Dasymetric Spatiotemporal Interpolation

This research applies the principles of dasymetric mapping to spatiotemporal interpolation by extending the spatial concepts of zone and area to their temporal analogs of interval and duration, respectively. An example application of dasymetric spatiotemporal interpolation using crime event data is presented. Results indicate that dasymetric spatiotemporal interpolation significantly improves the accuracy of estimates over areal or duration weighting. In addition, even when dasymetric interpolation in either the spatial or temporal dimension is relatively weak, combining dasymetric estimation in both space and time dimensions simultaneously has the potential to amplify the accuracy of the overall dasymetric estimation.     

Mineralogy and petrogenesis of lunar magnesian granulitic meteorite Northwest Africa 5744

Lunar meteorite Northwest Africa (NWA) 5744 is a granulitic breccia with an anorthositic troctolite composition that may represent a distinct crustal lithology not previously described. This meteorite is the namesake and first‐discovered stone of its pairing group. Bulk rock major element abundances show the greatest affinity to Mg‐suite rocks, yet trace element abundances are more consistent with those of ferroan anorthosites. The relatively low abundances of incompatible trace elements (including K, P, Th, U, and rare earth elements) in NWA 5744 could indicate derivation from a highlands crustal lithology or mixture of lithologies that are distinct from the Procellarum KREEP terrane on the lunar nearside. Impact‐related thermal and shock metamorphism of NWA 5744 was intense enough to recrystallize mafic minerals in the matrix, but not intense enough to chemically equilibrate the constituent minerals. Thus, we infer that NWA 5744 was likely metamorphosed near the lunar surface, either as a lithic component within an impact melt sheet or from impact‐induced shock.     

Seasonal and inter-annual relationships between vegetation and climate in central New Mexico, USA

Linear correlations between seasonal and inter-annual measures of meteorological variables and normalized difference vegetation index (NDVI) are calculated at six nearby yet distinct vegetation communities in semi-arid New Mexico, USA Monsoon season (June–September) precipitation shows considerable positive correlation with NDVI values from the contemporaneous summer, following spring, and following summer. Non-monsoon precipitation (October–May), temperature, and wind display both positive and negative correlations with NDVI values. These meteorological variables influence NDVI variability at different seasons and time lags. Thus vegetation responds to short-term climate variability in complex ways and serves as a source of memory for the climate system.     

Age and tectonomagmatic setting of the Eocene Çöpler–Kabataş magmatic complex and porphyry-epithermal Au deposit, East Central Anatolia, Turkey

The Çöpler epithermal Au deposit and related subeconomic porphyry Cu–Au deposit is hosted by the middle Eocene Çöpler–Kabata? magmatic complex in central eastern Anatolia. The intrusive rocks of the complex were emplaced into Late Paleozoic–Mesozoic metamorphosed sedimentary basement rocks near the northeastern margin of the Tauride-Anatolide Block. Igneous biotite from two samples of the magmatic complex yielded ⁴⁰Ar/³⁹Ar plateau ages of 43.75?±?0.26 Ma and 44.19?±?0.23, whereas igneous hornblende from a third sample yielded a plateau age of 44.13?±?0.38. These ages closely overlap with ⁴⁰Ar/³⁹Ar ages of hydrothermal sericite (44.44?±?0.28 Ma) and biotite (43.84?±?0.26 Ma), and Re–Os ages from two molybdenite samples (44.6?±?0.2 and 43.9?±?0.2 Ma) suggesting a short-lived (<1 my) magmatic and hydrothermal history at Çöpler. No suitable minerals were found that could be used to date the epithermal system, but it is inferred to be close in age to the precursor porphyry system. The Çöpler–Kabata? intrusive rocks show I-type calc-alkaline affinities. Their normalized trace element patterns show enrichments in large ion lithophile and light rare earth elements and relative depletions in middle and heavy rare earth elements, resembling magmas generated in convergent margins. However, given its distance from the coeval Eocene Maden–Helete volcanic arc, the complex is interpreted to be formed in a back-arc setting, in response to Paleocene slab roll-back and upper-plate extension. The tectonomagmatic environment of porphyry-epithermal mineralization at Çöpler is comparable to some other isolated back-arc porphyry systems such as Bajo de la Alumbrera (Argentina) or Bingham Canyon (USA).     

