Metal partitioning in sediments and mineralogical controls on the acid mine drainage in Ribeira da Água Forte (Aljustrel,Iberian Pyrite Belt,Southern Portugal)

This work focuses on the geochemical processes taking place in the acid drainage in the Ribeira da Água Forte, located in the Aljustrel mining area in the Iberian Pyrite Belt. The approach involved water and stream sediment geochemical analyses, as well as other techniques such as sequential extraction, Mössbauer spectroscopy, and X-ray diffraction. Ribeira da Água Forte is a stream that drains the area of the old mine dumps of the Aljustrel mine, which have for decades been a source of acid waters. This stream flows to the north for a little over than 10 km, but mixes with a reduced, organic-rich, high pH waste water from the municipal waste water pools of the village. This water input produces two different results in the chemistry of the stream depending upon the season: (i) in the winter season, effective water mixing takes place, and the flux of acid water from the mine dumps is continuous, resulting in the immediate precipitation of the Fe from the acid waters; (ii) during the summer season, acid drainage is interrupted and only the waste water feeds the stream, resulting in the reductive dissolution of Fe hydroxides and hydroxysulfates in the stream sediments, releasing significant quantities of metals into solution. Throughout the year, water pH stays invariably within 4.0–4.5 for several meters downstream of this mixing zone even when the source waters come from the waste water pools, which have a pH around 8.4. The coupled interplay of dissolution and precipitation of the secondary minerals (hydroxides and sulfates), keeps the system pH between 3.9 and 4.5 all along the stream. In particular, evidence suggests that schwertmannite may be precipitating and later decomposing into Fe hydroxides to sustain the stream water pH at those levels. While Fe content decreases by 50% from solution, the most important trace metals are only slightly attenuated before the solution mixes with the Ribeira do Rôxo stream waters. Concentrations of As are the only ones effectively reduced along the flow path. Partitioning of Cu, Zn and Pb in the contaminated sediments also showed different behavior. Specific/non-specific adsorption is relevant for Cu and Zn in the upstream branch of Ribeira da Água Forte with acid drainage conditions, whereas the mixture with the waste water causes that the association of these metals with oxyhydroxide to be more important. Metals bound to oxyhydroxides are on the order of 60–70% for Pb, 50% for Cu and 30–60% for Zn. Organic matter is only marginally important around the waste water input area showing 2–8% Cu bound to this phase. These results also show that, although the mixing process of both acid and organic-rich waters can suppress and briefly mitigate some adverse effects of acid drainage, the continuing discharge of these waste waters into a dry stream promotes the remobilization of metals fixed in the secondary solid phases in the stream bed back into solution, a situation that can hardly be amended back to its original state.     

Impact of coal tar pavement on polycyclic hydrocarbon distribution in lacustrine sediments from non-traditional sources

The evaluation of potential environmental impacts from polycyclic aromatic hydrocarbon is a subject that requires investigation, especially related to emission sources from highway roads with high traffic. In this paper, the distribution of polycyclic aromatic hydrocarbons was investigated in the surface sediments from a subtropical lake, located in the south of Brazil and away from urban areas. The results showed that all sediments presented such compounds in significant concentration, ranging from 9.50 to 29.88???g/g. The highest total concentration was found in those sites close to the highway (bridges) and the deepest area of the lake. Moreover, a high concentration of polycyclic aromatic hydrocarbons of high molecular weight, such as benzo(a)anthracene and dibenzo(a,h)anthracene was found. It was laso found that high concentrations might be related to asphalt and coal tar pavement used in the highway construction close to the lake. In addition, the potential capacity of sediment toxicity was compared with values of the interim sediment quality guidelines values. The results indicate that most of the sediment presents concentrations of hydrocarbons above these limits. Only fluoranthene and chrysene were found in concentrations below the guideline values. The concentrations of most of the polycyclic hydrocarbons are higher than the quality guidelines. However, the main concern is associated with the presence of benzo(a)anthracene whose concentration is 416 times higher than the limit establisehed by guidelines. The same observation can be done to traces of benzo(a)pyrene and dibenz(a,h)anthracene, with concentration values of 13 and 1,993 times higher.     

