5′-硝基水杨基荧光酮与锆显色反应及其应用

在００８～０１０ｍｏｌ／ＬＨＣｌ介质中,溴化十六烷基三甲铵（ＣＴＭＡＢ）存在下,Ｚｒ（Ⅳ）与５′＿硝基水杨基荧光酮（５′＿ＮＳＦ）发生显色反应,形成１∶４的桔红色络合物,λｍａｘ＝５４０ｎｍ,ε为１４６×１０５Ｌ·ｍｏｌ－１·ｃｍ－１,Ｚｒ（Ⅳ）含量在０～０５ｍｇ／Ｌ符合比尔定律。方法用于氧化铝及陶瓷釉料中锆的测定,结果与ＩＣＰ＿ＡＥＳ法相符,ＲＳＤ（ｎ＝５）在１３％～３７％。     

鄂尔多斯盆地东北部构造热演化史的磷灰石裂变径迹分析

运用磷灰石裂变径迹(AFT)分析的构造热年代学研究方法,系统探讨鄂尔多斯盆地东北部不同区段中新生代以来的热演化历史,为盆地东北部石油和天然气等多种沉积能源矿产的勘探预测提供新的约束条件。模拟结果表明:盆地东北部经历了250~150 Ma缓慢埋藏增温过程,平均增温速率为0.9℃/Ma;150~120 Ma为快速增温阶段,平均增温速率高达2.1℃/Ma,地层温度达到最高,且均大于130℃。之后不同区段经历差异降温过程:北缘露头区经历了120~65 Ma快速降温,平均冷却速率约1.3℃/Ma;65~10 Ma缓慢降温,平均冷却速率约为0.4℃/Ma。南缘露头区及盆地沉降区则经历了120~30 Ma缓慢降温,平均冷却速率约为0.9℃/Ma;30~10 Ma快速降温,平均冷却速率约为1.5℃/Ma。10 Ma以来,盆地东北部整体抬升冷却,平均冷却速率约6.5℃/Ma。分析结果认为燕山中期构造热事件之最高热增温作用的关键时刻为(120±10)Ma,促成鄂尔多斯盆地东北部主要烃源岩层系的成熟生烃和大规模油气成藏。在后期的差异抬升冷却过程中,北缘露头区在65 Ma±通过了110℃等温面,南缘露头区及盆地的沉降区在30 Ma±通过了110℃等温面,有利于相邻地区原生油气藏的积聚和保存,古近纪晚期(30 Ma)尤其是新近纪晚期近10 Ma以来的强烈构造抬升作用有可能是引发原生油气藏调整—改造和次生成藏的关键因素。     

Study on rain-runoff process in the peripheral mountainous area of the Sichuan Basin

Studies on rain-runoff process in the peripheral mountainous area of the Sichuan Basin, which is regarded as a key ecological shelter, will contribute to flood control and environmental protection for the Upper Yangtze River Basin. In two typical catchments--the Fujiang River Catchment and the Wujiang River Catchment, rainfall simulations have been conducted to study the rain-runoff processes of yellow soil and limestone soil in three types of land use--forestland, farmland and grassland. Results showed that （1） within the same rainfall process, overland flow occurs first on farmland, then on grassland, and finally on forestland; （2） soil surface coverage has a great impact on the occurrence and amount of overland flow. The runoff amount can increase 2-4 times after the coverage is removed; （3） the infiltration before the occurrence of overland flow will decrease because of higher gravel contents of soil, but it takes no effect on infiltration once overland flow becomes stable; （4） the runoff coefficient of the limestone soil forestland is greater than that of the yellow soil forest land, but less than that of the farmland; （5） three empirical infiltration models, including Horton＇ model, Kostiakov＇ model, and modified Kostiakov＇ model, were compared by using the observed results under rainfall simulation. The results showed that the Kostiakov＇ model performed better than both the Horton＇ model and modified Kostiakov model. According to the results of this research, the Kostiakov＇s model can be used to simulate rainfall infiltration when water erosion is modeled in the peripheral mountainous area of the Sichuan Basin.     

赤柏松No.1含镍基性岩体中矿物界生(Synantectic)现象浅析

在两种相邻矿物边界上生长出第三种矿物的现象称为界生。界生现象在长白山区赤柏松镍矿田诸含镍基性辉长苏长岩岩体中广泛发育。通过研究,作者提出界生现象的多种成因观点,并在矿物学、矿物化学与热力学研究的基础上把界生现象区分为原生与次生两大类。研究不同成因的界生现象可提供大量地质成因信息,用手成岩成矿作用的研究。     

大别造山带大陆深俯冲和折返过程中壳-幔相互作用信息--来自大理岩铅同位素的证据

对大别造山带不同产状大理岩的铅同位素研究表明,红安群王家店和双河大理岩分别经历过高压和超高压变质作用,具有较高的铅同位素变化范围和高的放射性成因铅,反映了上地壳铅同位素的特征;新店大理岩的铅同位素比值和变化范围很小,具有EM1型地幔铅同位素特征,表明有地幔铅同位素特征的记录;而位于剪切带的方高坪大理岩的铅同位素除了n(206Pb)/n(204Pb)值更高外,与新店大理岩的铅同位素特征相似,记录了放射性铅同位素的大量加入或丢失,导致本来具有与双河大理岩类似的铅同位素特征变得不明显.这些结果均表明大陆深俯冲及其折返过程对大理岩铅同位素组成的改造是相当复杂的.     

