Air–sea carbon dioxide fluxes in the coastal southeastern tropical Pacific

Comprehensive sea surface surveys of the partial pressure of carbon dioxide (pCO₂) have been made in the upwelling system of the coastal (0–200 km from shore) southeastern tropical Pacific since 2004. The shipboard data have been supplemented by mooring and drifter based observations. Air–sea flux estimates were made by combining satellite derived wind fields with the direct sea surface pCO₂ measurements. While there was considerable spatial heterogeneity, there was a significant flux of CO₂ from the ocean to the atmosphere during all survey periods in the region between 4° and 20° south latitude. During periods of strong upwelling the average flux out of the ocean exceeded 10 moles of CO₂ per square meter per year. During periods of weaker upwelling and high productivity the CO₂ evasion rate was near 2.5 mol/m²/yr. The average annual fluxes exceed 5 mol/m²/yr. These findings are in sharp contrast to results obtained in mid-latitude upwelling systems along the west coast of North America where the average air–sea CO₂ flux is low and can often be from the atmosphere into the ocean. In the Peruvian upwelling system there are several likely factors that contribute to sea surface pCO₂ levels that are well above those of the atmosphere in spite of elevated primary productivity: (1) the upwelling source waters contain little pre-formed nitrate and are affected by denitrification, (2) iron limitation of primary production enhanced by offshore upwelling driven by the curl of the wind stress and (3) rapid sea surface warming. The combined carbon, nutrient and oxygen dynamics of this region make it a candidate site for studies of global change.     

Evaluation and analysis of surface deformation in west Chapala basin,central Mexico

Vertical deformation was measured at 14 benchmarks within the urban area of Jocotepec Mexico using first-order leveling methods and then spatially analyzed in relation to land subsidence and soil discontinuity patterns. The study area is located within the western portion of the Chapala basin, middle-west Mexico. Observations of vertical surficial deformation were made at each benchmark (September and November 2012) relative to a fixed station and compared to an initial survey of each benchmark (April 2012). Results indicate that a maximum subsidence of 7.16 cm over the 8-month measurement interval occurs near downtown coincident with the largest levels of drawdown and translates to a maximum subsidence rate of 0.89 cm/month for the sampling period. Two benchmarks located northwest and southeast of the urban area exhibited uplift of 2.8 and 0.76 cm, respectively, suggesting a complex mechanical response between the sedimentary soil units and the factors causing deformation. A potential spatial relationship exists between subsidence patterns and soil discontinuities. Four separate cones of groundwater depression were observed with two being coincident with subsidence bowls downtown and south of the urban area; however, there is no clear relationship between drawdown and subsidence in the remaining areas. Hydrogeologic reconstructions reveal alternating sequences of alluvial aquifers and highly deformable lacustrine aquitards. An analysis of the soil discontinuities reveals that they are directly aligned with the patterns of vertical deformation.     

Geology of southeast Bohol,central Philippines: Accretion and sedimentation in a marginal basin

Recent field mapping has refined our understanding of the stratigraphy and geology of southeastern Bohol, which is composed of a Cretaceous basement complex subdivided into three distinct formations. The basal unit, a metamorphic complex named the Alicia Schist, is overthrust by the Cansiwang mélange, which is, in turn, structurally overlain by the Southeast Bohol Ophiolite Complex. The entire basement complex is overlain unconformably by a ～2000 m thick sequence of Lower Miocene to Pleistocene carbonate and clastic sedimentary rocks and igneous units. Newly identified lithostratigraphic units in the area include the Cansiwang mélange, a tectonic mélange interpreted as an accretionary prism, and the Lumbog Volcaniclastic Member of the Lower Miocene Carmen Formation. The Cansiwang mélange is sandwiched between the ophiolite and the metamorphic complex, suggesting that the Alicia Schist was not formed in response to emplacement of the Southeast Bohol Ophiolite Complex. The accretionary prism beneath the ophiolite complex and the presence of boninites suggest that the Southeast Bohol Ophiolite Complex was emplaced in a forearc setting. The Southeast Bohol Ophiolite Complex formed during the Early Cretaceous in a suprasubduction zone environment related to a southeast‐facing arc (using present‐day geographical references). The accretion of this ophiolite complex was followed by a period of erosion and then later by extensive clastic and carbonate rock deposition (Carmen Formation, Sierra Bullones Limestone and Maribojoc Limestone). The Lumbog Volcaniclastic Member and Jagna Andesite document intermittent Tertiary volcanism in southeastern Bohol.     

