A LREE-depleted component in the Afar plume: Further evidence from Quaternary Djibouti basalts

Major, trace element and isotopic (Sr, Nd, Pb) data and unspiked K–Ar ages are presented for Quaternary (0.90–0.95 Ma old) basalts from the Hayyabley volcano, Djibouti. These basalts are LREE-depleted (La_n/Sm_n = 0.76–0.83), with ⁸⁷Sr/⁸⁶Sr ratios ranging from 0.70369 to 0.70376, and rather homogeneous ¹⁴³Nd/¹⁴⁴Nd (ε_Nd = + 5.9–+ 7.3) and Pb isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.47–18.55, ²⁰⁷Pb/²⁰⁴Pb = 15.52–15.57, ²⁰⁸Pb/²⁰⁴Pb = 38.62–38.77). They are very different from the underlying enriched Tadjoura Gulf basalts, and from the N-MORB erupted from the nascent oceanic ridges of the Red Sea and Gulf of Aden. Their compositions closely resemble those of (1) depleted Quaternary Manda Hararo basalts from the Afar depression in Ethiopia and (2) one Oligocene basalt from the Ethiopian Plateau trap series. Their trace element and Sr, Nd, Pb isotope systematics suggest the involvement of a discrete but minor LREE-depleted component, which is probably an intrinsic part of the Afar plume.     

Soil Cd,Cu, Pb and Zn contaminants around Mount Isa city,Queensland, Australia: Potential sources and risks to human health

This article investigates the relationship between soil Cd, Cu, Pb and Zn contaminants and the location and activities of the Pb–Zn–Ag and Cu mines at Mount Isa, Queensland, Australia. Analysis of the data focuses primarily on soil Pb distributions and concentrations because of their potential impact on children’s health. The Xstrata Mount Isa Mines lease (XMIM) is Australia’s leading emitter of numerous contaminants to the environment, including Cu and Pb, and the mining-related activities have been linked causally to the findings of a 2008 study that showed 11.3% of local children (12–60 months) have blood Pb levels >10 μg/dL. Queensland government authorities and Xstrata Mount Isa Mines Pty Ltd maintain that contaminants within environmental systems around Mount Isa are largely the result of near-surface mineralization. The evidence for whether the contamination is derived from XMIM or other possible sources, such as the natural weathering of ore-rich bedrock, is investigated using data from surface and subsurface soil chemistry, atmospheric modelling of metal contaminants from mining and smelting operations and local geological and associated geochemical studies. Sixty surface soil samples collected from sites adjacent to houses, parks and schools throughout Mount Isa city were analyzed for their total extractable Cd, Cu, Pb and Zn concentrations in the <2 mm to >180 μm (coarser) and <180 μm (finer) grain size fractions. Concentrations in the finer size fraction reveal a range of values: Cd – 0.7–12.5 ppm; Cu – 31–12,100 ppm; Pb – 8–5770 ppm; Zn – 26–11,100 ppm, with several samples exceeding Australian residential health investigation guidelines. Spatial analysis shows that surface soil metal concentrations are significantly higher within 2 km of XMIM compared to more distant samples, and that more than 1000 property lots are at risk of having detrimentally high soil Pb levels. Determination of metal concentrations in 49 samples from eight soil pits shows that surface samples (0–2 cm) are enriched significantly relative to those at depth (10–20 cm), suggesting an atmospheric depositional origin. AUSPLUME air dispersal modelling of Pb originating from the Cu and Pb smelter stacks and mine site fugitive sources confirms that Pb is deposited across the urban area, during periods of the year (∼20%/a) when the wind blows from the direction of XMIM towards the urban area and disperses dusts from the uncovered spoil and road surfaces, as well as from stack emission sources. Although there are some spatially restricted outcrops of Pb close to the surface in parts of the urban area, the Cu-ore body is ∼244 m below the surface. However, enriched and significantly correlated surface soil concentrations of Cu and Pb (Pearson correlation 0.879, p = 0.000) in and around the urban area of Mount Isa can only be explained by atmospheric transport and deposition of metals from the adjoining mining and smelting operations. The results from this study provide unequivocal evidence that both historic and ongoing emissions from XMIM are contaminating the urban environment. Given the ongoing Pb poisoning issues in Mount Isa children, it is clear that remediation, reductions in mine emissions and more stringent regulatory actions are warranted.     

