Composition of the Descartes region,lunar highlands

Analytical data for 40 elements are reported for Apollo 16 soils 60601, 61181, 61501, 64801, 67701, 68501, 65701 and breccias 60015, 60017, 60018, 60315, 61016, 61175, 65015 and 66055. The soils are uniform except for the North Ray Crater rim sample which is richer in Al₂O₃.The breccia components show great diversity in composition. Low-K Fra Mauro basalt, Highland basalt (anorthositic gabbro) and plagioclase are important constituents. Medium-K Fra Mauro basalt is an important constituent of breccias 65015 and 60315.The breccias contain many meteorite fragments and high nickel contents, evidence of the early highland bombardment.Most of the refractory elements (REE, Th, U, Zr, Hf, Nb, Ba) show strong positive correlations, interpreted as resulting from mixing. The REE patterns of the breccias show extreme variation relative to chondrites. There is a good inverse correlation between REE and the europium anomaly ($\text{Eu}\text{Eu}{}^{\mathrm{x}}$). The $\text{La}\text{Yb}$ ratio is constant at 3.1 except in plagioclase. Eu depletion or enrichment is interpreted as due to addition or removal of plagioclase.The Cayley and Descartes formations cannot be distinguished chemically and the differences in surface expression are not due to chemical distinctions. They are interpreted as structural differences, related to early highland cratering and mare basin formation.The complex soil and breccia compositions are related to mixing of four components. These are Low-K Fra Mauro basalt, Highland basalt (anorthositic gabbro) and subordinate plagioclase and Medium-K Fra Mauro basalt. These compositions have been used in a computer program (PETMIX III) to provide fits for the analytical data in terms of the end-members.An average highland composition is proposed, based on the Apollo 15 and 16 orbital data for Si, Al, Mg and Th. Abundances for most other elements are derived from the interelement relationships and correlations, and checked by the mixing program.The resulting composition consists of 69 per cent Highland basalt (anorthositic gabbro) and 31 per cent Low-K Fra Mauro basalt. There is no significant Eu anomaly. The abundances are: SiO₂: 45.2 per cent; TiO₂: 0.68 per cent; Al₂O₃: 24.9 per cent; FeO: 6.3 per cent; MgO: 8.5 per cent; CaO: 13.8 per cent; Na₂O: 0.4 per cent; K₂O: 0.11 per cent; Cr₂O₃: 0.11 per cent; Ba: 144 ppm; Th: 1.8 ppm; U: 0.46 ppm; Pb: 1.6 ppm; Zr: 156 ppm; Hf: 3.2 ppm; Nb: 10.8 ppm; Y: 32 ppm; ΣREE: 85 ppm.     

Helium-uranium dating of corals from Middle Pleistocene Barbados reef tracts

By He-U dating of corals from elevated Pleistocene reef tracts on Barbados, we have extended back to the Middle Pleistocene the high sea stand chronology previously deduced by Th²³⁰-U dating. Six samples from the first major reef tract complex older than the 200,000-yr complex gave ages of 350,000 ± 25,000 yr B.P. Two corals from the crest of Second High Cliff, an unusually large escarpment occurring approximately midway in the terrace sequence, gave concordant ages of 480,000 and 500,000 yr. Unrecrystallized corals from older reefs gave ages ranging back to 650,000 yr.The results date episodes of high sea stands at 350,000 and 500,000 yr B.P.     

Spectroscopic measurements of surfaces using vacuum ultraviolet radiation

Recent research on surface properties of materials using X-ray and vacuum ultraviolet radiation suggest some relationships in common to lunar research. New and intense sources of vacuum ultraviolet continuum radiation may offer the possibility of probing the surface properties of lunar materials and may permit some experimental demonstrations of the surface phenomena observed on the Moon.     

Decadal- to interannual-scale source water variations in the Caribbean Sea recorded by Puerto Rican coral radiocarbon

Water that forms the Florida Current, and eventually the Gulf Stream, coalesces in the Caribbean from both subtropical and equatorial sources. The equatorial sources are made up of, in part, South Atlantic water moving northward and compensating for southward flow at depth related to meridional overturning circulation. Subtropical surface water contains relatively high amounts of radiocarbon (¹⁴C), whereas equatorial waters are influenced by the upwelling of low ¹⁴C water and have relatively low concentrations of ¹⁴C. We use a 250 year record of Δ¹⁴C in a coral from southwestern Puerto Rico along with previously published coral Δ¹⁴C records as tracers of subtropical and equatorial water mixing in the northern Caribbean. Data generated in this study and from other studies indicate that the influence of either of the two water masses can change considerably on interannual to interdecadal time scales. Variability due to ocean dynamics in this region is large relative to variability caused by atmospheric ¹⁴C changes, thus masking the Suess effect at this site. A mixing model produced using coral Δ¹⁴C illustrates the time varying proportion of equatorial versus subtropical waters in the northern Caribbean between 1963 and 1983. The results of the model are consistent with linkages between multidecadal thermal variability in the North Atlantic and meridional overturning circulation. Ekman transport changes related to tradewind variability are proposed as a possible mechanism to explain the observed switches between relatively low and high Δ¹⁴C values in the coral radiocarbon records.     