二维随机介质模型正演指导复杂地层地震解释——以薄层砂泥岩交互地层为例

大港油田砂泥岩交互地层存在着非均质复杂地质形态,为保证其精细解释效果,根据随机过程理论,提出了选用二维指数型椭圆自相关函数为复杂非均质地质体进行简化建模的方法。正演算法使用交错网格有限差分法模拟弹性波在二维随机介质模型中的传播,激发方式使用自激自收模式。正演结果表明,随机介质模型模拟大港油田薄层砂岩互层地层具有合理性,交错网格有限差分算法对于该模型的正演数值模拟,算法合适。     

Carbon emission mitigation through regulatory policies and operations adaptation in supply chains: theoretic developments and extensions

Along with carbon emission regulations launched by governments and consumers’ rising concerns about climate changes and global carbon footprint, interests of academia and industry have risen in carbon-efficient supply chain management. This research focuses on some product supply chain to make a literature review-based investigation on proposing a theoretical framework. We also solve potential research issues of how diverse carbon emission regulations can work on supply chain performance as well as emission; in what way we can find coordination mechanisms and optimal policies for supply chain operations to abate emission and enhance system profitability within different scenarios; and also to evaluate the effect on emission reduction for each emission regulation aforementioned through comparing their associated supply chain performances and system emission. Both practitioners in industry and academia might find this study useful, as it generates concepts with a formal framework of potential and values theoretical issues in the emerging field of carbon-efficient supply chain management which combines carbon emission regulations with mature operation management to enrich the theory of supply chain management. This study is perhaps to be valuable and constructive both for operational decisions in firms and for the enactment as well as implementation of emission-reduction regulations. This study should activate further potential researches.     

中国东部苏鲁榴辉岩超基性岩褶皱带的演化及其与大别(中国)和柯切塔夫(哈萨克斯坦)杂岩的对比(英文)

苏鲁褶皱带形成于元古宙 (2 2 33～ 185 5Ma)典型优地槽构造环境 ,主要由石榴橄榄岩、石榴辉石岩、榴辉岩等侵入岩 (柯石英深度相地幔岩浆房中形成 )和它们的火山沉积建造围岩一起经褶皱、变质而形成。变质作用经历了先蓝片岩相 (前花岗岩 )后片麻岩混合岩相过程。由于变质作用的不规律性 ,苏鲁褶皱带可分为 2个构造带 :(1)东部构造带 (蓝片岩 )和 (2 )西部构造带 (片麻岩混合岩 )。根据A·都城秋穗所识别的变质带系统 ,可将其作为一个双变质带。东部构造带以出现许多块状、条带状榴辉岩辉石岩橄榄岩组合的残余岩块为特征 ,其中还残留着高压的矿物 (石榴石、绿辉石、柯石英 ) ,而且有被混合岩和各种交代岩替代的显著标志。在中生代 ,苏鲁元古褶皱带受造山作用的影响活化 ,导致许多花岗岩体的侵入 ,使交代岩广泛发育。     

泥岩盖层浓度封闭演化特征——以松辽盆地下白垩统泥岩为例

在研究泥岩盖层浓度封闭机理及形成条件的基础上,提出了抑制和替代两种浓度封闭作用。通过其形成及演化过程分析,研究了不同类型泥岩盖层浓度封闭性的演化特征。通过泥岩盖层浓度封闭形成期与气源岩大量排气期的匹配关系分析,探讨了研究泥岩盖层浓度封闭演化特征的意义。以松辽盆地三肇凹陷下白垩统青山口组和登娄库组二段泥岩盖层为例,研究了其浓度封闭演化特征及其在气藏形成中的作用。     

青藏高原中部北北东向深部负磁异常带的成因及其意义

根据最新测量获得的青藏高原中西部航磁异常图 ,经不同高度向上延拓后 ,发现在测区东部 ,即青藏高原中部自柴达木向西南延伸的广大地区 ,出现一条极为明显的北北东向负磁异常带。从对航磁区域场的分析 ,并结合人工地震、重力计算莫霍面深度、热水活动、最新火山岩活动、地貌特征和天然地震活动等多种资料的解释 ,认为负异常带是由于深部热流沿北北东向上升引起局部岩浆熔融 ,使上地壳下部具有较高的地温 ,导致磁性层底部消磁作用的结果。与此同时也加快了青藏高原隆升的幅度 ,为高原形成和演化的研究提供了新的证据