The Electric Field During Blowing Snow Events

A model is proposed to determine the electric field strength in blowing snow. To test this model, the electric field strength was measured over an 80-day period during the Canadian Arctic Shelf Exchange Study (CASES) in 2004. The electric field strength at 0.5 m correlates well with the difference between 10-m wind speed and a threshold wind speed, although there is a large amount of variation between the electric fields generated during different blowing snow events. Although the model predicts that the electric field should be proportional to particle number density, the correlation is weak. The correlation of wind speed and electric field strength suggests that particles become charged primarily due to friction-induced temperature difference as they impact upon the surface. The strength of the electric field is likely influenced by a large number of other factors that are difficult to measure. However, the model predicts electric field strengths in excess of 25 kV m⁻¹ near the surface, which would have a significant effect on particle motion.     

River Dog: Re‐imagining and re‐representing the environment and de‐idealising the rural in New Zealand film

The depiction of pristine countryside in New Zealand film has engendered a cultural disconnection with the environmental stories within the landscape. In this essay, we briefly examined the meaning of rural New Zealand landscape and its role in film. This research was done in part by making a short documentary, River Dog, a film about the rural New Zealand landscape. The character, plot and underlying message of River Dog were framed within visually relevant archetypes to form a constructive environmental message. Here, we examined River Dog's use of empathetic storytelling, an approach used to communicate an environmental issue without promulgating science or politics.     

Groundwater-dependent ecology of the shoreline of the subtropical Lake St Lucia estuary

The ecology of the St Lucia estuary in South Africa is of unique international importance. During droughts the estuary experiences high salinities, with values above that of seawater. Ion-poor groundwater flowing into the estuary from prominent sand aquifers along its eastern shoreline forms low-salinity habitats for salt-sensitive biota. During droughts, plants and animals can take refuge in the groundwater discharge zone until the condition in the estuary regains tolerable salinity. Simulations of the groundwater discharge indicate that the flow can persist during droughts over at least a decade, and be of great important for the resilience of the estuary. Anthropogenic activities have reduced the river inflow and made the St Lucia estuary more sensitive to droughts. The groundwater has thereby become increasingly important for the estuary’s ecology. Protection of the groundwater discharge along the shoreline itself and actions to increase the groundwater recharge are therefore important management tasks.     

Cluster Observations of the CUSP: Magnetic Structure and Dynamics

This paper reviews Cluster observations of the high altitude and exterior (outer) cusp, and adjacent regions in terms of new multi-spacecraft analysis and the geometry of the surrounding boundary layers. Several crossings are described in terms of the regions sampled, the boundary dynamics and the electric current signatures observed. A companion paper in this issue focuses on the detailed plasma distributions of the boundary layers. The polar Cluster orbits take the four spacecraft in a changing formation out of the magnetosphere, on the northern leg, and into the magnetosphere, on the southern leg, of the orbits. During February to April the orbits are centred on a few hours of local noon and, on the northern leg, generally pass consecutively through the northern lobe and the cusp at mid- to high-altitudes. Depending upon conditions, the spacecraft often sample the outer cusp region, near the magnetopause, and the dayside and tail boundary layer regions adjacent to the central cusp. On the southern, inbound leg the sequence is reversed. Cluster has therefore sampled the boundaries around the high altitude cusp and nearby magnetopause under a variety of conditions. The instruments onboard provide unprecedented resolution of the plasma and field properties of the region, and the simultaneous, four-spacecraft coverage achieved by Cluster is unique. The spacecraft array forms a nearly regular tetrahedral configuration in the cusp and already the mission has covered this region on multiple spatial scales (100–2000 km). This multi-spacecraft coverage allows spatial and temporal features to be distinguished to a large degree and, in particular, enables the macroscopic properties of the boundary layers to be identified: the orientation, motion and thickness, and the associated current layers. We review the results of this analysis for a number of selected crossings from both the North and South cusp regions. Several key results have been found or have confirmed earlier work: (1) evidence for magnetically defined boundaries at both the outer cusp/magnetosheath interface and the␣inner cusp/lobe or cusp/dayside magnetosphere interface, as would support the existence of a distinct exterior cusp region; (2) evidence for an associated indentation region on the magnetopause across the outer cusp; (3) well defined plasma boundaries at the edges of the mid- to high-altitude cusp “throat”, and well defined magnetic boundaries in the high-altitude “throat”, consistent with a funnel geometry; (4) direct control of the cusp position, and its extent, by the IMF, both in the dawn/dusk and North/South directions. The exterior cusp, in particular, is highly dependent on the external conditions prevailing. The magnetic field geometry is sometimes complex, but often the current layer has a well defined thickness ranging from a few hundred (for the inner cusp boundaries) to 1000 km. Motion of the inner cusp boundaries can occur at speeds up to 60 km/s, but typically 10–20 km/s. These speeds appear to represent global motion of the cusp in some cases, but also could arise from expansion or narrowing in others. The mid- to high-altitude cusp usually contains enhanced ULF wave activity, and the exterior cusp usually is associated with a substantial reduction in field magnitude.     

