豫西南高庄金矿床Re-Os定年及S-Pb同位素和REE示踪

高庄金矿床是豫西南一处重要金矿,成矿时代、物质来源以及矿床成因类型尚不清楚。本文对高庄金矿石中载金矿物磁黄铁矿进行Re-Os测年,获得(137±2) Ma成矿年龄,表明金矿床为燕山晚期成矿。分别对载金矿物磁黄铁矿、容矿地层(二郎坪群火神庙组)和侵入岩体(堂坪岩体)进行了S、Pb和REE组成分析。矿石硫化物δ34SCDT值为-3.0‰～-1.5‰,平均值为-2.24‰,深源S特征明显,矿石S可能来源于容矿的二郎坪群火神庙组基性火山岩地层。矿石硫化物206Pb/204Pb、207Pb/204Pb、208Pb/204Pb的变化范围分别为17.106～17.505、15.469～15.602、37.835～38.194。堂坪岩体206Pb/204Pb、207Pb/204Pb、208Pb/204Pb的变化范围分别为18.244 3～19.238 2、15.594 8～15.693 5、38.504 2～39.616 3,二郎坪群火山岩206Pb/204Pb、207Pb/204Pb、208Pb/204Pb变化范围分别为18.176 8～18.669 2、15.607 1～15.801 9、38.375 9～39.080 9。矿石铅同位素组成与地层和岩体的岩石铅组成相近,表明岩体和地层都提供了成矿物质。矿石与二郎坪群火神庙组地层的REE球粒陨石标准化配分曲线都为平坦型。可见,豫西南高庄金矿形成于秦岭碰撞造山之后的燕山晚期陆内构造岩浆热液过程,成矿物质主要来源于矿体周围火山岩地层。     

小庄矿井采煤对地下水的影响及保水采煤措施

针对煤炭开采易造成地表塌陷及含水层破坏等问题,采用类比法计算了彬长矿区规划新建的矿井——小庄矿井开采导水裂缝带高度,在此基础上分析了采煤对地下水的影响,并提出保水采煤的措施。经计算,采用分层开采时产生的导水裂隙带最大高度为147.84 m,在三盘区将导通安定组隔水层,造成宜君组、洛河组承压含水层破坏,导通区域面积为0.773 6 km2。因此,在可能导通的区域应进行保水采煤以保证安定组隔水层的稳定,从而达到保护具有供水意义的含水层和保障矿井生产安全的双重目的。      

中国高速铁路网络的发展过程、格局及空间效应评价

高速铁路作为现代交通基础设施的重要组成部分,其建设产生时空收敛效果,并进一步对生产要素流动、城市空间扩张、区域空间结构重构产生重要影响。文章在分析中国高速铁路发展过程、模式的基础上,剖析了其空间格局特征及与区域人口和经济的耦合关系;同时,借助ArcGIS方法从空间服务水平、时空收敛效应和中心城市交通圈等角度,探讨高速铁路网络的空间效应。结果显示：高速铁路的空间扩展过程表现出独特的“核心―核心”至“核心―网络”模式,与城市群的空间分布具有较好的耦合性;高速铁路的空间格局与中国城市人口、工业分布表现基本一致,站点1 h范围内可覆盖全国50.07%的城镇人口、73.47%的GDP和98.17%的第二产业产值;中国高速铁路建设导致的时空收敛效果呈现出明显的廊道效应,中心城市枢纽地位得以强化,服务范围的拓展和生产要素的便捷流动为城市群的空间扩张和重构提供了条件。     

冻融循环对兰州黄土渗透性变化的影响

在季节冻土区, 周期性的冻结与融化持续改变着土体内部结构, 土的孔隙率与渗透性也随之产生相应的变化. 针对这一现象进行了原状黄土和重塑黄土的冻融循环试验和冻融循环后的渗透试验. 结果显示: 随着冻融循环作用的进行, 原状黄土与重塑黄土干密度的变化趋势都是先增大后减小, 然后趋于稳定. 由于渗透系数与干密度呈负线性关系, 所以随着冻融循环次数的增加, 原状黄土与重塑黄土的渗透系数都是先减小后增大, 最后在4×10^-4~6×10^-4 cm·s^-1之间趋于一个稳定值. 因为重塑黄土是扰动土, 土结构中的颗粒大小较为均匀, 而原状黄土的土结构中颗粒大小不均匀, 导致重塑黄土的渗透系数始终大于原状黄土.     

