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Volcanic ash is dispersed in the atmosphere according to meteorology and particle properties, including size and shape. However, the multiple definitions of size and shape for non-spherical particles affect our ability to use physical particle properties to understand tephra transport. Moreover, although particles are often excluded from operational ash dispersion model setups, ash in tephra deposits 1000 km from source can exceed . Here we measure the shape and size of samples of Vedde ash from Iceland, an exceptionally widespread tephra layer in Europe, collected in Iceland and Norway. Using X-ray computed tomography and optical microscopy, we show that distal ash is more anisotropic than proximate ash, suggesting that shape exerts an important control on tephra dispersion. Shape also impacts particle size measurements. Particle long axis, a parameter often reported by tephrochronologists, is on average greater than geometric size, used by dispersion modellers. By using geometric size and quantifying shape, we can explain the transport of Vedde ash particles more than 1200 km from source. We define a set of best practices for measuring the size and shape of cryptotephra shards and discuss the benefits and limitations of using physical particle properties to understand cryptotephra transport.  相似文献   
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Microbial mercury (Hg) methylation and methylmercury (MeHg) degradation processes were examined using radiolabled model Hg compounds in San Francisco Bay-Delta surface sediments during three seasonal periods: late winter, spring, and fall. Strong seasonal and spatial differences were evident for both processes. MeHg production rates were positively correlated with microbial sulfate reduction rates during late winter only. MeHg production potential was also greatest during this period and decreased during spring and fall. This temporal trend was related both to an increase in gross MeHg degradation, driven by increasing temperature, and to a build-up in pore water sulfide and solid phase reduced sulfur driven by increased sulfate reduction during the warmer seasons. MeHg production decreased sharply with depth at two of three sites, both of which exhibited a corresponding increase in reduced sulfur compounds with depth. One site that was comparatively oxidized and alkaline exhibited little propensity for net MeHg production. These results support the hypothesis that net MeHg production is greatest when and where gross MeHg degradation rates are low and dissolved and solid phase reduced sulfur concentrations are low.  相似文献   
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Batam Island, Indonesia, located a short ferry ride away from Singapore, is a place where tourism and industry have been developed simultaneously and a border area where “developed” and “developing” nations meet. Government officials, investing international corporations and the “factory women” who work in the island's industrial estates arrive in Batam ‐ native to none of them ‐ with their own preconceptions and goals. When challenges not foreseen through master planning arise, the authorities cling ever more tightly to their physical and structural development model: the nearby city‐state of Singapore. Conversely, the factory workers who travel intranationally to work in this export processing zone (EPZ) find their objectives contested in the face of the Master Plan, corporate agendas and ethnic fusions characterising this transnational capitalist space. Entering into the homes of three groups of women migrants living and working in Batam, the relationship between the private realm that they inhabit and the social contexts in which they participate publicly is investigated. Some of the choices that women make at and about home are identified, and their ability to “micro‐resist” these external structures is explored. At home, the dynamic relationship between the Batam development project and the women's own hopes and visions of the place ‐ sometimes parallel and sometimes incongruous ‐ are revealed. As they experience life on Batam, their “social imaginaries” of it are shaped into various new realities, and their homes, removed from the confines of the factory floor, thus become spaces of release from these tensions.  相似文献   
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The study area is situated along the Zolotica river in NW Russia, located within the Kola–Dvyna Rift System in the Baltic Shield that developed during Meso and Neoproterozoic times. A 9-m thick section made up of shallow marine sediments of Upper Ediacaran age was sampled in this locality. Two volcaniclastic levels from the middle part of the section yielded an age of 556 Ma. (U/Pb SHRIMP-II on zircons). Two magnetic components were successfully isolated, component A (Decl = 157.1, Incl = 68.0, 95 = 1.9°, N = 575 in situ) carried by magnetite and component B (Decl = 120.3, Incl = − 31.7, 95 = 3.9°, N = 57, bedding corrected), carried by haematite. While component A is thought to represent a younger overprint direction, the in situ direction for component B on the other hand, is dissimilar to any expected younger direction and is considered to be primary magnetisation in origin, acquired during or soon after deposition of the sediments in the Late Ediacaran. The corresponding palaeomagnetic pole for component A in situ is located at Lon = 55.4°E, Lat = 31°N, A95 = 2.7° and for component B at Lon = 110°E, Lat = 28.3°S, A95 = 3.8°, N = 57. Combined with other palaeomagnetic poles of the same tectonostratigraphic unit an alternative apparent polar wander path for the Late Proterozoic–Early Palaeozoic of Baltica is proposed. Such an alternative path shows that after the mid Cryogenian (750 Ma), the poles that were situated over South Africa (p.d.c.) moved to the east until they reached Australia during the Late Ediacaran (555 Ma) where they remained approximately stationary until the beginning of the Cambrian (545 Ma). Finally, they moved to the northwest until they reached the Arabian Peninsula in the Early Ordovician. Palaeolatitudes indicate that Baltica situated near the equator from the Cryogenian through to the Ediacaran moving gradually to the south at c. 1 cm/yr. During the Late Early Ediacaran, the plate suddenly began to drift northward at c. 8 cm/yr and in the boundary with the Cambrian it was positioned in low to intermediate latitudes. Finally, Baltica began to move back to the south at c. 13 cm/yr until in the Early Ordovician, reaching intermediate to high southern latitudes.  相似文献   
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