地裂缝场地施工降水对地表沉降和地层应力的影响研究

地裂缝是西安市典型的城市地质灾害，地下水位的变化是诱发地裂缝活动的重要因素。以西安地铁六号线暗挖段施工降水为研究背景，基于有限元数值模拟计算，分析了地裂缝场地施工降水引起的地表沉降规律和地层应力变化特征。计算结果表明:当地下水位下降时，地表沉降量上盘大于下盘，地裂缝带两侧地表存在差异沉降的现象，最大差异沉降量与地下水位下降深度近似呈直线关系；不同位置处地表的横向沉降呈现出"Z"形的变化特征，差异沉降区随地裂缝位置的变动而变化，且差异沉降量与横向地表位置近似呈二次函数曲线关系；地层竖向应力随着地下水位下降而增大，地裂缝位置处地层应力存在突变现象，上下盘应力影响区与地层深度近似呈三次函数曲线关系；基于分层总和法计算了地下水位下降时地表沉降量的解析解，并与数值模拟结果进行对比，发现两种方法计算结果基本一致，得到了计算地表最大沉降量的经验公式。研究结果可为地裂缝场地地铁隧道及其他地下工程安全施工提供科学指导。      

The δ60/58Ni Values of Twenty‐Six Selected Geological Reference Materials

The high‐precision δ^60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ^60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ^60/58Ni _{NIST SRM 986} values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ^60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories.     

Results for Rarely Determined Elements in MPI-DING, USGS and NIST SRM Glasses Using Laser Ablation ICP-MS

New analytical results are reported for rarely determined elements Be, B, Ge, As, Mo, Rh, Pd, Ag, Cd, In, Sn, Sb, W, Re, Ir, Pt, Au, Tl and Bi in MPI‐DING and USGS (BCR‐2G, BHVO‐2G, BIR‐1G) silicate glasses and the NIST SRM 610‐614 synthetic soda‐lime glasses using 193 nm ArF excimer laser ablation and quadrupole ICP‐MS. The method used involved external calibration against GOR132‐G for Ir and NIST SRM 610 for other elements, internal standardisation using Ca, and ablation with a crater diameter of 160 μm and a pulsed laser repetition rate of 10 Hz. Small amounts of nitrogen (5 ml min^?1) were added to the central channel gas of the plasma to improve the limits of detection for most of these elements by a factor of 1.2–2.5 and to reduce the oxide interference level to 0.02% (ThO⁺/Th⁺). Under these conditions, the LODs for most of these rarely determined elements were within the range 0.1 to 10 ng g^?1. The operating conditions that were required to minimise ICP‐induced fractionation (U⁺/Th⁺≈ 1) in the mode without nitrogen were accompanied by a 50–60% reduction in sensitivity for elements such as Ca, Au and Pt. In contrast, ICP‐induced fractionation could be minimised (U⁺/Th⁺≈ 1) with no loss of analyte sensitivity in the nitrogen mode. Interferences of CuAr⁺, ZnAr⁺, Cd⁺, Pb²⁺ and Sn⁺ on Pd⁺, Rh⁺, Cd⁺ and In⁺ were corrected. Oxide interferences were not considered due to their lower production rate. Analytical precision, as given by one relative standard deviation (% RSD) was less than 15% for most of the elements present at concentrations greater than 0.1 μg g^?1. A significant negative correlation was found between logarithmic concentration and logarithmic RSD, with a correlation coefficient of ?0.76. This trend indicates that possible chemical heterogeneities for most of these elements are smaller than the analytical uncertainty. Our results for Be, B, Ge, Sb and W are generally in good agreement with their reference values. In contrast, other elements in many of the reference glasses have only information values, upper limits or even no values, which restrict any detailed evaluation of the accuracy of the determined values. However, concentrations from multiple isotopes of one element analysed in this study showed excellent agreement, which guarantee the quality of our data to a certain extent.     

In-situ sulfur isotope and trace element of pyrite constraints on the formation and evolution of the Nibao Carlin-type gold deposit in SW China

Acta Geochimica - The fault-controlled Nibao Carlin-type gold deposit, together with the strata-bound Shuiyindong deposit, comprise a significant amount of the disseminated gold deposits in...     

