Doubtful Events Reported in Current Italian Earthquake Catalogues: The Medieval Earthquakes of Subiaco (Central Italy)

Within the framework of a study of the seismicity of the Aniene Valley (Central Italy), we analysed the medieval earthquakes of Subiaco (1216, 1227, 1299), the largest events reported for the area. Our main goal was to investigate some doubtful events reported in earthquake catalogues and, as such, currently utilised for seismic hazard estimates. A careful screening of the oldest available sources and their filiation pattern up to the present pointed out the uncertainty on the date and nature of these phenomena. A multidisciplinary approach based on the joint analysis of archaeological, geomorphologic and historical evidence allowed us to propose new interpretations concerning these events and their significance for the assessment of seismic hazard in the Aniene Valley. The main conclusion is that the dates of the 1216 and 1227 events are fairly unsupported. In particular, the 1216 earthquake could be dated back to between AD 1159 and 1181.     

The use of GPR and VES in delineating a contamination plume in a landfill site: a case study in SE Brazil

This paper presents the results of the application of the Ground Penetrating Radar (GPR) method, or Georadar, in outlining a zone of contamination due to solid residues at the waste burial site of Rio Claro in the state of São Paulo, SE Brazil. A total of eight GPR profiles with 50- and 100-MHz antennae were surveyed. Six profiles were located within the landfill site and the remaining two were outside. The main objective of the GPR survey was to evaluate the side extension of contamination. A Vertical Electric Sounding (VES) survey was performed at four points within the site in order to investigate the vertical extent of the contamination plume and to define the bottom of the landfill. Two additional VESs were done outside the landfill with the purpose of determining the top of the ground water table and the geoelectric stratigraphy of the background. From the interpretation of the GPR profiles, it was possible to locate the top of the contamination plume and to infer that it was migrating laterally beyond the limits of the waste disposal site. This was observed along the profile situated close to the highway SP-127, which was about 20 m from the limit of the site. The signature of the contaminant appears as a discontinuous reflector that is believed to be a shallow ground water table. The discontinuity is marked by a shadow zone, which is characteristic of conductive contaminant residues. The contamination did not move far enough to reach a sugar cane plantation located at approximately 100 m from the border of the site. In the regions free from contamination, the ground water table was mapped at approximately 10 m of depth, and it was characterized by a strong and continuous reflector. The radar signal penetrated deep enough and enabled the identification of a second reflector at approximately 14 m deep, interpreted as the contact between the Rio Claro and the Corumbataí formations. The contact is marked by the presence of gravel characterized by ferruginous concretes, which cause the strong amplitude reflection in the GPR profile. Within the landfill site, the quantitative interpretation of the VES results showed the contamination zone. The base of the landfill varies between 11 and 15 m deep. Outside the landfill site, the VES results showed no indication of contamination and allowed the determination of the top of the ground water table and the contact between the Rio Claro and the Corumbataí formations. The results of GPR and VES showed a good agreement and the integrated interpretations were supported by local geology and information from several boreholes, about 17 m depth, on average. The bottom of the landfill reaches a maximum of 14.5 m depth.     

Sedimentology and palynology of the Calafate Formation (Maastrichtian), Austral Basin, Southern Patagonia, Argentina

The Calafate Formation crops out in south-western Santa Cruz Province, Argentina, and displays a stacking of asymmetrical coarsening–fining-upward cycles. These cycles are interpreted as the product of short-lived transgressive-regressive events in which the coarsening upward part represents sedimentary aggradation with a stable or decreasing sea level. Sedimentological and palynological analyses indicate nearshore marine conditions. Even though the existence of an estuary or incised valley cannot be determined, this is the most probable palaeogeographic model. Based on dinoflagellate cysts, the base of the section is considered to be not older than Maastrichtian. The presence of the oyster Ambigostrea clarae (Ihering) occurring together with the dinoflagellate cyst species Manumiella druggii (Stover) Bujak and Davies and Eisenackia circumtabulata Drugg in the middle part of the section indicates an age no older than late Maastrichtian. According to sedimentological data, deposits representing the Cretaceous–Palaeogene transition would have been eroded, which is confirmed by the presence of Grapnelispora loncochensis Papú. This megaspore is a consistent component of the Maastrichtian assemblages from Patagonia.     

