利用膨润土与工业废渣制轻质保温材料

本文介绍了利用膨润土、钙质造纸废渣制备轻质保温材料的研究,分析了膨润土在轻质保温材料制备中的作用,优选出制备轻质保温材料的配方和工艺。该材料的导热系数为０ ．１７１ Ｗ／ｍ·Ｋ,抗压强度约为９ ．３７ ｋｇ／ｃｍ２ ,容重为０ ．４９ ｇ／ｃｍ３ 。     

白钨矿的原位高压X射线衍射研究

使用金刚石对顶砧高压装置(DAC)和同步辐射光源,对天然白钨矿进行了原位高压能量色散X射线衍射(EDXD)研究,实验最高压力为16.0 GPa.在实验压力范围内观察到了一次白钨矿结构→钨锰铁矿结构的可逆相变:压力小于5.3 GPa时为白钨矿结构(I4_1/a),在5.3～12.3 GPa压力区间内为白钨矿结构与钨锰铁矿结构(P2/c)并存,大于12.3 GPa时完全相变为钨锰铁矿结构.从键长、配位数和配位多面体角度对白钨矿→钨锰铁矿结构的相变机制进行了解释.     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

高精度温度采集系统设计

针对高精度温度采集的需求,设计了一个以低功耗单片机MSP430F149作为核心处理器,以PT100铂电阻为传感器的温度采集系统。为了提高系统的复用性,采用精密电阻法,从硬件设计上消除了恒流源电流漂移以及A/D转换电路参考电压精度对温度测量数据的影响。重点描述了系统设计方案,详细说明了恒流源选择的原则、电流偏差的消除以及AD7792转换器的操作步骤。实验结果表明,温度测量精度优于0.1 ℃。对比试验表明,系统稳定性良好,已应用于业务产品中。     

Characteristics of dry-wet abrupt alternation events in the middle and lower reaches of the Yangtze River Basin and the relationship with ENSO

During recent decades, more frequent flood-drought alternations have been seen in China as a result of global climate change and intensive human activities, which have significant implications on water and food security. To better identify the characteristics of flood-drought alternations, we proposed a modified dry-wet abrupt alternation index (DWAAI) and applied the new method in the middle and lower reaches of the Yangtze River Basin (YRB-ML) to analyze the long-term spatio-temporal characteristics of dry-wet abrupt alternation (DWAA) events based on the daily precipitation observations at 75 rainfall stations in summer from 1960 to 2015. We found that the DWAA events have been spreading in the study area with higher frequency and intensity since 1960. In particular, the DWAA events mainly occurred in May and June in the northwest of the YRB-ML, including Hanjiang River Basin, the middle reaches of the YRB, north of Dongting Lake and northwest of Poyang Lake. In addition, we also analyzed the impact of El Niño Southern Oscillation (ENSO) on DWAA events in the YRB-ML. The results showed that around 41.04% of DWAA events occurred during the declining stages of La Niña or within the subsequent 8 months after La Niña, which implies that La Niña events could be predictive signals of DWAA events. Besides, significant negative correlations have been found between the modified DWAAI values of all the rainfall stations and the sea surface temperature anomalies in the Nino3.4 region within the 6 months prior to the DWAA events, particularly for the Poyang Lake watershed and the middle reaches of the YRB. This study has significant implications on the flood and drought control and water resources management in the YRB-ML under the challenge of future climate change.     

重庆城区浓雾的基本特征

统计分析沙坪坝1951～2002年间发生的浓雾事件，结合2001年12月重庆市雾的外场试验资料，探索重庆市主城区浓雾的基本特征。重庆主城区浓雾随年代演变有减缓趋势；主城区浓雾是自然雾与烟尘等的混合物，河谷及城市效应使雾更浓；城市中出现浓雾的大气边界层特征是在近地面层有逆温及增湿降温现象；高浓度气溶胶的净辐射效应阻碍白天混合层发展，使大气边界层趋于稳定，它是重庆连续几天有雾的原因之一；浓雾具有一定的湿沉降作用，能有限地清洁空气；有浓雾的天气条件下，建议降低污染物的排放总量，以避免严重大气污染事件发生。     

松花江、嫩江流域水资源形势分析

黑龙江省位于我国东北边疆地区,全省总面积 45.5万 km^2,属寒温带大陆季风区,年平均降水量 523.8mm,全省地表水资源量 655.83亿 m^3.人均占有水量 2074m^3,低于全国人均 2460m^3,居全国第 13位.亩均占有量 564m^3,低于全国亩均 1980m^3,居全国第 19位,可见水资源并不丰富.随着人口的增长,工农业不断发展,需水量逐年增加. 20世纪 80年代以来黑龙江气候变暖明显,蒸发量加大,连续干旱导致黑龙江水资源匮乏,松花江自 1998年以来连续 4、 5年枯水位,降到建国以来水位最低值,生活用水困难,航运中断,供需之间矛盾突出,水资源形势不容乐观.今后随着经济发展,工农业用水、河道内外用水与水资源之间矛盾会越来越突出.要求依法管好水、用好水,制定长运供需计划,提出水资源开发利用具体对策,以便供各级政府发展经济,规划蓝图作重要参考.文中水资源资料由文献和黑龙江省水文水资源勘测局提供.     

珠江流域1961-2007年气候变化及2011-2060年预估分析

 根据珠江流域1961-2007年气温、降水量观测资料和ECHAM5/MPI-OM模式2011-2060年预估结果,分析了流域过去47 a的气温和降水量变化,并预估未来50 a变化趋势。结果表明,在全球变暖的背景下,过去47 a温度呈上升趋势,约升高1.8℃。冬季增温最明显,夏季最弱。未来50 a流域温度仍呈上升趋势,A1B情景下升幅约1.9℃,并且年际变化增强。A2和B1两种排放情景下秋季升温最显著,冬季最弱,A1B排放情景与此相反。过去47 a秋季降水量呈减少趋势;春、夏、冬季和年降水量均呈增加趋势。未来50 a降水总体呈增加趋势,A1B排放情景降水增加最多,约为230 mm。A2、A1B和B1情景下降水季节分配未发生显著变化。年降水和冬季降水的年际变率增强,秋季减弱。