攀西红格钒钛磁铁矿矿田富钴硫化物中钴的地球化学特征及其地质意义

攀西红格钒钛磁铁矿矿田白草矿区发育富钴硫化物矿物,关于其成因和形成环境方面的研究较为薄弱。本文采用矿物学、矿物化学、地球化学等方法对其进行系统研究。矿石中主要富钴硫化物为磁黄铁矿（Po）、黄铁矿（Py）、镍黄铁矿（Pn）、硫钴镍矿（Se）。磁黄铁矿Co、Ni平均质量分数分别为0.21%、0.42%,Co/Ni平均值为1.10;黄铁矿Co、Ni平均质量分数分别为0.18%、0.29%,Co/Ni平均值为0.77;镍黄铁矿Co、Ni平均质量分数分别为2.67%、34.30%,Ni/Fe平均值为1.08、S/Fe平均值为1.91、M/S^#平均值为1.13;硫钴镍矿Co、Ni平均质量分数分别为24.30%、22.90%,Co/Ni平均值为1.06。根据Po-Py矿物温度计,白草矿区富钴硫化物结晶温度在267~490℃之间,表明其形成于中高温的条件。通过与地幔包体镍黄铁矿S/Fe、M/S^#特征值的对比,结合磁黄铁矿具有陨硫铁（Tr）同质多象晶体的特征,认为白草矿区硫化物具有地幔源的特征,说明成矿物质来源于地幔。白草矿区钴地球化学特征研究表明,在硫化物熔体分离过程中,钴迁移至单硫化物固溶体形成Po-Py固溶体,再由Po-Py固溶体中迁移至Pn、Se,形成了Se、Pn、Po-Py、Ccp（黄铜矿）中Co质量分数依次递减的现象。     

The Impact of Urbanization on Groundwater Quantity,Quality,Hydrothermal Changes and Its Countermeasures

Groundwater, as a drinking water source for nearly one third of the world’s urban population, plays a strategic role in the development of urbanization. The object of this study is urban areas with the largest demand for water resources, the heaviest load of groundwater pollution and the most intense development of underground projects. This study sorted out the eco-hydrological problems such as the variation of the groundwater hydrological process, the groundwater pollution, and the urban heat island of groundwater in urban areas under the background of urbanization. Furthermore, the mechanism of changes in the quantity, quality and heat of groundwater was also systematically analyzed, and the intrinsic interaction among these three factors was revealed. The study showed that changes in land use and land cover caused by the urbanization are the main reasons for the variation of groundwater hydrological process. The pollution load of urbanization construction and domestic production waste has aggravated the deterioration of groundwater quality. The increase in vertical heat flux caused by urbanization gives rise to the warming of groundwater. By summarizing the eco-hydrological problems and causes of groundwater in urbanized areas, several suggestions were proposed: \mathrm{①} Establishing the evaluation method and system of urban groundwater resources; \mathrm{②} Speeding up the technological breakthroughs of groundwater pollution control; \mathrm{③} Improving the regional control strategies for groundwater pollution; \mathrm{④} Optimizing the allocation of groundwater resources. This study will provide the theoretical basis and technical support for ensuring urban water safety, building ecological civilized cities and further promoting the sustainable development of economy and society.     

A Top Pilot Tunnel Preconditioning Method for the Prevention of Extremely Intense Rockbursts in Deep Tunnels Excavated by TBMs

The headrace tunnels at the Jinping II Hydropower Station cross the Jinping Mountain with a maximum overburden depth of 2,525 m, where 80% of the strata along the tunnels consist of marble. A number of extremely intense rockbursts occurred during the excavation of the auxiliary tunnels and the drainage tunnel. In particular, a tunnel boring machine (TBM) was destroyed by an extremely intense rockburst in a 7.2-m-diameter drainage tunnel. Two of the four subsequent 12.4-m-diameter headrace tunnels will be excavated with larger size TBMs, where a high risk of extremely intense rockbursts exists. Herein, a top pilot tunnel preconditioning method is proposed to minimize this risk, in which a drilling and blasting method is first recommended for the top pilot tunnel excavation and support, and then the TBM excavation of the main tunnel is conducted. In order to evaluate the mechanical effectiveness of this method, numerical simulation analyses using the failure approaching index, energy release rate, and excess shear stress indices are carried out. Its construction feasibility is discussed as well. Moreover, a microseismic monitoring technique is used in the experimental tunnel section for the real-time monitoring of the microseismic activities of the rock mass in TBM excavation and for assessing the effect of the top pilot tunnel excavation in reducing the risk of rockbursts. This method is applied to two tunnel sections prone to extremely intense rockbursts and leads to a reduction in the risk of rockbursts in TBM excavation.     

活动断裂引发的环境地质问题及措施

随着经济的飞速发展和现代化建设的加快，全社会防灾减灾意识的增强，在国土规划、抗震规划及高、深、大型工程项目的建设中，对活动断裂的研究，已成为勘测、设计中的重要课题。本文就影响张家口市城市安全的活动断裂的类型、空间展布、活动特征、引发的环境地质灾害及工程对策等予以阐述，为城市规划提供依据。     

南海晚新生代地层结构特征、沉积厚度及沉积模式

本文综合地震、钻井及区域地质资料，通过分析地震相参数等，研究南海晚新生代（E3-Q）地层结构特征和沉积厚度变化，建立了晚新生代沉积模式，所取得的研究成果可为南海油气的进一步勘探开发提供有效的基础资料。     

我国东部若干地区新生代玄武岩中长石巨晶的特征及成因

本文汇集了中国东部新生代玄武岩中76个长石巨晶的化学成分,并与53个国外长石巨品进行了对比。文中对长石巨晶的产状、物理性质、矿物化学及微量元素进行了研究,并对国际上关于长石巨晶五个有争议的问题进行了讨论。作者同时也提出了自己的观点。     

国产WSP—2半米平面光栅测定超痕量金方法介绍

本文叙述了国产半米平面光栅光程短、光强好、谱线锐度佳的特点,通过最佳条件选择,改进分析方法,使其测金灵敏度为3×10~(-9)g,取样10g可测定含金量范围为0.3—1000ppb,取得了很好的效果。     

铜官山地区矽卡岩型铜金矿床稀土元素特征及其成因意义

铜官山地区不同成因类型的矽卡岩发育，各自对应着不同成因类型的铜金矿床，且具有不同的稀土元素分布模式及演化特征，提供了矽卡岩矿床多成因的信息。     

原子荧光光谱法直接连续测定化探样品中的As Sb Bi Hg

研究了还原性介质中原子荧光光谱法直接连续测定化探样品中Ａｓ、Ｓｂ、Ｂｉ、Ｈｇ的方法。按拟定的条件进行测定,各元素的检出限分别为Ａｓ２．９×１０－９、Ｓｂ１．３×１０－１０、Ｂｉ１．８×１０－１０、Ｈｇ５×１０－１１。应用于区域化探扫面工作中,效果良好。