Seismic studies of the Brasília fold belt at the western border of the São Francisco Craton, Central Brazil, using receiver function, surface-wave dispersion and teleseismic tomography

The Tocantins Province in Central Brazil is composed of a series of SSW–NNE trending terranes of mainly Proterozoic ages, which stabilized in the Neoproterozoic in the final collision between the Amazon and São Francisco cratons. No previous information on crustal seismic properties was available for this region. Several broadband stations were used to study the regional patterns of crustal and upper mantle structure, extending the results of a recent E–W seismic refraction profile. Receiver functions and surface wave dispersion showed a thin crust (33–37 km) in the Neoproterozoic Magmatic Arc terrane. High average crustal Vp/Vs ratios (1.74–1.76) were consistently observed in this unit. The foreland domain of the Brasília foldbelt, on the other hand, is characterized by thicker crust (42–43 km). Low Vp/Vs ratios (1.70–1.72) were observed in the low-grade foreland fold and thrust zone of the Brasília belt adjacent to the São Francisco craton. Teleseismic P-wave tomography shows that the lithospheric upper mantle has lower velocities beneath the Magmatic Arc and Goiás Massif compared with the foreland zone of the belt and São Francisco craton. The variations in crustal thickness and upper mantle velocities observed with the broadband stations correlate well with the measurements along the seismic refraction profile. The integration of all seismic observations and gravity data indicates a strong lithospheric contrast between the Goiás Massif and the foreland domain of the Brasília belt, whereas little variation was found across the foldbelt/craton surface boundary. These results support the hypothesis that the Brasília foreland domain and the São Francisco craton were part of a larger São Francisco-Congo continental plate in the final collision with the Amazon plate.     

A constrained 2D gravity model of the Sebastián Vizcaíno Basin, Baja California Sur, Mexico

The subsurface geometry of the Sebastián Vizcaíno Basin is obtained from the 2D inversion of gravity data, constrained by a density-versus-depth relationship derived from an oil exploration deep hole. The basin accumulated a thick pile of marine sediments that evolved in the fore-arc region of the compressive margin prevalent along western North America during Mesozoic and Tertiary times. Our interpretation indicates that the sedimentary infill in the Sebastián Vizcaíno Basin reaches a maximum thickness of about 4 km at the centre of a relatively symmetric basin. At the location of the Suaro-1 hole, the depth to the basement derived from this work agrees with the drilled interface between calcareous and volcaniclastic members of the Alisitos Formation. A sensitivity analysis strongly suggests that the assumed density function leads to a nearly unique solution of the inverse problem.     

Macroseismic Intensity Modelling of Earthquakes in Southern Spain: Attenuation and Tectonic Implications

A modelling of the observed macroseismic intensity of historical and instrumental earthquakes in southern Spain is proposed, with the aim of determining the macroseismic parameters for seismic hazard evaluation in a region in which the characterization of intensity distribution of seismic events shows different levels of difficulty referable to the complex faults system of the area in study. The adopted procedure allows an analytical determination of epicenters and principal attenuation directions of earthquakes with a double level of verification with reference to the maximum shaking area and structural lineaments of the region, respectively. The analyses, carried out on a suitable number of events, highlight, therefore, some elements for a preliminary characterization of a seismic zonation on the basis of the consistency between seismic intensity distribution of earthquakes and corresponding structural framework.     

Effect of heat treatment on tourmaline from Brazil

The crystal-chemical behaviour of tourmaline from Araçuaí, Minas Gerais state, Brazil, when subjected to heating in air atmosphere has been studied by several techniques, including EMPA, UV–Vis, TGA, and Mössbauer spectroscopy. The tourmaline samples are typically intermediate members of the elbaite-schorl series. The origin of colour and of its change after treatment has been discussed in terms of local disorder, presence of metal transition elements, oxidation of ferrous iron at the octahedral site, and simultaneous trap of the excess electron. These findings may be used to enhance the colour in tourmaline crystals or generate wanted colour changes.     

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

Residual Exchange Flows in Subtropical Estuaries

Observations of residual exchange flows at the entrance to four subtropical estuaries, two of them semiarid, indicate that these flows are mainly tidally driven, as they compare favorably with theoretical patterns of tidal residual flows. In every estuary examined, the tidal behavior was that of a standing or near-standing wave, i.e., tidal elevation and tidal currents were nearly in quadrature. The pattern of exchange flow that persisted at every estuary exhibited inflow in the channel and outflow over the shoals. Curiously, but also fortuitously, this pattern coincides with the exchange pattern driven by density gradients in other estuaries. The tidal stresses and the residual elevation slopes should be the dominant mechanisms that drive such tidal residual pattern because the Stokes transport mechanism is negligible for standing or near-standing waves. Time series measurements from the semiarid estuaries showed fortnightly modulation of the residual flow by tidal forcing in such a way that the strongest net exchange flows developed with the largest tidal distortions, i.e., during spring tides. This modulation is opposite to the modulation that typically results in temperate estuaries, where the strongest net exchange flows tend to develop during neap tides. The fortnightly modulation on tidal residual currents could be inferred from previous theoretical results because residual currents arise from tidal distortions but is made explicit in this study. The findings advanced herein should allow the drawing of generalities about exchange flow patterns in subtropical estuaries where residual flows are mainly driven by tides.