A luminescence‐based chronology for the Harletz loess sequence,Bulgaria

The Harletz loess‐palaeosol sequence is located in northwestern Bulgaria and represents an important link between well‐studied loess sequences in eastern Romania and further sites to the west of the Carpathians (e.g. Serbia and Hungary). The aim of this study was to establish a chronostratigraphy of the deposits, using various methods of luminescence dating, together with basic stratigraphical field observations as well as magnetic properties. Luminescence dating was carried out using the quartz fine grain fraction and a SAR protocol, and the feldspar coarse grain fraction, applying the MET‐pIRIR protocol. Due to underestimation of the quartz fine grain fraction in the lower parts of the sequence, the resulting chronology is mainly based on the feldspar ages, which are derived from the stimulation temperature at 150 °C. A comparison with nearby sequences from Serbia, Hungary and Romania, and interpretations obtained through the stratigraphical and sedimentological signature of the sequence, supports the established chronology. Our data suggest that the prominent palaeosol (soil complex) in the upper quarter of the sequence was formed during MIS 5. It would follow that large parts of the Last Glacial loess overlying this palaeosol were probably eroded, and that the thick loess accumulation underlying this soil complex can be allocated to the penultimate glacial (MIS 6). A prominent MIS 6 tephra, which has been reported from other sequences in the area, is also present at Harletz.     

Sedimentary architecture of a glaciolacustrine braidplain delta: proxy evidence of a pre‐Middle Wisconsinan glaciation (Grimshaw gravels,Interior Plains,Canada)

The erosional nature of glacial systems commonly results in removal of direct evidence of previous glaciation (e.g. till and moraine). Therefore, reconstruction of former ice‐margin positions may rely, in part, on indirect (proxy) evidence from the sedimentary record. This study examines the facies and sedimentary architecture of a pre‐Middle Wisconsinan sand and gravel deposit (the ‘Grimshaw gravels’), which is positioned between areas where previous stratigraphical investigations have identified single (Late Wisconsinan) and multiple (pre‐Middle to Late Wisconsinan) glaciation by the Laurentide Ice Sheet. Five facies associations (FAs) are characterized within the deposit, which, together with the sedimentary architecture, record a transition from a braided river environment in the west (FA1‐3) to a gravelly braidplain delta front in the east (FA4 and 5). We propose that the Grimshaw gravels braid delta formed at the margin of a body of water that occupied the ancestral Peace River valley, probably impounded by the LIS; hence, the Grimshaw braid delta provides proxy evidence of the presence of an ice margin (previously unrecognized) in the Peace River lowland prior to the Middle Wisconsinan. This study provides further understanding of the origin of the Grimshaw gravels deposit, allowing re‐evaluation of previous models of formation. These findings offer insight into the glacial history of the southwestern margin of the LIS, and may help to refine ice‐sheet reconstructions spanning the Wisconsinan glaciation.     

BOCAIUVA—A SILICATE-INCLUSION BEARING IRON METEORITE RELATED TO THE EAGLE-STATION PALLASITES

Bocaiuva is a unique meteorite consisting of major metal having a high Ge/Ga ratio and minor (～ 50 mg/g) silicates. The silicates are generally chondritic and consist of major olivine (Fa.7.7) and orthopyroxene (Fs7.6) and minor plagioclase (Ab49, An49) and clinopyroxene (Fs4.5, Wo42). The low alkali content of the silicates is the only property inconsistent with a chondritic composition. Based on metal composition Bocaiuva seems distantly related to certain iron meteorites having similar Ge contents and similar Ge/Ga ratios, but detailed comparison with six such irons shows none to be closely related to Bocaiuva. Perhaps most closely related is Cold Bay, a member of the Eagle-Station trio of pallasites, but its composition is too different to suggest formation on the same parent body. Oxygen-isotope data show that Bocaiuva silicates are closely related to those in the Eagle-Station pallasites and to the CO and CV chondrites. The composition and texture of the Bocaiuva metal-silicate assembly indicate mixing in an impact event. We suggest that the Eagle-Station pallasites were also formed by impact heating rather than by a long-lived internal heat source.     