Identifying strengths and limitations of pan-European forest cover maps through spatial comparison

Detailed and harmonized information on spatial forest distribution is an essential input for forest-related environmental assessments, in particular, for biomass and growing stock modeling. In the last years, several mapping approaches have been developed in order to provide such information for Europe in a harmonized way. Each of these maps exhibits particular properties and varies in accuracy. Yet, they are often used in parallel for different modeling purposes. A detailed spatial comparison seemed necessary in order to provide information on the advantages and limitations of each of these forest cover maps in order to facilitate their selection for modeling purposes.

This article confronts the high-resolution forest cover map recently developed by the Joint Research Centre for the year 2000 (FMAP2000) with previously existing maps for the same time period: the CORINE Land Cover 2000 (CLC2000) and the Calibrated European Forest Map 1996 (CEFM1996). The spatial comparison of these three maps was carried out based on forest proportion maps of 1 km derived from the original maps. To characterize differences according to biogeographic regions, two criteria were used: detail of thematic content within each map and local spatial agreement.

Concerning thematic content, CLC2000 displayed a surfeit of non-forested areas at the cost of low forest proportions, while FMAP2000 showed a more balanced distribution likely to preserve more detail in forest spatial pattern. Good spatial agreement was found for CLC2000 and FMAP2000 within about 70% of the study area, while only 50% agreement was found when compared with CEFM1996. The largest spatial differences between all maps were found in the Alpine and Mediterranean regions. Reasons for these might be different input data and classification techniques and, in particular, the calibration of CEFM1996 to reported national statistics.     

Mixing induced reactive transport in fractured crystalline rocks

In this paper the solute retention properties of crystalline fractured rocks due to mixing-induced geochemical reactions are studied. While fractured media exhibit paths of fast flow and transport and thus short residence times for conservative solutes, at the same time they promote mixing and dilution due to strong heterogeneity, which leads to sharp concentration contrasts. Enhanced mixing and dilution have a double effect that favors crystalline fractured media as a possible host medium for nuclear waste disposal. Firstly, peak radionuclide concentrations are attenuated and, secondly, mixing-induced precipitation reactions are enhanced significantly, which leads to radionuclide immobilization. An integrated framework is presented for the effective modeling of these flow, transport and reaction phenomena, and the interaction between them. In a simple case study, the enhanced dilution and precipitation potential of fractured crystalline rocks are systematically studied and quantified and contrasted it to retention and attenuation in an equivalent homogeneous formation.     

Analysis of contamination hazard of surface water by the methodology of TECHNEAU: a case study from the dam 9 April 1947 in northern Morocco

Preventive protection of surface waters against pollution and the guarantee of the best quality water are the major challenges to provide a sustainable supply of drinking water for the future generations. In this article, we present a hazard mapping application for water contamination of the dam “9 April 1947” located in the northwest of Morocco. This study was motivated by the proliferation of many pollution sources in the study area knowing that the dam feeds the region of Tanger-Asilah that has over 3 million inhabitants. The methodology used was applied for the first time in the city of Freiburg-Ebnet in Germany under the TECHNEAU project funded by the European commission and based on weighting of the different sources of contamination according to three indices: the toxicity index, quantity index, and probability index. The multiplication of the three indices has given us a hazard index named HI varying between 0 and 120 depending on the harmfulness of hazard; the later index has been used to create the final contamination hazard map. The hazard map shows 65% of the watershed area is witnessing a very low danger, 22% of the watershed area is witnessing a low danger, 10% of the watershed area is witnessing a the high danger, and 3% of the watershed area is witnessing a moderate.     

