5－（4－羧基苯偶氮）－8－（对甲苯磺酰氨基）－喹啉与金显色反应研究及应用

以８－氨基喹啉为母体，合成了新试剂５－（４－羧基苯偶氮）－８－（对甲苯磺酰氨基）－喹啉（ＣＰＴＳＱ），研究了它与Ａｕ的显色反应，在ＣＴＭＡＢ存在下，于ｐＨ１０～１３的ＮａＯＨ介质中，ＣＰＴＳＱ与Ａｕ形成２：１紫蓝色络合物，最大吸收峰位于６１０ｎｍ，摩尔吸光系数１．０×ｌ０５Ｌ·ｍｏｌ－１·ｃｍ－１，Ａｕ含量在０～１．２ｍｇ／Ｌ内符合比尔定律。方法选择性好，灵敏度高，操作简便，已用于金矿石样品中Ａｕ的测定，结果满意。     

时间剖面上小断层的计算机自动检测

煤田地震勘探一直探寻着对小断层的自动检测方法，因受各种因素的影响，至今尚无良策。本文介绍了多元地震参数的模式识别方法，并通过模型及实测资料成功地检测到１０ｍ以下小断层。     

华南西部晚二叠世碳同位素地层学研究

对黔桂地区７条晚二叠世碳酸盐岩型煤系剖面进行了碳酸盐岩碳氧同位素测定，发现晚二叠世吴家坪阶与长兴阶碳酸盐岩的δ１３Ｃ值有明显差异，前者δ１３Ｃ多大于３．０‰，后者多小于３．０‰，进一步对晚二叠世δ１３Ｃ的变化原因的分析表明，δ１３Ｃ的变化可能与晚古生代末期聚煤作用的减弱密切相关，后者造成自然界碳库中的１２Ｃ的富集，从而使得海水以及在其中沉淀出的碳酸盐岩中的δ１３Ｃ值降低。此外，植物光合作用从大气中吸收ＣＯ２的量也随陆地植被减少而减少，结果造成大气中的ＣＯ２的大量富集，从而进一步产生温室效应，制约生物界的发展。联系到这一阶段生物界的衰亡灭绝，可以认为温室效应是晚二叠世生物逐渐衰亡及晚二叠世末群体灭绝的主要原因之一。     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

黄土区人类活动影响下的 产汇流模拟研究

日益频繁的人类活动改变了流域下垫面条件,对流域产汇流产生很大的影响。本文以黄河中游典型支流岔巴沟为研究区域,提出利用基于DEM的分布式水文模拟技术,探讨流域人类活动过程中的产汇流模拟,避免了经验公式的概化和由此引起的局限。模拟的结果证实了该方法的可行性。采用网格滞蓄的方法可以在子网格上体现人类活动引起的下垫面的变化及其对产汇流的影响,反映各个时期的产汇流条件,对降雨做出合理响应。     

Using Geomechanical Method to Predict Tectonic Fractures in Low-Permeability Sandstone Reservoirs

Understanding and interpreting the timing, location, orientation, and intensity of natural fractures within a geological structure are commonly important to both exploration and production planning activities of low-porosity and low-permeability carbonate reservoirs. In this study, we explore the application of comprehensive geomechanical methods to quantitatively characterize the fracture parameters based on Strain Energy Density Theory, such as linear fracture density and volume fracture density. This study approach is based on the idea that energy generated by tectonic stress on brittle sandstone,which can be distinguished fracture surface energy, friction energy dissipation and residual strain energy and natural fractures can be interpreted or inferred from geomechanical-model-derived strains. For this analysis, we model an extension and compression compound fault block developed in a mechanically stratified sandstone and shale sequence because mechanics experimental data and drilling data exist that can be directly compared with model results.However, the results show that the approach and our study conclusion are independent of the specified structural geometry, which can correlate fracture parameters in different stages with different tectonic activities, and finally build and visualize fracture networks in sandstone. The presence or absence of filling minerals in fractures is shown to strongly control the destruction and transformation of low-permeability sandstone, and this control possesses crucial implications for interpreting fracture aperture and reservoir flow simulation.     

不同UV-B辐射时间对菹草表型可塑性的影响

菹草(Potamogeton crispus)衰亡的原因一直是水体生态修复的研究热点。已有的研究认为,强光照是促进菹草衰亡的关键因素。分别将菹草幼苗置于150μW/cm2剂量的中波紫外线(UV-B,波长为275~320 nm)辐射下,设置4种UV-B辐射持续时间处理,其每日的持续辐射时间分别设定为0 h(对照处理)、2 h、4 h和6 h,对照处理下的菹草幼苗不接受UV-B辐射,仅接受长波紫外线(UV-A)辐射和光合有效辐射,监测各处理下菹草幼苗的生长、形态状况、石芽形成和萌发等指标。研究结果表明,每日6 h的UV-B辐射,能促进菹草分枝,且能促进菹草衰亡;2 h和4 h的UV-B辐射,对菹草的影响较小,随着UV-B辐射时间的延长,菹草植株的株高、节间距和单株鲜质量明显下降,每日2 h的UV-B辐射,能促进植株叶面积的增加;每日延长UV-B辐射时间,可以促进石芽的形成,但形成的石芽随着变态率的增加,其长度增加、宽度减小,石芽质量减轻,下一个生长季的萌发率降低,萌发出二苗的比率降低,萌发苗的各项生长指标随着辐射剂量增加而逐渐降低。因此,在春末、夏初,随着太阳辐射时间的增加,阳光中累计的UV-B辐射剂量增加,这可能是促进菹草大批衰亡的重要原因。     

胶东金翅岭金矿构造控矿规律及找矿预测

金翅岭金矿是胶东招远北部的一个典型石英脉型金矿,构造是金矿最为重要的控矿因素。在前人资料的基础上,综合分析了矿区构造控矿特征,总结了构造控矿规律:矿脉分支复合,表现为NE向矿脉产生SN,NNE向次级矿脉,NNE向矿脉产生NE向次级矿脉;矿体厚度与金品位呈负相关,深部次级矿脉群在P4脉下盘出现;矿脉侧伏角和倾伏向变化处矿体富集,表现为SW向侧伏的P4矿脉,矿体富集于-240 m,侧伏角变大,同时倾伏向由SW向转变为NW向的部位。最后建立了平面和剖面P4矿脉的波形函数,并对深部进行了预测。     

余姚—丽水断裂带嵊州地区燕山期主要构造特征

余姚—丽水断裂带是浙东南地区活动时间长、延伸远、发育比较宽的一条NE—NNE展布的断裂构造带,在浙江嵊州地区上火山岩系磨石山群和下火山岩系永康群中构造形迹表现十分明显。余姚—丽水断裂带由一系列NE—NNE向控制区内白垩纪盆地形成与发展的正断层,以及NE—NNE走向、自北西向南东逆冲的叠瓦状断层和轴迹呈NE—NNE向的褶皱组成。通过对其构造活动特征及控制新老地层的时序关系研究,结合区域构造活动规律和时空演化关系等综合分析认为: 正断层形成时间较早,控制白垩纪盆地的形成和发展,与早白垩世岩石圈伸展减薄形成的拉张作用密切相关; 叠瓦状逆冲断层及斜歪褶皱、紧闭同斜褶皱等褶、断构造组合形成于晚白垩世之后,其动力学机制可能与古太平洋构造域向太平洋构造域的转换效应有关。研究成果为深入探讨浙东地区燕山期构造演化提供了新的素材和资料。