Groundwater Impacts from the M5.8 Earthquake in Korea as Determined by Integrated Monitoring Systems

This paper describes the impacts of the M5.8(5.1) Gyeongju earthquakes on groundwater levels using data obtained from a unique coastal monitoring well. The monitoring strategy integrates conventional water level monitoring with periodic, continuous measurements of temperature and electrical conductivity (EC) within the water column of the well. Another important component of the monitoring system is a new instrument, the InterfacEGG, which is capable of dynamically tracking the freshwater-saltwater interface. Although the system was set up to monitor seawater intrusion related to over-pumping, as well as rainfall and tidal effects, it recorded impacts associated with a large earthquake and aftershocks approximately 241 km away. Seismic energies associated with the M5.8(5.1) Gyeongju earthquakes induced groundwater flows to the monitoring well through fractures and joints in the crystalline basement rocks. Temperature and EC logging data showed that the EC vertical profile declined from an average of approximately 5300 to 4800 μS/cm following the earthquakes. The temperature profile showed a trend toward lower temperatures as the depth increased, a feature not commonly observed in previous studies. Data from the InterfacEGG suggested that the rise in EC was not due to the saltwater intrusion, but from the tendency for brackish water entering the borehole to induce convective mixing at deeper depths as the seismic waves travel through the well-aquifer system. The increase in groundwater levels was caused by pulse of colder, less brackish water flowing into the well because of the earthquake. This behavior reflects an enhancement in rock permeability by removing precipitates and colloidal particles from clogged fractures, which improve the hydraulic connection with a nearby unit with a higher hydraulic head. This study suggests there is value added with a more aggressive monitoring strategy.     

Natural Stimuli Calibration with Fining Direction Regularization in an Integrated Hydrologic Model

The interaction between surface water and groundwater during flood events is a complex process that has traditionally been described using simplified analytical solutions, or abstracted numerical models. To make the problem tractable, it is common to idealize the flood event, simplify river channel geometry, and ignore bank soil heterogeneity, often resulting in a model that only loosely represents the site, thus limiting its applicability to any specific river cross-section. In this study, we calibrate a site-specific fully-integrated surface and subsurface HydroGeoSphere model using flood events for a cross-section along the South River near Waynesboro, VA. The calibration approach presented in this study demonstrates the incorporation of fining direction regularization with a highly parameterized inversion driven by natural stimuli, to develop several realistic realizations of hydraulic conductivity fields that reflect the depositional history of the system. Specifically, we calibrate a model with 365 unique material zones to multiple flood events recorded in a dense well network while incorporating possible fining sequences consistent with the depositional history of the riverbank. Over 25,000 individual simulations were completed using calibration software and a cloud platform specifically designed for highly parallelized computing environments. The results of this study demonstrate the use of fining direction regularization during model calibration to generate multiple calibrated model realizations that account for the depositional environment of the system.     

Desorption of Hydrophobic Organic Chemicals from Fragment-Type Microplastics

Microplastics provide an important medium for hydrophobic organic chemicals (HOCs), and the desorption of HOCs from microplastics is an important process for the dynamics of HOCs associated with microplastics. Although desorption kinetics has been studied for microplastics with ideal geometries, most of the microplastics isolated from the environment are irregular fragment-type microplastics. This study investigated the desorption of six model HOCs from polyethylene (PE) and polypropylene (PP) fragments to artificial seawater and compared the results with those predicted assuming ideal geometries (e.g., sphere and infinitely flat sheet) of microplastics. The experimental desorption was explained well by the model predictions with the characteristic radius for a sphere and the thickness for a plate estimated from visual imaging. The mass fraction remaining at the later stage of desorption was higher than the model simulation assuming a single characteristic length, likely due to the heterogeneity of the particle size distribution. Although there are inevitable uncertainties, it would be useful to assign a single length dimension in desorption modeling for even fragment-type microplastics, especially for the estimation of desorption half-life.     

