MTBE in Drinking Water Production – Occurrence and Efficiency of Treatment Technologies

In Germany, the gasoline additive methyl tert‐butyl ether (MTBE) is almost constantly detected in measurable concentrations in surface waters and is not significantly removed during riverbank filtration. The removal of MTBE from water has been the focus of many studies that mostly were performed at high concentration levels and centred in understanding the mechanisms of elimination. In order to assess the performance of conventional and advanced water treatment technologies for MTBE removal in the low concentration range further studies were undertaken. Laboratory experiments included aeration, granulated activated carbon (GAC) adsorption, ozonation and advanced oxidation processes (AOP). The results show that the removal of MTBE by conventional technologies is not easily achieved. MTBE is only removed by aeration at high expense. Ozonation at neutral pH values did not prove to be effective in eliminating MTBE at all. The use of ozone/H₂O₂ (AOP) may lead to a partly elimination of MTBE. However, the ozone/H₂O₂ concentrations required for a complete removal of MTBE from natural waters is much higher than the ozone levels applied nowadays in waterworks. MTBE is only poorly adsorbed on activated carbon, thus GAC filtration is not efficient in eliminating MTBE. A comparison with real‐life data from German waterworks reveals that if MTBE is detected in the raw water it is most often found in the corresponding drinking water as well due to the poor removal efficiency of conventional treatment steps.     

Short‐term intertidal bar mobility on a ridge‐and‐runnel beach,Merlimont, northern France

Digital elevation models and topographic pro?les of a beach with intertidal bar and trough (ridge‐and‐runnel) morphology in Merlimont, northern France, were analysed in order to assess patterns of cross‐shore and longshore intertidal bar mobility. The beach exhibited a pronounced dual bar–trough system that showed cross‐shore stationarity. The bars and troughs were, however, characterized by signi?cant longshore advection of sand under the in?uence of suspension by waves and transport by strong tide‐ and wind‐driven longshore currents. Pro?le changes were due in part to the longshore migration of medium‐sized bedforms. The potential for cross‐shore bar migration appears to be mitigated by the large size of the two bars relative to incident wave energy, which is modulated by high vertical tidal excursion rates on this beach due to the large tidal range (mean spring tidal range = 8·3 m). Cross‐shore bar migration is also probably hindered by the well‐entrenched troughs which are maintained by channelled high‐energy intertidal ?ows generated by swash bores and by tidal discharge and drainage. The longshore migration of intertidal bars affecting Merlimont beach is embedded in a regional coastal sand transport pathway involving tidal and wind‐forced northward residual ?ows affecting the rectilinear northern French coast in the eastern English Channel. Copyright © 2004 John Wiley & Sons, Ltd.     

An automated salt‐tracing gauge for flow‐velocity measurement

This article introduces the SVG (salt‐velocity gauge), a novel automated technique for measuring flow velocity by means of salt tracing. SVG allows a high measuring rate (up to one every 2 seconds), short control section length (down to 10 cm), high accuracy (+[sol ]?1·5 cm s^?1), and unbiased calculation of the mean velocity in experimental conditions with turbulent, supercritical flow. A few cubic centimetres of saturated salt solution (NaCl) are injected into the flow at regular time intervals using a programmable solenoid valve. The tracer successively passes two conductivity probes placed a short distance downstream. The transformation of the signal between the two probes is modelled as a one‐dimensional diffusion wave equation. Model calibration gives an estimation of the mean velocity and the diffusion for each salt plume. Two implementations of the SVG technique are described. The first was an outdoors simulated rainfall experiment in Senegal (conductivity probes at 40 cm apart, 8 Hz measurement rate, salt injections at 10 second intervals). Mean velocity was estimated to range between 0·1 and 0·3 m s^?1. The second was a laboratory‐based flume experiment (conductivity probes at 10 cm apart, 32 Hz, salt injections at 2 second intervals). Another SVG with probes at 34 cm apart was used for comparison. An acoustic Doppler velocimeter (ADV) was also used to give an independent assessment of velocity. Using the 10 cm salt gauge, estimated mean velocity ranged from 0·6 to 0·9 m s^?1 with a standard deviation of 1·5 cm s^?1. Comparisons between ADV, 10 cm SVG and 34 cm SVG were consistent and demonstrated that the salt‐tracing results were unbiased and independent of distance between probes. Most peaks were modelled with r² > 90 per cent. The SVG technology offers an alternative to the dye‐tracing technique, which has been severely criticized in the literature because of the wide interval of recommended values for the correction factor α to be applied to the timings. This article demonstrates that a fixed value of α is inappropriate, since the correction factor varies with velocity, diffusion and the length of the control section. Copyright © 2005 John Wiley & Sons, Ltd.     