A New Understanding of the Provinces of the Amazon Craton Based on Integration of Field Mapping and U-Pb and Sm-Nd Geochronology

New conventional and sensitive high-resolution ion microprobe zircon U-Pb dating has led to a new understanding of the subdivision and evolution of the Amazon Craton during Precambrian time, with major improvements and changes made to the previous Rb-Sr based model. The interpretation of U-Pb and Sm-Nd isotopic data identifies eight main Precambrian tectonic provinces in the Craton, with ages ranging from 3.1 to 0.99 Ga. Some of the provinces were generated by accretional, arc-related processes (Carajás, Transamazonic, Tapajós-Parima and Rondônia-Juruena) and others by recycling of continental crust (Central Amazon, Rio Negro and Sunsas). The exposed Archean crust is restricted to the east (Carajás and south Amapá in Brazil) and north (Imataca in Venezuela) of the craton, indicating that the Amazon Craton is largely a Proterozoic crust. The Carajás-Imataca (3.10–2.53 Ga) and Transamazonian (2.25–2.00 Ga) Provinces are composed predominantly of granite-greenstone terranes. The Tapajós-Parima (2.10–1.87 Ga) and Rondônia-Juruena (1.75–1.47 Ga) Provinces represent new crust added as orogenic belts, while the Rio Negro (1.86–1.52 Ga) and Sunsas (1.33–0.99 Ga) Provinces originated mainly by magmatic-tectonic recycling of the above two orogenic belts. The only zone with a prominent northeast trend is the poorly known K'Mudku Shear Belt, characterized by a 1.20 Ga shear zone which deforms the rocks of at least three different provinces (Rio Negro, Tapajós-Parima and Transamazonic). The Central Amazon Province comprises mostly Orosirian volcano-plutonic rocks (Uatumã Magmatism) and is a terrane in which the exposed crustal structure and deformation are pluton-related. The Sm-Nd T_DM model ages and _Nd suggest that the Central Amazon Province was generated by the partial melting of Archean continental crust (Carajás Province?), perhaps related to underplating that began at the end of the Tapajós-Parima Orogeny (1.88–1.86 Ga).     

The ultraviolet survey of the Gould Belt: general properties of the Taurus star forming region

The Gould Belt is the local superassociation of star formation. The age of the Belt is some few 10⁷ yr, henceforth, its population is dominated by luminous young OB associations and low mass pre-main sequence stars. Attempts to unveil the low mass population have been run making use of the ROSAT all-sky survey. The all sky ultraviolet survey run by the GALaxy Evolution eXplorer (GALEX) maps several regions in the Belt. In this contribution, we present the preliminary analysis of the UV stellar population towards the Taurus region, one of the nearest and best studied regions of star formation.     

Perceptions of environmental change in Moorea,French Polynesia: the importance of temporal,spatial, and scalar contexts

Pacific Islands are considered among the most vulnerable geographies and societies to the effects of climate change and variability (CCV). This study addresses the mismatch between global climate change narratives and local perceptions of environmental change in Moorea, French Polynesia. This study builds on CCV risk perception and adaptation research by analyzing how temporal and historical socio-economic, cultural, political, and ecological contexts shape local perceptions of environmental change among a sample of environmental stakeholders in Moorea. The data were collected prior to the widespread global narrative and social amplification of climate change risk and its particular impact on islands. As such, they offer an important portrait of environmental perceptions in French Polynesia prior to the influence of a circumscribed climate change narrative, which has since come to shape government and NGO responses to environmental change in the Pacific Island Countries and Territories. The data presented in this paper illustrate that perceptions of drivers and effects of environmental change and risk in Moorea are embedded in larger social processes of political economy and ecology, particularly related to contemporary environmental politics, contextualized within the histories of colonialism and tourism-led economic development. Integrating the complexity of local environmental risk perceptions into CCV policy will help to avoid maladaptation, social movements against CCV planning, and may help maximize government and donor investments.     

The atmospheric water as a triggering factor for earthquakes in the central Virginia seismic zone

Even though central Virginia is far from the nearest plate boundaries, the region is well-known for minor-to-moderate shocks, which have occurred frequently since at least the eighteenth century. Many of its people have experienced small earthquakes, while infrequent larger ones have caused damage. The largest destructive earthquake (magnitude 5.8) in this seismic zone was recorded in August 2011. Smaller earthquakes that cause little or no damage are felt each year or two. It is difficult to link the earthquakes of this zone to known small faults which are numerous, deeply buried and do not show up at the surface. The mean earthquake depth since 1960 is 6.7 km. On the other hand, central Virginia is a big collector and transporter of precipitation water, which flows to the Atlantic Ocean through the James River and its tributaries. There are about 2,000 abandoned mining sites in Virginia with underground openings that can facilitate the interception and conveyance of surface water. This paper presents evidence that seismic activity in certain zones can be associated clearly with the hydrological effects of abundant precipitation. Such effects can increase tectonic stress, which surpasses the marginal amount when an earthquake occurs. We analyze the cross-correlation between precipitation or water discharge in the rivers and earthquake occurrence in the central Virginia seismic zone. This correlation is examined both over a long-term span (57–92 years) and with regard to individual cases in which earthquakes have followed the occurrence of intense hydrological phenomena such as torrential rainfall or hurricanes. As we probe for a correlation between earthquake time series for central Virginia and the monthly precipitation series at hydrometeorological stations located in the zone, we observe that the best cross-correlation is obtained for a time period of 3 months. The same time period applies to certain historical earthquakes that were preceded by large amounts of precipitation. These results support the hydroseismicity hypothesis, which points to the role of water in the generation of intraplate seismicity.     