Enthalpies and entropies of proton and cadmium adsorption onto Bacillus subtilis bacterial cells from calorimetric measurements

We used titration calorimetry to measure the bulk heats of proton and Cd adsorption onto a common Gram positive soil bacterium Bacillus subtilis at 25.0 °C. Using the 4-site non-electrostatic model of Fein et al. [Fein, J.B., Boily, J.-F., Yee, N., Gorman-Lewis, D., Turner, B.F., 2005. Potentiometric titrations of Bacillus subtilis cells to low pH and a comparison of modeling approaches. Geochim. Cosmochim. Acta69 (5), 1123-1132.] to describe the bacterial surface reactivity to protons, our bulk enthalpy measurements can be used to determine the following site-specific enthalpies of proton adsorption for Sites 1-4, respectively: −3.5 ± 0.2, −4.2 ± 0.2, −15.4 ± 0.9, and −35 ± 2 kJ/mol, and these values yield the following third law entropies of proton adsorption onto Sites 1-4, respectively: +51 ± 4, +78 ± 4, +79 ± 5, and +60 ± 20 J/mol K. An alternative data analysis using a 2-site Langmuir-Freundlich model to describe proton binding to the bacterial surface (Fein et al., 2005) resulted in the following site-specific enthalpies of proton adsorption for Sites 1 and 2, respectively: −3.6 ± 0.2 and −35.1 ± 0.3 kJ/mol. The thermodynamic values for Sites 1-3 for the non-electrostatic model and Site 1 of the Langmuir-Freundlich model of proton adsorption onto the bacterial surface are similar to those associated with multifunctional organic acid anions, such as citrate, suggesting that the protonation state of a bacterial surface site can influence the energetics of protonation of neighboring sites. Our bulk Cd enthalpy data, interpreted using the 2-site non-electrostatic Cd adsorption model of Borrok et al. [Borrok, D., Fein, J.B., Tischler, M., O’Loughlin, E., Meyer, H., Liss, M., Kemner, K.M., 2004b. The effect of acidic solutions and growth conditions on the adsorptive properties of bacterial surfaces. Chem. Geol.209 (1-2), 107-119.] to account for Cd adsorption onto B. subtilis, yield the following site-specific enthalpies of Cd adsorption onto bacterial surface Sites 2 and 3, respectively: −0.2 ± 0.4 and +14.4 ± 0.9 kJ/mol, and the following third law entropies of Cd adsorption onto Sites 2 and 3, respectively: +57 ± 4 and +128 ± 5 J/mol K. The calculated enthalpies of Cd adsorption are typical of those associated with Cd complexation with anionic oxygen ligands, and the entropies are indicative of inner sphere complexation by multiple ligands. The experimental approach described in this study not only yields constraints on the molecular-scale mechanisms involved in proton and Cd adsorption reactions, but also provides new thermodynamic data that enable quantitative estimates of the temperature dependence of proton and Cd adsorption reactions.     

The impact of natural hazards on the health sector in the Caribbean: Implications for health sector planning

In the last decade significant initiatives have been taken in the health sector with the view to better manage and respond to natural disaster emergencies. However, the recent hurricane disasters related to Hugo and Gilbert have highlighted many areas of health sector emergency planning still to be adressed. This paper briefly summarises the impact of recent natural disaster on the health sector in the Caribbean and comments on the performance of the sector during the emergencies. An effort is then made to detail what are the policy and programming issues to be tackled, if desired improvements are to be achieved.The reader may like to see GeoJournal vol. 23, no. 4 (April 1991) on Caribbean Hurricanes     

Recent progress on combining geomorphological and geochronological data with ice sheet modelling,demonstrated using the last British–Irish Ice Sheet

Palaeo-ice sheets are important analogues for understanding contemporary ice sheets, offering a record of ice sheet behaviour that spans millennia. There are two main approaches to reconstructing palaeo-ice sheets. Empirical reconstructions use the available glacial geological and chronological evidence to estimate ice sheet extent and dynamics but lack direct consideration of ice physics. In contrast, numerically modelled simulations implement ice physics, but often lack direct quantitative comparison with empirical evidence. Despite being long identified as a fruitful scientific endeavour, few ice sheet reconstructions attempt to reconcile the empirical and model-based approaches. To achieve this goal, model-data comparison procedures are required. Here, we compare three numerically modelled simulations of the former British–Irish Ice Sheet with the following lines of evidence: (a) position and shape of former margin positions, recorded by moraines; (b) former ice-flow direction and flow-switching, recorded by flowsets of subglacial bedforms; and (c) the timing of ice-free conditions, recorded by geochronological data. These model–data comparisons provide a useful framework for quantifying the degree of fit between numerical model simulations and empirical constraints. Such tools are vital for reconciling numerical modelling and empirical evidence, the combination of which will lead to more robust palaeo-ice sheet reconstructions with greater explicative and ultimately predictive power.     

