An integrated object-based image analysis and CA-Markov model approach for modeling land use/land cover trends in the Sarab plain

The present paper is an attempt to integrate a semi-automated object-based image analysis (OBIA) classification framework and a cellular automata-Markov model to study land use/land cover (LULC) changes. Land use maps for the Sarab plain in Iran for the years 2000, 2006, and 2014 were created from Landsat satellite data, by applying an OBIA classification using the normalized difference vegetation index, salinity index, moisture stress index, soil-adjusted vegetation index, and elevation and slope indicators. The classifications yielded overall accuracies of 91, 93, and 94% for 2000, 2006, and 2014, respectively. Finally, using the transition matrix, the spatial distribution of land use was simulated for 2020. The results of the study revealed that the number of orchards with irrigated agriculture and dry-farm agriculture in the Sarab plain is increasing, while the amount of bare land is decreasing. The results of this research are of great importance for regional authorities and decision makers in strategic land use planning.     

Evaluation of hydrogeochemical processes and groundwater quality for suitability of drinking and irrigation purposes: a case study in the Aosta Valley region,Italy

The present study aims to discuss the hydrogeochemical processes in the Aosta Valley region and assess the quality of its groundwater for suitability of drinking and irrigation purposes. One hundred twenty-two samples were collected from the Aosta Valley region in the years 2007 and 2008 (61 per year), and analysed for pH, electrical conductivity, total dissolved solids (TDS), total hardness, major cations and anions. The pH of the samples in both years indicated a near-neutral to alkaline nature of the groundwater. The cation and anion chemistry showed the general ionic abundance as: Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ and HCO₃ ^?>SO₄ ^2?>Cl^?>NO₃ ^?>F^? in both years. Ca²⁺-Mg²⁺-HCO₃ ^? and Ca²⁺-Mg²⁺-Cl^?-SO₄ ^2? were the dominant hydrogeochemical facies. The computed saturation indices demonstrated that the groundwater was supersaturated with respect to dolomite and calcite in both years. The groundwater chemistry of the study area was mainly controlled by the dissolution of carbonate, sulphate and silicate minerals, as well as ion exchange processes. A comparison of the groundwater quality in relation to drinking water standards showed that most of the water samples were suitable for drinking and domestic uses. The computed water quality index (WQI) values of the study area groundwater ranged from 24 to 84 in the year 2007 and from 22 to 82 in the year 2008, and all the location fell under the Excellent to Good category. Quality assessment for irrigation uses revealed that the groundwater was good to permissible quality for irrigation; however, locally higher salinity, residual sodium carbonate (RSC) and magnesium hazard (MH) restricted its suitability for irrigation at a few sites. These results will be useful in implementing future measures in groundwater resource management at regional and national level.     

Characterizing site response in the Attock Basin,Pakistan, using microtremor measurement analysis

The Attock Basin is situated close to the northwest of Pakistan. Recent seismic event of October 2015 (7.5M_w) near the Pakistan Afghanistan border has proved that the area of interest is seismically active and triggered a series of aftershocks of magnitude even greater than 6.5M_w. This seismic activity has posed danger to the future of the people and infrastructure especially to the northwestern part of the country. Therefore, site response analysis is essential for estimating local site conditions in response to seismic events. Ambient noise recordings were made at 50 sites within urban and semi-urban settlements in the Attock Basin to analyze the site response of the small but densely populated basin. At each of these sites, the fundamental frequency of the soft sediments (f ₀), the amplitude (A ₀) of corresponding H/V spectral ratios, the thickness of soft sediment (H) lying over competent lithology, and the soil vulnerability index (K _g) were studied. Results were correlated with sparsely available borehole data to enhance the credibility of the study conducted for microzonation and predicting the site response to earthquake seismicity in the Attock Basin. The soil vulnerability index was found to range from moderate to high. Results clearly showed that the study area exhibits low to moderate fundamental frequency with greater soft sediment thicknesses distributed throughout the study area. Moreover, higher impedance contrasts were found at most of the sites within the central part of the Attock Basin, thus reflecting a moderate to high susceptibility of damage in those regions in response to seismic events.     