基于回归分析法的地下水位预测研究

彭楼灌区位于山东省聊城市西南部,为引黄灌溉灌区。2002年彭楼灌区复灌以来,有效缓解当地水资源紧缺的矛盾。为研究彭楼灌区引黄水量对地下水位的影响,采用回归分析法,具体分析地下水位变差与引黄水量、干旱指数的回归关系,建立回归方程。通过实例分析检验,建立的回归方程可作为进行彭楼灌区地下水位预测的一种方法。     

Geology and Metallogenesis of the Sawayaerdun Gold Deposit in the Southwestern Tianshan Mountains, Xinjiang, China

The Sawayaerdun gold deposit, located in Wuqia County, Southwest Tianshan, China, occurs in Upper Silurian and Lower Devonian low‐grade metamorphic carbonaceous turbidites. The orebodies are controlled by a series of NE‐NNE‐trending, brittle–ductile shear zones. Twenty‐four gold mineralized zones have been recognized in the Sawayaerdun ore deposit. Among these, the up to 4‐km‐long and 200‐m wide No. IV mineralized zone is economically the most important. The average gold grade is 1–6 g/t. Gold reserves of the Sawayaerdun deposit have been identified at approximately 37 tonnes and an inferred resource of 123 tonnes. Hydrothermal alteration is characterized by silicification, pyritization, arsenopyritization, sericitization, carbonatization and chloritization. On the basis of field evidence and petrographic analysis, five stages of vein emplacement and hydrothermal mineralization can be distinguished: stage 1, early quartz stage, characterized by the occurrence of quartz veins; stage 2, arsenopyrite–pyrite–quartz stage, characterized by the formation of auriferous quartz veinlets and stockworks; stage 3, polymetallic sulfide quartz stage, characterized by the presence of auriferous polymetallic sulfide quartz veinlets and stockworks; stage 4, antimony–quartz stage, characterized by the formation of stibnite–jamesonite quartz veins; and stage 5, quartz–carbonate vein stage. Stages 2 and 3 represent the main gold mineralization, with stage 4 representing a major antimony mineralization episode in the Sawayaerdun deposit. Two types of fluid inclusion, namely H₂O–NaCl and H₂O–CO₂–NaCl types, have been recognized in quartz and calcite. Aqueous inclusions show a wide range of homogenization temperatures from 125 to 340°C, and can be correlated with the mineralization stage during which the inclusions formed. Similarly, salinities and densities of these fluids range for each stage of mineralization from 2.57 to 22 equivalent wt% NaCl and 0.76 to 1.05 g/cm³, respectively. The ore‐forming fluids thus are representative of a medium‐ to low‐temperature, low‐ to medium‐salinity H₂O–NaCl–CO₂–CH₄–N₂ system. The δ³⁴S_CDT values of sulfides associated with mineralization fall into a narrow range of ?3.0 to +2.6‰ with a mean of +0.1‰. The δ¹³C_PDB values of dolomite and siderite from the Sawayaerdun gold deposit range from ?5.4 to ?0.6‰, possibly reflecting derivation of the carbonate carbon from a mixed magmatic/sedimentary source. Changes in physico‐chemical conditions and composition of the hydrothermal fluids, water–rock exchange and immiscibility of hydrothermal fluids are inferred to have played important roles in the ore‐forming process of the Sawayaerdun gold–antimony deposit.     

厄立特里亚Augaro金矿床碳氢氧硫同位素特征及其成因意义

厄立特里亚Augaro金矿床产于努比亚地盾新元古代变质火山岩中,矿体主要赋存于片理化安山岩内,受北北东向断裂与近东西向次级断裂控制。对矿床主要含金石英脉型矿石与蚀变岩型矿石进行碳氢氧硫同位素研究显示,成矿流体的δD_w-H2O范围为-68.7‰～-49.4‰,δ¹⁸O_w-H2O范围为-1.9‰～4.9‰,δ¹³C_V-PBD范围为-15.9‰～-10.9‰,石英脉型金矿石硫同位素组成以较小的正值为特征,变化范围为0.18‰～0.63‰,而蚀变岩型金矿石硫同位素组成偏低,以较大负值为特征,变化范围为-7.07‰～-6.86‰,表明Augaro金矿床成矿流体主要来源于变质热液,伴有岩浆水与大气降水的混合,矿区地层与岩浆物质为金矿床的形成提供大量成矿物质。     

