,社会经济发展水平驱动力增强,政策调控力度驱动作用深远。下一步可通过国土空间规划、调整产业布局和引导生产生活方式优化国土空间格局。     

基于网络视频的建设工程监管系统研究

探讨网络视频应用于建设工程监管领域的系统建设,介绍了系统框架、数据建设、功能设计和技术路线,以重庆市重点建设工程为例进行项目开发并在建委系统取得了试用,最后指出全过程、多传感、集成的体制性建设工程监管系统是未来趋势。     

Input data resolution‐induced uncertainty in watershed modelling

The temporal‐spatial resolution of input data‐induced uncertainty in a watershed‐based water quality model, Hydrologic Simulation Program‐FORTRAN (HSPF), is investigated in this study. The temporal resolution‐induced uncertainty is described using the coefficient of variation (CV). The CV is found to decrease with decreasing temporal resolution and follow a log‐normal relation with time interval for temperature data while it exhibits a power‐law relation for rainfall data. The temporal‐scale uncertainties in the temperature and rainfall data follow a general extreme value distribution and a Weibull distribution, respectively. The Nash‐Sutcliffe coefficient (NSC) is employed to represent the spatial resolution induced uncertainty. The spatial resolution uncertainty in the dissolved oxygen and nitrate‐nitrogen concentrations simulated using HSPF is observed to follow a general extreme value distribution and a log‐normal distribution, respectively. The probability density functions (PDF) provide new insights into the effect of temporal‐scale and spatial resolution of input data on uncertainties involved in watershed modelling and total maximum daily load calculations. This study exhibits non‐symmetric distributions of uncertainty in water quality modelling, which simplify weather and water quality monitoring and reducing the cost involved in flow and water quality monitoring. Copyright © 2011 John Wiley & Sons, Ltd.     

青藏高原500hpa暖性高压生成的热成风适应机制

本文利用热成风适应原理,采取分解分析法对青藏高原500hpa暖性高压的生成机制作了一些定性和定量的讨论。结果表明:在扰动的水平尺度大于热成风适应的特征尺度的条件下,当源地有明显的负值非热成风涡度出现时,流场将向温度场适应,而温度场由于高原的加热作用存在暖中心或暖脊,则适应的结果在高原大气500hpa形成暖性高压,并伴随高层辐合,低层辐散及下沉运动。