An empirical model of subcritical bedform migration

The ability to predict bedform migration in rivers is critical for estimating bed material load, yet there is no relation for predicting bedform migration (downstream translation) that covers the full range of conditions under which subcritical bedforms develop. Here, the relation between bedform migration rates and transport stage is explored using a field and several flume data sets. Transport stage is defined as the non‐dimensional Shields stress divided by its value at the threshold for sediment entrainment. Statistically significant positive correlations between both ripple and dune migration rates and transport stage are found. Stratification of the data by the flow depth to grain‐size ratio improved the amount of variability in migration rates that was explained by transport stage to ca 70%. As transport stage increases for a given depth to grain‐size ratio, migration rates increase. For a given transport stage, the migration rate increases as the flow depth to grain‐size ratio gets smaller. In coarser sediment, bedforms move faster than in finer sediment at the same transport stage. Normalization of dune migration rates by the settling velocity of bed sediment partially collapses the data. Given the large amount of variability that arises from combining data sets from different sources, using different equipment, the partial collapse is remarkable and warrants further testing in the laboratory and field.     

High- and low-affinity binding sites for Cd on the bacterial cell walls of Bacillus subtilis and Shewanella oneidensis

Bulk Cd adsorption isotherm experiments, thermodynamic equilibrium modeling, and Cd K edge EXAFS were used to constrain the mechanisms of proton and Cd adsorption to bacterial cells of the commonly occurring Gram-positive and Gram-negative bacteria, Bacillus subtilis and Shewanella oneidensis, respectively. Potentiometric titrations were used to characterize the functional group reactivity of the S. oneidensis cells, and we model the titration data using the same type of non-electrostatic surface complexation approach as was applied to titrations of B. subtilis suspensions by Fein et al. (2005). Similar to the results for B. subtilis, the S. oneidensis cells exhibit buffering behavior from approximately pH 3-9 that requires the presence of four distinct sites, with pK_a values of 3.3 ± 0.2, 4.8 ± 0.2, 6.7 ± 0.4, and 9.4 ± 0.5, and site concentrations of 8.9(±2.6) × 10⁻⁵, 1.3(±0.2) × 10⁻⁴, 5.9(±3.3) × 10⁻⁵, and 1.1(±0.6) × 10⁻⁴ moles/g bacteria (wet mass), respectively. The bulk Cd isotherm adsorption data for both species, conducted at pH 5.9 as a function of Cd concentration at a fixed biomass concentration, were best modeled by reactions with a Cd:site stoichiometry of 1:1. EXAFS data were collected for both bacterial species as a function of Cd concentration at pH 5.9 and 10 g/L bacteria. The EXAFS results show that the same types of binding sites are responsible for Cd sorption to both bacterial species at all Cd loadings tested (1-200 ppm). Carboxyl sites are responsible for the binding at intermediate Cd loadings. Phosphoryl ligands are more important than carboxyl ligands for Cd binding at high Cd loadings. For the lowest Cd loadings studied here, a sulfhydryl site was found to dominate the bound Cd budgets for both species, in addition to the carboxyl and phosphoryl sites that dominate the higher loadings. The EXAFS results suggest that both Gram-positive and Gram-negative bacterial cell walls have a low concentration of very high-affinity sulfhydryl sites which become masked by the more abundant carboxyl and phosphoryl sites at higher metal:bacteria ratios. This study demonstrates that metal loading plays a vital role in determining the important metal-binding reactions that occur on bacterial cell walls, and that high affinity, low-density sites can be revealed by spectroscopy of biomass samples. Such sites may control the fate and transport of metals in realistic geologic settings, where metal concentrations are low.     

Evaluating Subsurface Parameterization to Simulate Hyporheic Exchange: The Steinlach River Test Site

Hyporheic exchange is the interaction of river water and groundwater, and is difficult to predict. One of the largest contributions to predictive uncertainty for hyporheic exchange has been attributed to the representation of heterogeneous subsurface properties. Our study evaluates the trade-offs between intrinsic (irreducible) and epistemic (reducible) model errors when choosing between homogeneous and highly complex subsurface parameter structures. We modeled the Steinlach River Test Site in Southwest Germany using a fully coupled surface water-groundwater model to simulate hyporheic exchange and to assess the predictive errors and uncertainties of transit time distributions. A highly parameterized model was built, treated as a “virtual reality” and used as a reference. We found that if the parameter structure is too simple, it will be limited by intrinsic model errors. By increasing subsurface complexity through the addition of zones or heterogeneity, we can begin to exchange intrinsic for epistemic errors. Thus, the appropriate level of detail to represent the subsurface depends on the acceptable range of intrinsic structural errors for the given modeling objectives and the available site data. We found that a zonated model is capable of reproducing the transit time distributions of a more detailed model, but only if the geological structures are known. An interpolated heterogeneous parameter field (cf. pilot points) showed the best trade-offs between the two errors, indicating fitness for practical applications. Parameter fields generated by multiple-point geostatistics (MPS) produce transit time distributions with the largest uncertainties, however, these are reducible by additional hydrogeological data, particularly flux measurements.