Wrench tectonics of Abu Gharadig Basin,Western Desert,Egypt: a structural analysis for hydrocarbon prospects

Mapping based on the interpreted seismic data covering the Abu Gharadig Basin in the northern Western Desert has revealed that the deposition of the Upper Cretaceous succession was controlled by dextral wrench tectonics. This dextral shear accompanied NW movement of the African Plate relative to Laurasian Plate. Structural depth maps of the Cenomanian Bahariya Formation and the Turonian-Coniacian D and A members of Abu Roash Formation display a clear NE-SW anticline dissected by NW-SE normal faults. This anticline represents one of the en echelon folds characterizing the wrench compressional component. The interpreted normal faults reflect the extensional T-fractures associated with the wrenching tectonics. The interaction between the aforementioned NE-SW anticline with the NW-SE extensional faults further confirms the effect of the Upper Cretaceous dextral wrench tectonic. However, the influence of this wrench tectonics was gradually diminishing from the Cenomanian up to the Coniacian times. The NW-SE compressional stress of the dextral wrench compressional component during the Cenomanian up to Coniacian age was greater in NW direction than the SE direction. Three mapped structural closures which are predicted to be potential hydrocarbon traps belonging to the Bahariya Formation and Abu Roash D Member, and are recommended to be drilled in the study area, with potential reservoirs. The regularity of the en echelon array of both anticlines and normal faults within the wrench zones suggests additional closures may be located elsewhere beside the study area.     

Risk assessment of metals from groundwater in northeast Rajasthan

In Shear strength reduction (SSR) technique, the factor of safety (FOS) is defined as the ratio of the material’s actual shear strength to the minimum shear strength required to prevent failure. Failure surface is found automatically through the zones within the material, where applied shear stresses cross the shear strength of the material. In this paper, a review of the technique is discussed in reference to FLAC. A brief background of the approach together with detailed procedure is presented.An attempt is made to exhibit the shear strength dependency of the strain. As stability of the slope is a function of the shear strength, the development of failure strain reflects the potential failure zone of slope. The shear strain developed in the slope increases with reduction in the shear strength and is reflected in the analysis. The concept of failure ratio (R_f) is incorporated in shear strength reduction technique and is demonstrated. Relationships between the critical shear strength reduction ratio and the safety factor are examined.     

Mid-Miocene (post 12 Ma) displacement along the central Karakoram fault zone in the Nubra Valley,Ladakh, India from spot LA-ICPMS U/Pb zircon ages of granites

The Karakoram fault zone is a prominent right lateral fault that connects the frontal thrust of the North Pamir with the Indus suture zone near Mount Kailas. Its nature and age of initiation is controversial. In the Nubra valley, Ladakh, India, a Karakoram range granite is thrust over Cretaceous magmatic arc rocks and this thrust is cut by a western strand of the Karakoram fault zone. Three different lithologies from this granite gave weighted mean zircon U/Pb ages of 12.92±0.77 Ma, 12.41±0.43 Ma, and 11.72±0.31 Ma. The ages indicate a relatively short intrusive history of about 1 Ma for the phases: the geochemistry is practically identical to the Pangong leucogranites in the same tectonic block. The Karakoram fault zone in this area is thus less than ~12 Ma old which supports a post middle Miocene (Serravallian) age of Karakoram fault initiation in this area.     

Assessment of uranium in correlation with physico-chemical properties of drinking water of Northern Rajasthan

