Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

一种数据网格的元数据分类管理机制研究

网格环境下数据发现和访问的关键问题是应用元数据管理和拷贝元数据管理，针对这一问题，提出了一种元数据分类管理机制。该机制定义了数据模型和应用元数据模式，采用了分类存储的方式对不同的元数据进行管理，并设计了一个基于向导的查询智能体。     

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。     

班公湖—怒江构造带西段三叠纪—侏罗纪构造—沉积演化

班公湖－怒江构造带西段在大地构造位置上处于特提斯构造域东端，横跨班公湖－怒江断裂带。三叠纪－株罗纪期间，其构造－沉积演化经历了大陆初始裂谷（T）、原洋裂谷（J1）、残余弧后盆地（J2－J3）阶段。初始裂谷阶段的拉张是呈南断北超的半地堑式由东向西进行的，逐渐形成地堑式原洋裂谷盆地。中晚侏罗世，南部新特提斯洋壳开始北各俯冲,产生的区域挤压应力使原洋裂谷逐渐封闭，裂谷盆地的小洋壳表现出以南向俯冲为主的双向式腑冲，同时伴生区域热沉降，盆地具残余弧后盆地的性质。该阶段,羌南地区发育碳酸盐岩为主的稳定陆缘沉积，冈度斯－念青唐古拉板片北部则形成广泛南超的近源碎屑沉积。     

中国北方农牧交错带与非洲萨哈尔地带全新世环境变迁的比较研究

中国北方农牧交错带和非洲萨哈尔带均为处在季风尾闾带的干旱向半湿润气候过渡的地带。通过对比分析 ,发现两个地带自然地理环境及其全新世以来的环境演变等具有很大程度的相似性 ;自全新世以来 ,两个地带均出现过几乎同步的 8个千年尺度的冷暖、干湿旋回 ;在近百年的干湿变化方面都有 10～ 2 0a变化周期 ;在少雨期和多雨期的转变过程中非洲萨哈尔带较中国北方农牧交错带提前 5a以上。这一超前信息的存在 ,为中国北方农牧交错带的气候预测提供了一个重要的前兆因素。     

喉癌CT分型和CD44V6表达的意义

目的 探讨喉癌的CT分型和转移相关因子CD44V6表达的意义。方法 对39例喉鳞癌行术前常规CT检查，其术后标本进行CD44V6的表达检测，与术前CT片作对照分析。结果39例喉鳞癌CT检查；声门型24例，声门上型14例，跨声门型1例，声门下型0例；T1－2级22例，T3－4级17例；淋巴结转移组13例，非转移组26例，CD44V6总的阳性表达率为61．5％，对各组均采用秩次检验分析，CD44V6在喉癌的CT的T分级和淋巴结分组中存在显著性差异（P＜0．01）。而部位分区无明显差异。结论 喉癌的CT分型中的T分级、淋巴结分组与CD44V6的阳性表达密切相关。     

基于模糊模式识别理论的土地利用合理性分析

以模糊模式识别理论为基础 ,采用模糊综合评判法 ,对土地利用结构合理性等级的模糊划分进行了初步的研究。在此基础上 ,以陕西榆林地区土地利用为例 ,通过计算土地利用结构合理性模糊等级序列及其隶属度 ,对该区土地利用结构的合理性进行了模糊等级评判。研究结果显示 :在土地利用研究中模糊综合评判是一种科学合理的研究方法。     

新时期我国区域经济地理学发展问题初探

我国新时期的区域经济地理学在取得全面发展的同时，在理论体系，研究方法和实践领域等方面还需要进一步的发展，文章根据学习和实践区域经济地理学的体会，初步提出基础理论和应用理论，思维方法和技术方法等方面发展见解，并指出区域创新系统和国际经济技术合作等学科应注意拓展的重要实践领域，最后提出我国区域经济地理学科发展的建议。