High-Frequency Response of the Atmospheric Electric Potential Gradient Under Strong and Dry Boundary-Layer Convection

The spectral response of atmospheric electric potential gradient gives important information about phenomena affecting this gradient at characteristic time scales ranging from years (e.g., solar modulation) to fractions of a second (e.g., turbulence). While long-term time scales have been exhaustively explored, short-term scales have received less attention. At such frequencies, space-charge transport inside the planetary boundary layer becomes a sizeable contribution to the potential gradient variability. For the first time, co-located (Évora, Portugal) measurements of boundary-layer backscatter profiles and the 100-Hz potential gradient are reported. Five campaign days are analyzed, providing evidence for a relation between high-frequency response of the potential gradient and strong dry convection.     

Tonian rift-related, A-type continental plutonism in the Araçuaí Orogen, eastern Brazil: New evidence for the breakup stage of the São Francisco–Congo Paleocontinent

Zircon U–Pb SHRIMP, petrographical and geochemical data lead to the first characterization of the Tonian plutonism (Salto da Divisa Granite Suite), ascribed to the continental rift stage of the precursor basin of the Araçuaí Orogen (Eastern Brazil). The suite includes batholitic plutons and comprises mainly fluorite-bearing, dominantly mesoperthitic hornblende–biotite leucogranites. The presence of mafic (tholeiitic) gabbroic enclaves and syn-plutonic dykes confers to the suite a bimodal character. The plutons were locally deformed and foliated under amphibolite facies conditions, in response to the Neoproterozoic collage of the Araçuaí Orogen against the São Francisco Cratonic margin. However, undeformed magmatic facies are well preserved at inner portions of the plutons. The granitoids are metaluminous, with high SiO₂ and HFSE: Nb, Zr, Y, Ta and REE (except Eu); low CaO, Al₂O₃, Sc, Ba, Sr; high FeOt/MgO ratios, characterizing a chemical signature akin to the subalkaline, A-2 type granites. U–Pb SHRIMP data obtained on zircons from the main pluton yielded a magmatic crystallization age of 875 ± 9 Ma. Some inherited xenocrysts revealed ages of ca. 2080 Ma, corresponding to ages of the host rocks, a Paleoproterozoic basement. Nd isotopic evolution studies confirm the Paleoproterozoic influence on magma genesis with a T_DM model age of ca. 1.6 Ga and ε_Nd of − 5.58 at 880 Ma. The African counterpart, the West Congo Belt, encompasses thick rift-related alkaline volcanic-sedimentary basin (Zadinian and Mayumbian groups, and associated anorogenic granites), dated in the interval of ca. 1000–900 Ma. The age differences between the Salto da Divisa Suite intrusion and the anorogenic magmatic episode at the West Congo Belt suggests a westward migration (i.e. to the Brazilian side) of the thermal axis of the rift, ca. 30 Ma after the ending of the extensional process in Africa.     

Magmatic Differentiation at an Island-arc Caldera: Okmok Volcano, Aleutian Islands, Alaska