In the present study, analysis of 238U concentration in 40 drinking water samples collected from different locations of Jodhpur, Nagaur, Bikaner and Jhunjhunu districts of Rajasthan, India has been carried out by using high resolution inductively coupled plasma mass spectroscopy (HR-ICP-MS) technique. The water samples were taken from hand pumps and tube wells having depths ranging from 50 to 800 feet. The measured uranium concentration lies in the range from 0.89 to 166.89 μg l^-1 with the mean value of 31.72 μg l^-1. The measured uranium content in twelve water samples was found to be higher than the safe limit of 30 μg l^-1 as recommended by World Health Organization (WHO, 2011) and US Environmental Protection Agency (USEPA, 2011). Radiological risk calculated in the form of annual effective dose estimated from annual uranium intake ranges from 0.66 to 138.63 μSv y^-1 with the mean value of 26.28 μSv y^-1. The annual effective dose in two drinking water samples was found to be greater than WHO (2004) recommended level of 100 μSv y^-1. Chemical risk calculated in the form of lifetime average daily dose (LAAD) estimated from the water samples varies from 0.02 to 4.57 μg kg^-1 d^-1 with the mean value of 0.87 μg kg^-1 d^-1. The lifetime average daily dose (LAAD) of ten drinking water samples was found to be greater than WHO (2011) recommended level of 1 μg kg^-1 d^-1. The corresponding values of hazard quotient of 48% water samples were found to be greater than unity.A good positive correlation of uranium concentration with total dissolved solids (TDS) and conductance has been observed. However no correlation of uranium concentration with pH was observed. The results revels that uranium concentration in drinking water samples of the study area can cause radiological and chemical threat to the inhabitants.     

Stability assessment of slide zones in Lesser Himalayan part of Yamunotri pilgrimage route,Uttarakhand, India

The present study deals with the slope stability analysis and geotechnical assessment of a part of pilgrimage route to one of the holy shrines of India, i.e. Yamunotri. The route also embraces a proposed site for 204 m high concrete gravity dam across River Yamuna near Lakhwar village with the aim of generation of 300 MW power. Several slide zones were identified and based on the discontinuity orientation, structural features and debris materials, they are recognised as planar, wedge or circular failure types. The morphological dimensions, structural data, orientations and geotechnical parameters of circular failure slides within weathered quartzites, phyllites and shales were evaluated by extensive field work and by laboratory tests for their stability analysis. Internal mechanisms, cohesion and angle of internal friction that resist shear stress in slope materials, obtained from direct shear test are showing minor variation due to relatively consistent grain size distribution and mineralogical composition. General slope is about 40°–43° with sparse vegetation. Materials in and around slide zones are sands with appreciable amount of fines falling in SP–SM category as per Unified Soil Classification System (USCS), except Niste B slide which has clean sands lying in SP group. Factor of safety, computed by requisite parameters of strength, soil and slope properties in circular failure charts, varies from 1.02 to 1.23 in dry conditions while it reduces below unity with increasing saturation, representing stable conditions in dry conditions but with seepage and saturation along the cracks and discontinuities during rainfall make them unstable. Presence of steep slopes, proximity to stream channels and significant weathered and jointed area are causative factors in the route with rainfall and road widening as major triggers initiating the failure.     

The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

Reaction of soil enzymes and spring barley to copper chloride and copper sulphate

Study was carried out to compare the effect of the degree of contamination of soil with copper on the soil enzyme activity, depending on the type of chemical compound with which a metal reaches the soil and on the method of soil use. An effect of increasing doses of copper on growth and the development of spring barley has been studied. The study was carried out as a pot experiment on two types of soil: loamy sand and light loam. Copper was introduced to soil as copper(II) sulphate(VI) and copper(II) chloride at four doses: 150, 300, 450 and 600 mg Cu²⁺ kg^?1 d.m. of soil. Soil without copper was used as a control sample. The experiment showed that contamination of soil with copper applied as CuCl₂ and CuSO₄·5H₂O upset the homeostasis of soil. Dehydrogenases and urease were the most sensitive to contamination of soil with Cu²⁺, both as copper(II) chloride and as copper(II) sulphate(VI), and acid phosphatase and alkaline phosphatase were the least sensitive. Greater changes in enzymatic activity were observed in loamy sand than in light loam. The differences in the impact of copper(II) sulphate(VI) and copper(II) chloride on the soil microbiome were relatively small, because mean ED₅₀ for copper(II) chloride was 341 mg Cu²⁺ kg^?1 d.m. of soil, and for copper(II) sulphate(VI) it was 364 mg Cu²⁺ kg^?1 d.m. of soil. This inhibitory effect of copper persisted throughout the period of the experiment. The sensitivity of spring barley to copper compounds was lower than the enzymes under study.