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21.
对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。 相似文献
22.
An algorithm for detecting outliers and cycle slips in single-frequency GPS using a 3rd order polynomial model of the Kalman filter and for estimating the ambiguity by using optimal wavelet is presented in this paper. It is applicable to the carrier phase measurement with sample rate of one per second. The results of calculation with the GPS data aboard satellite Topex on 1995 June 22 show that the algorithm is so efficient that it can accurately estimate the ambiguity even for signals interrupted by a few seconds. 相似文献
23.
An improved approach is given for deriving the physical parameters of a molecular cloud by its NH3 rotation-inversion hyperfine spectra. The optical depth τ0(1, 1) of NH3 (1,1) is obtained by considering the blending effect of the magnetic hyperfine spectral lines, the (1-1) excitation temperature Tex (1, 1) is calculated by a two level model, the effect of different collision rate and the thermalization of the (1, 1) inversion lines are discussed, the rotation temperature TR ( 2, 1) between the NH3 levels (2, 2) and (1, 1) and the column density N( 1, 1) of the NH3 (1, 1) inversion level are derived, the results of the total column density from different assumptions for the abundance ratio of ortho-NH3 and para-NH3 are also discussed.
This approach is used for the molecular cloud NGC 2023 by using the relevant observed data and its optical depth and other physical parameters are obtained. 相似文献
24.
We study the magnetic field evolution and topology of the active region NOAA 10486 before the 3B/X1.2 flare of October 26, 2003, using observational data from the French–Italian THEMIS telescope, the Michelson Doppler Imager (MDI) onboard Solar and Heliospheric Observatory (SOHO), the Solar Magnetic Field Telescope (SMFT) at Huairou Solar Observation Station (HSOS), and the Transition Region and Coronal Explorer (TRACE). Three dimensional (3D) extrapolation of photospheric magnetic field, assuming a potential field configuration, reveals the existence of two magnetic null points in the corona above the active region. We look at their role in the triggering of the main flare, by using the bright patches observed in TRACE 1600 Å images as tracers at the solar surface of energy release associated with magnetic reconnection at the null points. All the bright patches observed before the flare correspond to the low-altitude null point. They have no direct relationship with the X1.2 flare because the related separatrix is located far from the eruptive site. No bright patch corresponds to the high-altitude null point before the flare. We conclude that eruptions can be triggered without pre-eruptive coronal null point reconnection, and the presence of null points is not a sufficient condition for the occurrence of flares. We propose that this eruptive flare results from the loss of equilibrium due to persistent flux emergence, continuous photospheric motion and strong shear along the magnetic neutral line. The opening of the coronal field lines above the active region should be a byproduct of the large 3B/X1.2 flare rather than its trigger. 相似文献
25.
本矿床是我国金红石矿床重要的成因及工业类型,为具有特定化学成分的岩石在特定变质条件下形成的。本文通过对大量数据的处理,查明了化学成分与成矿的关系:高Al2O3、MgO、Fe2O3+FeO、K2O、P2O5、H2O+、MnO,低SiO2、CaO、Na2O、CO2、S等,利于钛富集;高TiO2、MgO、P2O5、S,低SiO2、CaO、K2O、Al2O3、Fe2O3/FeO,利于金红石形成;高Sc、Zr、Ni、Zn及La/Yb,低Y、Nb、Th、Cd、Ba、Be、ΣREE,利于金红石纯度提高。对研究矿床成因及寻找新的同类矿床等有重要意义 相似文献
26.
Quasi-electrostatic electron and ion-cyclotron instabilities are studied. The result indicates that the higher harmonic ion cyclotron instabilities (ICI) can be excited while the fast ions produced from reconnection are injected into a coronal loop. Part of the energetic ions can be dragged out of the magnetic mirror turning points and a negative plasma potential is generated. The plasma potential may directly accelerate the electrons up to the relativistic velocity within a short time. This acceleration is similar to the processes occurring in the magnetic mirror devices of controlled thermonuclear fusion. The spectrum and flux of accelerated electrons have also been obtained. Some observational results during the solar flare might be explained by this acceleration mechanism. 相似文献
27.
介绍了近年来河外H2O超脉泽的主要观测结果。H2O超脉泽通常起源于活动星系核中央的拱核盘。它们主要寄生在 Serfert 2星系或低电离核区。至今为止,已有20个星系探测到H2O超脉泽。脉泽辐射的各向同性光度为10~6000L⊙。所有超脉泽星系显示出核的活动,显然,脉泽是由核活动所产生的射电和X射线光子或激波来抽运的。H2O超脉泽倾向存在于高倾斜度的星系,这使得沿视线上的分子柱密度增高,产生足够大的放大光深。最有可能产生H2O超脉泽辐射的星系应有一个包含着射电源的侧向的分子盘以及一个适当的抽运机制。 相似文献
28.
29.
Relict rock glaciers have considerable potential for contributing to palaeoclimatic reconstruction, but this potential is often undermined by lack of dating control and problems of interpretation. Here we reinvestigate and date four proposed ‘rock glaciers’ in the Cairngorm Mountains and show that the morphology of only one of these appears consistent with that of a true rock glacier produced by creep of underlying ice or ice‐rich sediment. All four features comprise rockslide or rock avalanche runout debris, and the possibility that all four represent unmodified runout accumulations cannot be discounted. Surface exposure dating of the four debris accumulations using cosmogenic 10Be produced uncertainty‐weighted mean ages of 15.4 ± 0.8 ka, 16.2 ± 1.0 ka, 12.1 ± 0.6 ka and 12.7 ± 0.8 ka. All four ages imply emplacement under cold stadial conditions, two prior to the Windermere Interstade of ca. 14.5–12.9 cal. ka BP and two during the Loch Lomond Stade of ca. 12.9–11.5 cal. ka BP. The above ages indicate that paraglacial rock‐slope failure on granite rockwalls occurred within a few millennia after deglaciation. The mean exposure ages obtained for runout debris at two sites – Strath Nethy (16.2 ± 1.0 ka) and Lairig Ghru (15.4 ± 0.8 ka) – are consistent with basal radiocarbon ages from Loch Etteridge, 22 km to the southwest (mean = 15.6 ± 0.3 cal. ka BP) and imply widespread deglaciation of the Cairngorms and adjacent valleys before 15 ka and possibly 16 ka. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
30.
Qinghai Wang Wenliang Xu Dongyan Wang Jingqian LinCollege of Earth Sciences Jilin University Changchun China 《东北亚地学研究》2003,(2)
1IntroductionAdakite has specially sense in the resuming structure background of rock formed,because of its distinctive geochemistry feature and implying partic-ular petrogenesis and ore genesis mechanism (De-fant and Drummond,1990),as a result,it arouses numerous researchers widely concern. After adakite conception was drawn by Chinese (Wang etal.,2000), it was widely concerned by domestic re-searchers (Wang etal.,2000,2001a,2001b;Xu etal.,2000;Pan etal.,2001;Qian,2001;Xu etal.,2001;X… 相似文献