基于参数劣化的软硬相间顺层边坡稳定性研究

三峡库区侏罗系地层具有独特的软硬相间的岩性组合和结构特征,侏罗系砂泥岩软硬相间地层是该地区典型的易滑地层,是滑坡集中发育的地层之一,也是三峡库区滑坡防治工作中的重点区域。为深入研究软硬相间层状岩质边坡的稳定性,通过对理论概化模型的分析,构建了软硬相间顺层岩质边坡的参数劣化计算模型。考虑风化作用对岩体结构面抗剪强度参数劣化的影响,引入空间变异函数,提出软硬相间层状岩质边坡结构面抗剪强度参数劣化模型,导出软硬相间层状岩质边坡沿层面方向抗剪强度参数劣化的函数表达式,表征了分析点的风化影响厚度与其强度参数的一一对应关系,有利于边坡稳定性的定量分析。利用该函数表达式对沿层面方向岩体的强度参数进行劣化,利用劣化后的强度参数进行稳定性评价,得到分析点至坡面距离与该点稳定系数的对应关系曲线,并结合三峡库区边坡实例进行了验证分析,指出软硬相间层状岩质边坡岩体抗剪强度参数的劣化对其稳定性评价具有较大影响,单平面滑动的稳定分析中抗剪强度参数沿层面恒定分布的假定具有一定的局限性;若不考虑结构面抗剪强度参数的劣化,可能导致稳定性计算结果偏于不安全。     

Purification and characterization of iron-cofactored superoxide dismutase from Enteromorpha linza

A superoxide dismutase was purified from Enteromorpha linza using a simple and safe procedure, which comprised phosphate buffer extraction, ammonium sulphate precipitation, ion exchange chromatography on Q-sepharose column, and gel filtration chromatography on Superdex 200 10/300GL. The E. linza superoxide dismutase （E/SOD） was purified 103.6-fold, and a yield of 19.1% and a specific activity of 1 750 U/rag protein were obtained. The SDS-PAGE exhibited E/SOD a single band near 23 kDa and the gel filtration study showed E/SOD＇s molecular weight is near 46 kDa in nondenatured condition, indicating it＇s a homodimeric protein. E/SOD is an iron-cofactored superoxide dismutase （Fe-SOD） because it was inhibited by hydrogen peroxide, insensitive to potassium cyanide. The optimal temperature for its maximal enzyme activity was 35℃, and it still had 29.8% relative activity at 0℃, then E/SOD can be classified as a cold-adapted enzyme. E/SOD was stable when temperature was below 40℃ or the pH was within the range of 5 10. The first 11 N-terminal amino acids orE/SOD were ALELKAPPYEL, comparison of its N-terminal sequence with other Fe-SOD N-terminal sequences at the same position suggests it is possibly a chloroplastic Fe-SOD.     

Magnetic constraints on the spatial distribution of seismic activity

The lithospheric magnetic field (LMF) in China and its surrounding are calculated using the spherical harmonic coefficients given by the NGDC-720 model. The LMF comes from the magnetization of minerals in the crust and in the uppermost mantle. It may, therefore, provide unique insight into lithospheric tectonic processes and mechanisms. Here, we study the geomagnetic manifestation of active tectonic blocks, and find a close correlation between the LMF and seismicity. Many large faults are found to closely overlap with magnetic anomalies, or are distributed along the boundaries of magnetic anomalies. Earthquakes in these fault regions have occurred on the boundaries of magnetic anomalies, or in the transition zones between positive and negative anomalies. We analyze the components of the LMF, and the LMFs at different altitudes, finding that the vertical component, B _z at 200 km, is the most related to seismic activity. Relevant physical mechanisms are also discussed. We propose that the stress or viscosity differences caused by temperature variations, which manifest in the LMF, may be the predominant reason for the correlation between the LMF and seismic activity along large faults.     