Paleolimnologically inferred eutrophication of a shallow, tropical, urban reservoir in southeast Brazil

We studied the eutrophication history of a tropical shallow reservoir in the S?o Paulo metropolitan region, southeast Brazil. We analyzed grain size, geochemistry, diatom assemblages, and land-use records in a sediment core from the reservoir to infer its trophic state history during the last ~110?years (1894?C2005). Eighty diatom species were observed in the core and shifts in the relative abundances of planktonic and benthic taxa indicate major limnological changes associated with complex interactions between hydrologic factors and eutrophication. Discostella stelligera was associated with deforestation and water physical changes whereas Aulacoseira granulata, a species abundant throughout the core, was mostly associated with high flux conditions and erosion events, regardless of trophic state. Eutrophication was triggered by construction of the city zoo (1958) and installation of the S?o Paulo State Department of Agriculture (1975) within the Gar?as watershed, and increasing loads of untreated sewage from these institutions. The data suggest that deterioration in water quality began after ~1975 and markedly accelerated after ~1990. The reservoir has been hypereutrophic since 1999. Steady increases in geochemical proxies for trophic state, along with a decrease in C/N ratios, indicated higher nutrient concentrations and the prevalence of autochthonous production towards the core top. Appearance of Achnanthidium catenatum ~1993 highlighted the onset of a marked eutrophication phase. The subsequent dominance of Planothidium rostratum and Cyclotella meneghiniana suggested a sharp shift to a hypereutrophic state since 1999. Land-use history proved valuable for validating the chronology and interpreting anthropogenic impacts. Multi-proxy analysis of the sediment record provided an effective tool for tracking ecological shifts in the reservoir ecosystem. This study provides the first reconstruction of lake eutrophication history in Brazil and highlights the importance of hydrological/physical changes as drivers of diatom assemblage shifts in reservoirs, which may confound trophic state inferences based on shifts in the planktonic/benthic diatom ratio.     

Active Fire Detection for Fire Emergency Management: Potential and Limitations for the Operational Use of Remote Sensing

The use of the mid-infrared and thermal bands of sensors on board airborne platforms and satellites permits the detection of active fires on the Earths surface. This application has been available to the fire-fighting community for many years. However, limitations in the fire detection capabilities of the sensors and/or the lack of adequate re-visit frequency have prevented the use of these systems for operational forest fire-fighting. In addition to mobile systems, remote sensors positioned on fixed fire-watch towers have also been used for active fire detection. These instruments are often positioned in strategic look-out places to provide continuous monitoring of the surrounding areas. They locate fires through the detection of either hot spots (areas of increased temperature in comparison to the background) or smoke plumes produced by the fires. This article evaluates the use of existing remote sensing systems for active fire detection, with emphasis on the applicability of these systems for fire emergency management and fire-fighting. Long-range remote sensing devices on board satellites are considered, airborne systems are assessed, and short-range fire detection instruments on fixed ground platforms are reviewed. A short introduction to forthcoming satellite systems, which will be based on the combined use of several small satellites, is presented. The advantages and drawbacks of the different systems are evaluated from a fire management perspective.     

Rare-earth elements in groundwaters from the Osamu Utsumi mine and Morro do Ferro analogue study sites, Poços de Caldas, Brazil

Data are presented on rare-earth elements (REE) in prefiltered (<450 nm) near-surface and deeper groundwaters and in corresponding particulate matter (>450 nm) from the Osamu Utsumi uranium mine and the Morro do Ferro thorium-REE-deposit. Groundwaters from both sites typically contain between 1–50 μg/l of total REE, but can reach values of up to 160 μg/l in the deepest borehole F4 (U-Mine: 150–415 m). Even higher REE concentrations of up to 29 mg/l were measured in acidic, sulfate-rich near-surface waters of the same site. The chondrite-normalized REE patterns in deeper, more reducing groundwaters and in their corresponding suspended particle fractions are similar to those observed in the bedrock (phonolites), indicating that bedrock leaching and secondary mineral sorption occurred without significant fractionation between these elements, in accordance with the only small variations in the stability constants of the expected REE-sulfate complexes in these waters. Groundwaters from the unsaturated zone of both sites show a very characteristic cerium depletion (less pronounced than that observed in the corresponding suspended particulate fractions), which is most probably related to the oxidation of Ce (III) under the prevailing E_h-conditions of these waters (600 to 800 mV), and to sorption/precipitation reactions of the much less soluble Ce(IV) species. Coarse particulate matter (>450 nm), composed mainly of amorphous ferric hydrous oxides, has a strong capacity for sorption of REE. This is shown by its very high REE concentrations, in some boreholes > 8,000 μg/g (total REE), and by the calculated association ratios R_a (ml/g), which are in the order of 10⁵ to 10⁶. The implications of these findings for the migration behavior of REE in both environments are discussed.