Precise orbit determination for the FORMOSAT-3/COSMIC satellite mission using GPS

The joint Taiwan–US mission FORMOSAT-3/ COSMIC (COSMIC) was launched on April 17, 2006. Each of the six satellites is equipped with two POD antennas. The orbits of the six satellites are determined from GPS data using zero-difference carrier-phase measurements by the reduced dynamic and kinematic methods. The effects of satellite center of mass (COM) variation, satellite attitude, GPS antenna phase center variation (PCV), and cable delay difference on the COSMIC orbit determination are studied. Nominal attitudes estimated from satellite state vectors deliver a better orbit accuracy when compared to observed attitude. Numerical tests show that the COSMIC COM must be precisely calibrated in order not to corrupt orbit determination. Based on the analyses of the 5 and 6-h orbit overlaps of two 30-h arcs, orbit accuracies from the reduced dynamic and kinematic solutions are nearly identical and are at the 2–3 cm level. The mean RMS difference between the orbits from this paper and those from UCAR (near real-time) and WHU (post-processed) is about 10 cm, which is largely due to different uses of GPS ephemerides, high-rate GPS clocks and force models. The kinematic orbits of COSMIC are expected to be used for recovery of temporal variations in the gravity field.     

Evolution of the Dok Do seamounts,Ulleung Basin,East Sea: constraints based on the reconstruction of virtual geomagnetic poles using paleomagnetic data

In the Ulleung Basin, East Sea, the Dok Do seamount group comprises Dok Do (Dok Island), consisting of very small islets/rocks and a large submerged volcanic edifice, and two voluminous tablemounts, Simheungtaek and Isabu. We attempted to reconstruct the evolution of these seamounts, using virtual geomagnetic poles (VGPs) determined by the least-squares and the seminorm magnetization methods, with 1,500 m upward continued magnetic anomalies. The VGPs of Dok Do with normal dipole anomaly, and of Simheungtaek with normal dipole anomaly are located near the present magnetic pole. The VGP of Isabu with normal dipole anomaly is located at low latitude, presumably due to overprints of reversals in the Tertiary, and the distortion of magnetization and structures associated with volcanism after its formation. In contrast to the tablemounts, magnetic anomalies over Dok Do are a combination of both normal polarity and reversed polarity dipoles in the northern hemisphere, indicating that Dok Do has had at least two major eruptions, one during normal and another during reversed polarity intervals. From these results, and information on the ages of the seamounts (either published radiometric ages of subaerial volcanic rocks, or ages reconstructed in terms of reported elastic thickness incorporated into an existing cooling plate model), we tentatively propose that (1) Isabu formed first, during a normal polarity interval after the opening of the East Sea had ceased; (2) this was followed by an initial and subsequent large eruption of Dok Do during a normal polarity and a reversed polarity interval after about 5 Ma; and (3) the formation of Simheungtaek occurred in between that of Isabu and Dok Do in a normal polarity interval. The pattern of normal/reversed magnetization is not inconsistent with the geomagnetic polarity timescale for at least the last 5 Ma. Nevertheless, precise ages of formation would need verification by additional geophysical/geochemical constraints. Evaluating various possible models explaining the successive formation of the Dok Do seamounts, we currently favor fracturing and volcanism related to compression-induced weakening of the extensional field from the late Miocene to Pliocene after the opening of the East Sea.     