Outgoing long wave radiation variability from IR satellite data prior to major earthquakes

Our analysis of the continuous outgoing long wave earth radiation (OLR) indicates anomalous variations prior to a number of medium to large earthquakes. The most recent analysis of OLR is from the M9.0 Sumatra Andaman Islands mega trust event. We compared the reference fields for December 2001 to 2004 and found OLR anomalous values, > 80 W/m², (2σ) within the epicentral area on Dec 21, 2004, 5 days before the event. We used the NOAA/IR daily (one degree) and monthly (two and half degree) gridded data to differentiate between the global and seasonal variability and the transient local anomalies. The cause of such anomalies is not fully understood; one possible explanation is the existence of thermal outgoing radiation as a result of near ground air ionization and latent heat change due to change of air humidity and temperature. This phenomenon is hypothesized to be part of a relationship between tectonic stresses, electrochemical and thermodynamic processes in the atmosphere and increasing mid IR flux, all part of a family of electromagnetic (EM) phenomena related to earthquake activity. The time scale of the observed variations is a few weeks before the onset of the seismic event. In comparison with several years of data, the observed time-series preceding the earthquake had unusually high OLR. The OLR anomaly corresponds to a large area of ground coverage and coincides with the main epicentral zone. The significance of these observations is explored using data from most recent East Asian earthquake swarm of December 2004 and three other earthquakes.     

Post-Palaeozoic evolution of weathered landsurfaces in Uganda by tectonically controlled deep weathering and stripping

A model for the evolution of weathered landsurfaces in Uganda is developed using available geotectonic, climatic, sedimentological and chronological data. The model demonstrates the pivotal role of tectonic uplift in inducing cycles of stripping, and tectonic quiescence for cycles of deep weathering. It is able to account for the development of key landforms, such as inselbergs and duricrust-capped plateaux, which previous hypotheses of landscape evolution that are based on climatic or eustatic controls are unable to explain. Development of the Ugandan landscape is traced back to the Permian. Following late Palaeozoic glaciation, a trend towards warmer and more humid climates through the Mesozoic enabled deep weathering of the Jurassic/mid-Cretaceous surface in Uganda during a period of prolonged tectonic quiescence. Uplift associated with the opening South Atlantic Ocean terminated this cycle and instigated a cycle of stripping between the mid-Cretaceous and early Miocene. Deep weathering on the succeeding Miocene to recent (African) surface has occurred from Miocene to present but has been interrupted in the areas adjacent to the western rift where development of a new drainage base level has prompted cycles of stripping in the Miocene and Pleistocene.     

The kinematics of the ionized gas in the Circinus galaxy

The TAURUS-2 Fabry–Perot interferometer, mounted on the 3.9-m Anglo-Australian Telescope, has been used to observe the Circinus galaxy. We have mapped the intensity and velocity distribution of the ionized hydrogen in the galaxy using the Balmer series Hα spectral line.
The semiresolved core (observed with a seeing disc of 30 pc) appears amorphous in shape, which is commonly observed in Seyfert 2 galaxies. Its peak coincides with the core position measured in the radio continuum, suggesting that ionized gas surrounds a non-thermal source.
A circumnuclear ring or spiral of radius 220 pc and a rotational velocity of 350 km s⁻¹ (assuming circular motions) surrounds the core. The inclination angle of this feature, i =40°±10°, is less than that of the previously observed radio continuum disc. The velocity channel maps obtained for the Hα ring show that the kinematics resemble those of a rotating ring and the intensity displays a complex structure indicative of several, unresolved, H II regions. We believe the ring to represent a circumnuclear starburst.
Our Hα data also show the presence of the previously detected [O III ] ionization cone to the north-west of the core, measuring more than 400 pc in length. We suggest that the ionization cone lies in a different plane from that of the starburst ring and is directed away from us. Several kinematic components of the core are derived and we calculate an outflow velocity in excess of 150–200 km s⁻¹ for gas above the core of Circinus. We also present evidence for inflowing ionized gas at the centre of Circinus.
The correlation of the Hα and radio continuum features is discussed, as well as the possible presence of a starburst-driven superwind in the Circinus galaxy.     

Trace element fractionation trends of tholeiitic magma at moderate pressure: Evidence from an Al-spinel ultramafic-mafic inclusion suite

Trace element data on an Al-spinel ultramafic-mafic inclusion suite in an analcimite support earlier proposals that the various inclusions are comagmatic and represent fragments of a layered tholeiitic ‘pluton’ which differentiated at pressures close to 8 kb. Ultramafic inclusions are dominantly pyroxenites, often websteritic, whereas the mafic inclusions are largely two pyroxene-plagioclase assemblages. Appropriate experimental data and abundances of Sc, Cr and V indicate that subcalcic clinopyroxene or relatively Ca-rich clinopyroxene was the major ferromagnesian phase fractionated, often accompanied by spinel in the early and middle stages of differentiation and, in the later stages, by titanomagnetite. Comparatively moderate decreases in Ni and Co suggest that olivine was a relatively unimportant fractionating phase. Clinopyroxene fractionation at moderate pressures should be assigned only a comparatively insignificant role in the production of evolved basaltic compositions.     

Origin of granitic magma by crustal remobilisation: Rb-Sr and Pb/Pb geochronology and isotope geochemistry of the late Archaean Qôrqut Granite Complex of southern West Greenland

Rb-Sr and Pb/Pb whole rock isochrons on the Qôrqut Granite Complex yield ages of $\text{2530 ± 30}\text{Myr}\text{(}\text{initial}{}^{87}\text{Sr}{}^{86}\text{Sr}\text{= 0.7081 ± 0.0008)}$ and 2580 ± 80 Myr respectively. A model relating initial Sr and Pb isotopic compositions of the Qôrqut granites to the Sr and Pb isotopic compositions of the Amîtsoq gneisses (ca. 3700 Myr) and Nûk gneisses (ca. 2900 Myr) at 2550 Myr ago, as well as Sr and Pb contents of the gneiss units, suggests that between 40 and 50% of the Qôrqut granite magma was generated by partial melting of Amîtsoq gneisses, and the remainder by partial melting of Nûk gneisses.