伊通地堑下第三系原油和生油岩中芳构化五环三萜及其地球化学意义

详细研究了吉林伊通地堑下第三系生油岩和原油中的芳烃生物标志物，包括常规的多环芳烃，以及丰富的来源于高等植物的芳香二萜和芳构化的五环三萜。目前，原油中芳构化五环三萜类生物类生物标志物国内外均尚报道极少。还详细讨论了利用原油中最新发现的芳构化五环三萜在解决本区生物输入，油源对比以及石油成因等方面的重要意义。     

临沧超大型锗矿床有机质与锗矿化的地球化学特征

临沧锗矿床是一产于第三系含煤岩系中的超大型矿床。矿床的最初锗源与盆地西缘的二云母花岗岩有关。主矿体产于下煤组沉积旋回的早期地层中，每一沉积阶段早期形成的褐煤和碳质泥岩中富含锗，最高含量达１４７０×１０＾－６。褐煤和碳质泥岩在矿化过程中平均富集了１６４－１６９倍。根据锗含量，褐煤和碳质泥岩可分为锗含量小于１２×１０＾－６的低锗煤（泥岩）和大于９０×１０＾－６的高锗煤（泥岩）。高锗煤中有机质富含氧官能     

广州珠江西航道,流溪河有机污染特征与感潮作用

珠江西航道和流溪河在广州市区上游，为广州市主要水源区。由于感潮作用，受市区严重污染的水体因涨潮上溯而上游传输。严重影响上游水质。因此，弄清感潮作用对广州水源区水质的影响程度和范围，对水源保护与利用有重要意义。本研究从下游到上游，对水源区底泥中有机物特征进行了分析，结果表明：（１）从上游到上游，受感潮作用影响逐渐减小，污染程度逐渐减轻；（２）水源区有机物特征呈有规律变化。从靠近城市的下游到远离城市的     

边坡及其它类工程地质问题研究

本文提出有关边坡工程地质研究方面的一些新概念，看法和问题，并概述了属地这一专题的边坡及其它各类工程地质问题的研究成果。     

南支气流对高原低涡移出高原影响的数值试验

本文在对2000年以来移出青藏高原后活动时间长的高原低涡活动过程,进行对流层中层南支气流对高原低涡移出高原的影响的观测事实分析基础上,通过对2001年6月1～5日索县低涡移出高原活动的数值模拟和试验分析,得出了在高原低涡以南的南支气流减弱或者是没有南风或者是没有南风脉动的影响,会使低涡移出高原的速度减慢,移出高原12小时后减弱消失。低涡以南的南支气流起到了向低涡区输送水汽通量、正涡度平流的作用,提供利于低涡活动持续的条件。从而丰富了高原低涡东移的认识,为高原低涡洪涝暴雨的预报提供了科学依据。     

Characteristics of carbonyl compounds in ambient air of Shanghai,China

The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m⁻³ respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.     

Composition and major sources of organic compounds in urban aerosols

Total suspended particles (TSP), collected during June 2002 to July 2003 in Guangzhou, a typical economically developed city in South China, were analyzed for the organic compound compositions using gas chromatography–mass spectrometry (GC/MS). Over 140 organic compounds were detected in the aerosols and grouped into different classes including n-alkanes, hopanoids, polycyclic aromatic hydrocarbons, alkanols, fatty acids, dicarboxylic acids excluding oxalic acid, polyols/polyacids, lignin products, phytosterols, phthalates and water-soluble sugars. The total amounts of the identified organic compounds including unresolved complex mixture (UCM) ranged from 3112 ng/m³ in spring to 5116 ng/m³ in winter, comprising on seasonal average 2.8% of TSP. Primary organic compounds peaked in winter although there are no heating systems burning fuels in Guangzhou. The highest saccharide levels occurred in fall due to agricultural activities. This study demonstrated that utilization of fossil fuels, biomass burning, soil resuspension and plastic/refuse burning are the major contributors to the identified organic compounds in the urban atmosphere of South China.     

Adsorption of Au(III) and Au(I) complexes on δ-MnO2

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.     

Monoterpinenes as terrigenous markers in Okinawa Trough sediments

Monoterpinenes were isolated from Okinawa Trough sediments at the 1000-m water depth by thin-layer chromatography (TLC) and identified by gas chromatography (GC) and gas chromatography-mass spectrometry-data system (GC-MS-DS). Identification has revealed cyclohexene, 1-methyl-5-(1-methylethenyl), cyclohexene, 1-methyl-3-(1-methylethenyl), and cyclohexane, 1-methyl-4-(1-methylethylidene). These monoterpinenes are believed to have been derived from terrigenous higher plant detritus, which may serve as new terrigenous markers.     

Biomarker Compounds as Indicators of Paleoenvironments

In an attempt to assess the paleoenvironments of terrestrial sediments,some twenty-two representa-tive Chinese non-marine sediment samples were studied using the molecular organic geochemistry method.The sediment samples stuied include oilshale,shale,mudstone and glauber salt from Tertiary to Cretaceous in age.Judging from geological/geochemical data and paleosalinity data,the samples studied are of lacustrine sedimentary origin and can be divided into three different types:fresh water,brackish and saline/hypersaline lake sediments.The aliphatic fractions were separated from the extracts of the samples and analysed by means of GC and GC/MS instruments,giving a number of parameters such as relative abundances of alkanes and cycloalkanes as shown in the mass chromatograms.