人工回灌过程中的水-岩相互作用模拟

人工回灌过程中所发生的水-岩相互作用是影响回灌层位地下水环境质量的重要因素。采用室内实验和水文地球化学模拟等技术对人工回灌过程中的水-岩相互作用机理进行了分析。研究结果表明：受混合作用影响,随着回灌水比例的增加,混合水中TDS质量浓度降低,水化学类型由Cl·HCO₃-Na型水逐渐转变为HCO₃·Cl-Na·Ca型水;受水-岩作用影响,在同一混合比例条件下,随着水-岩作用的进行,混合水中TDS质量浓度升高,各主要离子质量浓度呈现升高的趋势,但只有回灌水比例占10%时,混合水TDS质量浓度才大于原始地下水（涨幅约5%）。实验介质溶解于水的离子中,Ca²⁺、Mg²⁺和HCO^-₃主要来源于碳酸盐矿物的溶解, Na⁺主要来自岩盐的溶解。在人工回灌过程中,发生的水-岩相互作用主要包括方解石、白云石、钾长石、岩盐、CO₂的溶解和伊利石的沉淀。其中:钾长石溶解量与伊利石沉淀量、碳酸盐矿物溶解量与CO₂溶解量的相关性较强,其相关系数分别为1.00和0.78（显著性水平为0.05）;硅酸盐矿物反应量和回灌水比例之间的相关系数为0.97（显著性水平为0.01）,相关性极强;而碳酸盐矿物反应量和回灌水比例之间的相关系数为0.52（显著性水平为0.01）,相关性较弱。上述相关性分析为确定人工回灌过程中的水-岩相互作用机理、地下水中主要离子组分的来源途径以及定量分析人工回灌对含水层介质的影响提供了依据。     

持久性有机污染物气——土界面交换研究进展

气-土界面交换对于持久性有机污染物(POPs)在区域和全球尺度上的传输迁移、重新分布和归趋具有重要意义。气-土界面交换所涉及的过程主要包括:干沉降、湿沉降和从土壤向大气的挥发。其中, 气态化合物的扩散交换是决定“源和汇”的关键过程。气态化合物在气-土界面的交换过程由大气和土壤之间的浓度梯度驱动, 土-气分配主要受化合物理化性质、温度和土壤有机质的影响。随着全球POPs禁用进程的加快, 中纬度污染地区的土壤逐渐成为低分子量化合物向大气排放的二次源;而对于高分子量的化合物来说, 土壤仍然是污染物的汇, 可以存储更多的污染物。气-土交换方向还受到温度的影响, 呈现出土壤夏季为源、冬季为汇的季节性变化特点。逸度模型是估算POPs 气-土交换通量的有力工具, 由通量大小可以定量判断源和汇的强度。此外, 还讨论了目前POPs气-土界面交换研究中存在着的一些不足, 并提出该领域未来可能的发展趋势。     

A potential stratotype for the regional lowermost stage of the continental Paleocene in China

Phanerozoic chronostratigraphic units can only be defined through their lower boundary stratotypes.The lowermost stage of the Paleocene of China,which mainly consists of terrestrial deposits,can only be defined through its lower boundary stratotype,i.e.the continental Cretaceous/Paleogene boundary stratotype.There is no section yet found which contains continuous terrestrial deposits and biostratigraphic records of the Cretaceous-Paleogene transition in Nanxiong,Guangdong and Jiayin,Heilongjiang,there is no evidence for establishing the continental stratotype of the Cretaceous/Paleogene boundary in either area.Therefore,both the"Shanghuan stage"and"Furaoan stage"are not good candidates for the lowermost stage of the Paleocene of China.From the viewpoint of charophytes,the outcrop section of the Dangyang,Hubei Province(Central China)contains the most continuous,abundant and diverse terrestrial biostratigraphic records of the Cretaceous-Paleogene transition,in particular the early Paleocene,known so far in the world.The biostratigraphic records of ostracods in the transition are also continuous,rich,and diverse.The Dangyang outcrop section is the only section known so far in China that is a possible candidate for a continental stratotype of the Cretaceous/Paleogene boundary in China and the section is the only potential section identified to date for establishing the regional lowermost stage of the Paleocene,Paleogene and Cenozoic in China or stratotype section for the stage.