Probabilistic approach for active control of structures: experimental verification

In our previous study (Earthquake Engineering and Structural Dynamics 2003; 32 :2301), we have developed a probabilistic algorithm for active control of structures. In the probabilistic control algorithm, the control force is determined by the probability that the structural energy exceeds a specified target critical energy, and the direction of a control force is determined by the Lyapunov controller design method. In this paper, an experimental verification of the proposed probabilistic control algorithm is presented. A three‐story test structure equipped with an active mass driver (AMD) has been used. The effectiveness of the control algorithm has been examined by exciting the test structure using a sinusoidal signal, a scaled El Centro earthquake and a broadband Gaussian white noise; and, especially, experiments on control have been performed under different conditions to that of system identification in order to prove the stability and robustness of the proposed control algorithm. The experimental results indicate that the probabilistic control algorithm can achieve a significant response reduction under various types of ground excitations even when the modeling error exists. Copyright © 2004 John Wiley & Sons, Ltd.     

淮安五河口特大桥大口径灌注桩施工实践

介绍了使用大口径钻机，采用泥浆护壁气举反循环回转钻进工艺、进行淮安市五河口特大桥大口径灌注桩施工的工程实践。通过不断提高施工技术措施，摸索与总结出一套成孔施工经验，顺利地完成了施工任务。     

Isotopic evidence of TSR origin for natural gas bearing high H_2S contents within the Feixianguan Formation of the northeastern Sichuan Basin, southwestern China

Isotopic evidence of TSR origin for natural gas bearing high H2S contents 1961 As the hazardous component of natural gas, the ex-istence of H2S, due to its extremely strong toxicity and corrosivity, not only decreases the percentage of hy-drocarbon gas within natural gas and reduces its in-dustrial value, it also threatens each aspect of drilling and exploitation. It frequently causes serious safety accidents[1] and leads to the E&P cost and risk of natural gas with higher H2S contents be…     

Characteristics and genesis of maghemite in Chinese loess and paleosols: Mechanism for magnetic susceptibility enhancement in paleosols

Morphological characteristics and microstructures of magnetic minerals extracted from Chinese loess and paleosols were investigated using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Our results indicate that maghemite in loess–paleosol sequences was transformed from magnetite through oxidation of magnetite. Maghemite transformed from eolian magnetite during chemical weathering has low-angle grain boundaries among maghemite nano-crystals. Some nano-crystalline maghemites with nanoporous texture resulted from microbe-induced precipitation of magnetite or transformation of poorly crystalline ferric Fe (oxy)hydroxides in presence of Fe-reducing bacteria. Aggregates of euhedral maghemite nano-crystals were transformed from magnetite magnetosomes. Both microbe-induced nanoporous magnetite and microbe-produced magnetite magnetosomes are directly related to microbial activities and pedogenesis of the paleosols. It is proposed that the formation of nano-crystalline maghemite with superparamagnetic property in paleosol results in the enhancement of magnetic susceptibility, although the total amount (weight percent) of magnetic minerals in both paleosol and loess units is similar. Our results also show that nano-crystalline and nanoporous magnetite grains prefer to transform into maghemite in semi-arid soil environments instead of hematite, although hematite is a thermodynamically stable phase. This result also indicates that a decrease in crystal size will increase stability of maghemite. It is also inferred that surface energy of maghemite is lower than that of hematite.     

Statistical Analysis on the Corner Period of Site-Related Design Spectra

INTRODUCTIONFromTJ1 1 74 ,theseismicdesignforbuildingshasbeenbasedontheaccelerationresponsespectruminChina (HuYuxian ,1 988) .ThevalueofTgoftheresponsespectrumvariesbecauseofdifferentsiteclassesanddifferentearthquakeenvironments .Designresponsespectrainc…     

Characteristics of Energy Accumulation and Release of Seismogenic Tectonics and Seismic Risk Analysis in Some Areas in the Tianshan Mountains, Xinjiang1

INTRODUCTIONHowtocombinethestudyofseismogenictectonicswithearthquakepredictionisanurgentscientificdifficulty .Thereexistbiggapsbetweenstudymethodsandcurrentknowledgeonseismogenitectonics ,earthquakeprediction ,seismogenesisandthephysicsofearthquakeoccurre…     

长江三角洲全新世环境演变与人地关系研究综述

综合分析了近20年来长江三角洲全新世环境演变与人地关系研究的进展，着重对长江三角洲的形成与演变、环境演变与人类活动、人地关系的历史演变、古环境研究方法等进行了综述。指出今后研究的主要内容，包括多种环境替代指标的相互验证，高分辨率研究，定量研究，加强环境质量的时空演变研究，加强综合研究，寻求人地关系协调发展的途径。