Distribution Prediction of Middle-deep Lacustrine Source Rocks in Eocene Wenchang Formation in the Kaiping Sag,Pearl Mouth Basin

Oil and gas shows are rich in drilling wells in Kaiping sag,however,large oilfield was still not found in this area.For a long time,it is thought that source rocks were developed in the middle-deep lacustrine facies in the Eocene Wenchang Formation,while there is no source rocks that in middle-deep lacustrine facies have been found in well.Thickness of Wenchang Formation is big and reservoirs with good properties could be found in this formation.Distribution and scale of source rock are significant for further direction of petroleum exploration.Distribution characterization of middle-deep lacustrine facies is the base for source rock research.Based on the sedimentary background,fault activity rate,seismic response features,and seismic attributes were analyzed.No limited classification method and multi-attributes neural network deep learning method were used for predicting of source rock distribution in Wenchang Formation.It is found that during the deposition of lower Wenchang Formation,activity rate of main fault controlling the sub sag sedimentation was bigger than 100 m/Ma,which formed development background for middle-deep lacustrine facies.Compared with the seismic response of middle-deep lacustrine source rocks developed in Zhu I depression,those in Kaiping sag are characterized in low frequency and good continuity.Through RGB frequency decomposition,areas with low frequency are main distribution parts for middle-deep lacustrine facies.Dominant frequency,instantaneous frequency,and coherency attributes of seismic could be used in no limited classification method for further identification of middle-deep lacustrine facies.Based on the limitation of geology knowledge,multi-attributes of seismic were analyzed through neural network deep learning method.Distribution of middle-deep lacustrine facies in the fourth member of Wenchang Formation is oriented from west to east and is the largest.Square of the middle-deep lacustrine facies in that member is 154 km²and the volume is 50 km³.Achievements could be bases for hydrocarbon accumulation study and for exploration target optimization in Kaiping sag.     

南京河西地区地面沉降成因分析

为了查明南京河西地区地面沉降的成因,笔者等在系统研究水文地质与工程地质条件的基础上,研究了地面沉降的分布特征和发展规律,以及地面沉降与地下水位、软土分布及建筑荷载之间的关系,进而揭示了南京河西地区地面沉降的成因。研究结果表明：南京河西地区不开采地下水,地面沉降与软土层厚度和建筑荷载分布关系密切,地面沉降主要受建筑工程影响,即建筑荷载和深基坑降水的作用。     

Phosphorus biological cycle in the different Suaeda salsa marshes of the Yellow River estuary, China

Much uncertainty exists in the phosphorus (P) cycle in the marshes of the intertidal zone. This study explored the P cycling in the two Suaeda salsa marshes [middle S. salsa marsh (MSM) and low S. salsa marsh (LSM)] of the Yellow River estuary during April 2008 to November 2009. Results showed seasonal fluctuations and vertical distributions of P in different S. salsa marsh soils, and variations in P content in different parts of plants due to water and salinity status. The N/P ratios of the different S. salsa were 9.87 ± 1.23 and 15.73 ± 1.77, respectively, indicating that plant growth in MSM was limited by N, while that in LSM was limited by both N and P. The S. salsa litter in MSM released P to the environment throughout the year, while that in LSM immobilized P from the environment at all times. The P absorption coefficients of S. salsa in MSM and LSM were very low (0.0010 and 0.0001, respectively), while the biological cycle coefficients were high (0.739 and 0.812, respectively). The P turnovers among compartments of MSM and LSM showed that the uptake amounts of roots were 0.4275 and 0.0469 g m^?2 year^?1 and the values of aboveground parts were 1.1702 and 0.1833 g m^?2 year^?1, the re-translocation quantities from aboveground parts to roots were 0.8544 and 0.1452 g m^?2 year^?1, the translocation amounts from roots to soil were 0.0137 and 0.0012 g m^?2 year^?1, the translocation quantities from aboveground living bodies to litter were 0.3157 and 0.0381 g m^?2 year^?1, and the annual return quantities from litter to soil were less than 0.0626 and ?0.0728 g m^?2 year^?1 (minus represented immobilization), respectively. P was an important limiting factor in S. salsa marshes, especially in LSM. S. salsa was seemingly well adapted to the low-nutrient condition and the vulnerable habitat, and the nutrient enrichment due to the import of N and P from the Yellow River estuary would be a potential threat to the S. salsa marshes.