Okmok volcano is situated on oceanic crust in the central Aleutianarc and experienced large (15 km³) caldera-forming eruptionsat 12 000 years BP and 2050 years BP. Each caldera-forming eruptionbegan with a small Plinian rhyodacite event followed by theemplacement of a dominantly andesitic ash-flow unit, whereaseffusive inter- and post-caldera lavas have been more basaltic.Phenocryst assemblages are composed of olivine + pyroxene +plagioclase ± Fe–Ti oxides and indicate crystallizationat 1000–1100°C at 0·1–0·2 GPain the presence of 0–4% H₂O. The erupted products followa tholeiitic evolutionary trend and calculated liquid compositionsrange from 52 to 68 wt % SiO₂ with 0·8–3·3wt % K₂O. Major and trace element models suggest that the moreevolved magmas were produced by 50–60% in situ fractionalcrystallization around the margins of the shallow magma chamber.Oxygen and strontium isotope data (¹⁸O 4·4–4·9,⁸⁷Sr/ ⁸⁶Sr 0·7032–0·7034) indicate interactionwith a hydrothermally altered crustal component, which led toelevated thorium isotope ratios in some caldera-forming magmas.This compromises the use of uranium–thorium disequilibria[(²³⁰Th/ ²³⁸U) = 0·849–0·964] to constrainthe time scales of magma differentiation but instead suggeststhat the age of the hydrothermal system is 100 ka. Modellingof the diffusion of strontium in plagioclase indicates thatmany evolved crystal rims formed less than 200 years prior toeruption. This addition of rim material probably reflects theremobilization of crystals from the chamber margins followingreplenishment. Basaltic recharge led to the expansion of themagma chamber, which was responsible for the most recent caldera-formingevent. KEY WORDS: Okmok; caldera; U-series isotopes; Sr-diffusion; time scales; Aleutian arc     

Environmental Policies Can Buttress Conservation Norms

In an attempt to solve large-scale environmental problems, government agencies often resort to formal sanctioning systems: market-based incentives or command-and-control regulations, to promote cooperation. The purpose of this study was to investigate how the presence of these formal sanctioning systems impacts informal sanctioning systems for environmental protection. Study 1 used an experimental game to explore the influence of market-based and regulatory programs on informal sanctioning in a laboratory setting. Study 2 was a quasi-experimental field survey that compared informal sanctioning among Massachusetts residents living in towns with voluntary, mandatory, and pay-as-you-throw recycling programs. Results showed that in the presence of a formal sanctioning system, individuals felt guiltier for not engaging in the cooperative behavior and expressed more disapproval for non-cooperators. Combined, these results show that environmental policies can buttress conservation norms.     

Migration velocity analysis using a genetic algorithm

Migration velocity analysis, a method for determining long wavelength velocity structure, is a critical step in prestack imaging. Solution of this inverse problem is made difficult by a multimodal objective function; a parameter space often vast in extent; and an evaluation procedure for candidate solutions, involving the calculation of depth-migrated image gathers, that can be prohibitively expensive. Recognizing the global nature of the problem, we employ a genetic algorithm (GA) in the search for the optimum velocity model. In order to describe a model efficiently, regions of smooth variation are identified and sparsely parametrized. Region boundaries are obtained via map migration of events picked on the zero-offset time section. Within a region, which may contain several reflectors, separate components describe long and short wavelength variations, eliminating from the parameter space, models with large velocity fluctuations. Vital to the success of the method is rapid model evaluation, achieved by generating image gathers only in the neighbourhood of specific reflectors. Probability of a model, which we seek to maximize, is derived from the flatness of imaged events. Except for an initial interpretation of the zero-offset time section, our method is automatic in that it requires no picking of residual moveout on migrated gathers. Using an example data set from the North Sea, we show that it is feasible to solve for all velocity parameters in the model simultaneously: the method is global in this respect also.     

Expansions of (r/a)m cos jv and (r/a)m sin jv to high eccentricities

Expansions of the functions (r/a)^cos jv and (r/a)m ^sin jv of the elliptic motion are extended to highly eccentric orbits, 0.6627 ... <e<1. The new expansions are developed in powers of (e–e*), wheree* is a fixed value of the eccentricity. The coefficients of these expansions are expressed in terms of the derivatives of Hansen's coefficients with respect to the eccentricity. The new expansions are convergent for values of the eccentricity such that |e–e*|<(e*), where the radius of convergence (e*) is the same of the extended solution of Kepler's equation. The new expansions are intrinsically related to Lagrange's series.