Lateral variation in structural style of mountain building: controls of rheological and rift inheritance

Many mountain belts exhibit significant along‐strike variation in structural style with changes in the width of the orogen, the geometry and kinematics of the crustal‐scale thrust system, and the degree of partitioning between pro‐ and retro‐wedge deformations. Although the main factors controlling first‐order structural style are understood, the cause of these lateral variations remains to be resolved. Here we focus on the Pyrenees, characterized by significant lateral variation in structural style with a thrust system involving more and thinner thrust sheets in the eastern section than in the western part. Similarly, the prior Mesozoic rifting event was characterized by significant lateral variation in structure. We integrate available geological and geophysical data with forward lithospheric scale numerical models. We show that lateral variation in crustal strength attributed to inherited Variscan crustal composition accentuated during Mesozoic rifting explains the variation in structural style observed during Pyrenean mountain building.     

Methodology to evaluate the renewal period of carbonate aquifers: a key tool for their management in arid and semiarid regions,with the example of Becerrero aquifer,Spain

A methodological procedure is proposed for determining the renewal period (RP), which expresses the ratio of total storage to recharge of carbonate aquifers, and it was applied to the overexploited moderate-size Becerrero carbonate aquifer (southern Spain). To this end, geological and subsurface data—time domain electromagnetic (TEM) soundings and borehole logs—were integrated to construct a three-dimensional (3D) geological model of the aquifer. The interconnected porosity was estimated by analyzing 73 rock samples. The resulting 3D geometrical model makes it possible to quantify the fractions of the aquifer having a confined or unconfined behaviour. Based on the total storage capacity (179?·?10⁶–514?·?10⁶ m³) and available aquifer recharge estimation (4.8?·?10⁶–6.4?·?10⁶ m³/year), an RP between 37 and 106 years is obtained. In view of the RP, an exploitation rate slightly lower than the average recharge of the system is recommended, so that the piezometric level will be stable but below the discharge head that is produced through the springs in natural conditions. The proposed methodology to obtain an aquifer RP and the management strategies designed accordingly are of broad interest, especially for carbonate aquifers, which are abundant in arid and semiarid regions.     

Measurements of volcanic SO2 and CO2 fluxes by combined DOAS,Multi-GAS and FTIR observations: a case study from Turrialba and Telica volcanoes

Over the past few decades, substantial progress has been made to overcome the technical difficulties of continuously measuring volcanic SO₂ emissions. However, measurements of CO₂ emissions still present many difficulties, partly due to the lack of instruments that can directly measure CO₂ emissions and partly due to its strong atmospheric background. In order to overcome these difficulties, a commonly taken approach is to combine differential optical absorption spectroscopy (DOAS) by using NOVAC scan-DOAS instruments for continuous measurements of crateric SO₂ emissions, and electrochemical/NDIR multi-component gas analyser system (multi-GAS) instruments for measuring CO₂/SO₂ ratios of excerpts of the volcanic plume. This study aims to quantify the representativeness of excerpts of CO₂/SO₂ ratios measured by Multi-GAS as a fraction of the whole plume composition, by comparison with simultaneously measured CO₂/SO₂ ratios using cross-crater Fourier transform infrared spectroscopy (FTIR). Two study cases are presented: Telica volcano (Nicaragua), with a homogenous plume, quiescent degassing from a deep source and ambient temperature, and Turrialba volcano (Costa Rica), which has a non-homogeneous plume from three main sources with different compositions and temperatures. Our comparison shows that in our “easier case” (Telica), FTIR and Multi-GAS CO₂/SO₂ ratios agree within a factor about 3 %. In our “complicated case” (Turrialba), Multi-GAS and FTIR yield CO₂/SO₂ ratios differing by approximately 13–25 % at most. These results suggest that a fair estimation of volcanic CO₂ emissions can be provided by the combination of DOAS and Multi-GAS instruments for volcanoes with similar degassing conditions as Telica or Turrialba. Based on the results of this comparison, we report that by the time our measurements were made, Telica and Turrialba were emitting approximately 100 and 1,000 t day^?1 of CO₂, respectively.