Vertical impulse measurements of mines buried in saturated sand

The ultimate aim of our overall task, of which the effort described in this paper is a part, is to be able to model the impulsive output of buried charges and the response of targets of interest. It is not practical or cost-effective to determine the response of all targets of interest to buried charges of all sizes by testing them. In order to have confidence in our models, however, they must be validated by a modest number of tests. A critical element in modelling the response of a target is the ability to model the loading function. The load a buried charge applies to a target above it when the charge detonates can be characterized in terms of the vertical impulse. The vertical impulse is a function of the size of the charge, its depth of burial, and the properties of the soil in which it is buried. The primary objective of the effort described in this paper is to determine the load a known charge places on a non-responding target so the data can be used to validate our models.

For model validation, a large number of detonator-scale experiments have been conducted by the University of Maryland (Fourney et al. [1]). It was also necessary to conduct a modest number of experiments at a larger scale, nine in total, to ensure that the results of the detonator-scale tests can be satisfactorily scaled up. Of the nine large-scale experiments conducted, seven were conducted with 5 or 10 lb cast TNT charges. All experiments were conducted in sand that was as nearly fully water-saturated as possible. The objective of the experiments was to determine the vertical impulse applied to a non-deforming target plate above the charge.

The large-scale experiments were conducted using the Vertical Impulse Measurement Fixture (VIMF) at the Army Research Laboratory, Aberdeen, MD. The VIMF is a unique facility that has been designed specifically to measure accurately the vertical impulse from buried charges weighing up to 8 kg.

This paper describes the VIMF and its instrumentation, test methods and test results. The results obtained demonstrate that in some cases, when the soil is saturated sand, explosive 'bubble' effects similar to those encountered in shallow water are encountered.     

In situ U-series dating by laser-ablation multi-collector ICPMS: new prospects for Quaternary geochronology

The capabilities and potential applications of in situ dating of Quaternary materials using laser ablation-MC-ICPMS are explored. ²³⁴U/²³⁸U and ²³⁰Th/²³⁴U can be measured with precision sufficient for dating at a spatial resolution of 100 μm or better in samples that contain as a little as 1 ppm uranium. Moreover, U and Th concentrations and U-series isotope ratios can be continuously profiled to determine changes in age that occur with sample growth (e.g. in speleothems). These capabilities additionally permit the dating of bones, teeth and possibly molluscs, which are subject to post-mortem open-system behaviour of U-series isotopes, and can be employed to elucidate processes of U-series migration during weathering and diagenesis. A drawback of laser ablation-MC-ICPMS is that it cannot in general provide U-series age estimates with the high precision and accuracy of conventional TIMS or solution MC-ICPMS methods. However, sample preparation is straightforward, the amount of sample consumed negligible, and it can be used to rapidly characterise or screen and select samples from which more precise and accurate dates can be obtained using conventional methods. Given further instrumental developments and the establishment of suitable matrix-matched standards for carbonates and other materials, we foresee that laser ablation-MC-ICPMS will play an increasingly important role in Quaternary dating research.