During German R/V Meteor M67/2 expedition to Campeche Knolls, southern Gulf of Mexico, a set of 2D high resolution seismic data was acquired to study the near-surface sediment structure and its relationship with hydrocarbon seepages in this salt province. The comprehensive survey covered 20 individual bathymetric highs or ridges and identified three principle structural types: Passive Type, Chaopopte Type, and Asymmetric Flap Type. The first type is the result of passive diapirism, whereas the latter two were initialized by a regional compressional event in the Miocene, but are later differently modified by salt tectonism. Chapopote Type structures appear as symmetrical domes, with uplifted coarse-grained Miocene sediments in their cores and rather thin syn-kinematic sediments covering the crests. Asymmetric Flap Type structures are also first folded as domes or ridges, but one flap later subsided together with salt evacuation, resulting in single uplifted monoclines. With the coarse-grained pre-kinematic sediments as reservoir units, both structural types can focus and accumulate hydrocarbons. The geometries of the structures suggest that hydrocarbons are accumulated in the center of the Chapopote Type structures and in the subsided flaps of the Asymmetric Flap Type structures. Hydrocarbon leakage from these thinly sealed reservoirs is regarded as the principle mechanism for the seepage in the study area, and accordingly the most seepage-prone positions are above these reservoirs. The seep locations suggested by analysis of sea-surface oil slick images of SAR satellite data are also examined in this study. These independently derived seep locations confirm the seepage-prone positions to be above the shallow buried reservoirs. This study suggest that the shallow sediment structures control the distribution of the hydrocarbon seeps of the north-western Campeche Knolls, although the hydrocarbons are sourced from the greater depth. 相似文献
Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters. 相似文献
This study was carried out to investigate the biogenic amines(BAs), physicochemical property and microorganisms in dry salted fish, a traditional aquatic food consumed in China. Forty three samples of dry salted fish were gathered from retail and wholesale markets and manufacturers, which had been produced in various regions in China. Cadaverine(CAD) and putrescine(PUT) were quantitatively the most common biogenic amines. About 14% of the samples exceeded the histamine content standards established by the FDA and/or EU. The highest histamine content was found in Silver pomfret(Pampus argenteus)(347.79 mg kg-1). Five of forty three samples exceeded the acceptable content of TYR(100 mg kg-1), and 23.26% of dried-salted fish contained high contents of biogenic amines(above 600 mg kg-1). In addition, species, regions, pickling processes and drying methods made the physicochemical property, microorganisms and biogenic amines in dry salted fish to be different to some extents. The total plate count(TPC) was much higher than that of total halophilic bacteria in all samples. The biogenic amines, physicochemical property and microbiological counts exhibited large variations among samples. Furthermore, no significant correlation between biogenic amines and physicochemical property and TPC was observed. This study indicated that dry salted fish may still present healthy risk for BAs, depending on the processing methods, storage conditions among others. 相似文献