Experiences with constructed wetland systems in Korea

In spite of the low temperature during the winter season and the high land environment, the wetland treatment system is gaining popularity in Korea because of its lower construction cost and simplicity in operation and maintenance. Many different types of wetland treatment systems have been built during the last 10 years, among which the free water surface wetland has been predominant. Most of the large-scale systems are government projects for improving the water quality of the streams flowing into the estuary dikes and reservoirs. The covering plants used in this system are different in different areas but cattails and reeds or their combinations are common. Constructed wetlands in Korea can be characterized by their shallow depths and short hydraulic residence times. There is no established flow pattern and configuration rules for constructing wetlands, but many efforts have been made with a view to improving their ecological function. Flow control is the most difficult problem in designing a riverbed or riparian wetland. There have been scores of flow rate control devices developed for wetlands, but none of them guarantee wetlands＇ safety against flooding. In earlier wetland construction, the building materials were mainly soil. Recently, strong and durable building materials such as rocks, gravel beds, concrete and steel are used at vulnerable places to protect them from erosion. Our investigation indicated that the wetland system would be an appropriate technology because it is not only cheaper to construct, but also requires less maintenance work. However, we suffer from the reduced effectiveness in performance during the winter. We need to evaluate the partial treatment accomplished during 6 to 7 months per year.     

Comparison of volatile organic compounds in stormwater and groundwater in Seoul metropolitan city,South Korea

Volatile organic compounds (VOCs) detected in stormwater were compared with VOCs present in emission sources, air, groundwater, and influent to sewage treatment plants in Seoul to understand their fate and transport in the urban hydrological system. Stormwater is a carrier of non-point source pollutants and contains VOCs from land surfaces and air. Samples of stormwater and influent to sewage treatment plants were collected and analyzed for 61 VOCs, while the VOCs in emission sources, air and groundwater were investigated through literature reviews for comparison. The results showed that the most frequently detected VOCs in stormwater were similar to those in air. However, the atmospheric concentrations of benzene, toluene, ethylbenzene, and xylenes (BTEX), and methyl tertiary-butyl ether (MTBE) were too low to explain their frequent detection and high concentrations in stormwater. As a result, land surfaces seem to be a primary source of these VOCs in stormwater. Comparison of the VOCs in stormwater and groundwater showed that toluene and MTBE were frequently detected in both media, but more often and at higher concentrations in stormwater. This finding indicates that stormwater recharge is a source of toluene and MTBE in groundwater. Regarding groundwater, land surfaces seem to be a primary source of toluene, while urban air is the primary source in the case of MTBE. Specifically, the MTBE values in air were sufficiently high to explain its levels in groundwater, which had continually increased and remained low afterward. Furthermore, the high ratios of TEX (toluene, ethylbenzene, and xylenes) to benzene and MTBE in stormwater indicated that TEX had additional sources other than vehicles, most likely hydrocarbon solvents. These solvents seem to be a primary source of TEX and other frequently detected VOCs in stormwater. However, trichloroethylene (TCE), tetrachloroethylene (PCE) and their dechlorination intermediates were far more frequently detected and at higher concentrations in groundwater than in stormwater. Additionally, their concentrations frequently exceeded the water-quality criteria. It seems that halogenated solvents had produced contamination plumes of these chlorinated VOCs in the Seoul aquifer. Based on VOCs detected in Seoul, stormwater was mixed with groundwater in combined sewers and flowed into sewage treatment plants. The results imply that organic solvents should be handled with extreme care to protect groundwater quality.     

Biomagnification of persistent chlorinated and brominated contaminants in food web components of the Yellow Sea

Concentrations of polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polybrominated diphenyl ethers (PBDEs) were measured in 32 species inhabiting the Yellow Sea to assess their bioaccumulation potentials. The concentrations in these samples were lower than those reported for other countries or locations. Relatively high levels of BDE 209 in biota suggest an ongoing source of deca-BDE technical mixing within the Yellow Sea. The accumulation profiles of PCBs were uniform between species, but the concentrations of OCPs and PBDEs varied widely. Pelagic and benthic food-chain components were separated by their δ¹³C values. Significant positive correlations between δ¹⁵N and PCB 153, PCB 138, p,p′-DDE, oxy-chlordane, and trans-nonachlordane were found only for pelagic consumers, indicating that the pelagic food chain is an important bioaccumulation pathway for selected PCB and OCP compounds. The other compounds did not show any biomagnification through benthic and pelagic food chains, suggesting the lower bioaccumulation potentials of these contaminants.