Nutrient Fluxes from Sediments in the San Francisco Bay Delta

In September 2011 and March 2012, benthic nutrient fluxes were measured in the San Francisco Bay Delta, across a gradient from above the confluence of the Sacramento and San Joaquin Rivers to Suisun Bay. Dark and illuminated core incubation techniques were used to measure rates of denitrification, nutrient fluxes (phosphate, ammonium, nitrate), and oxygen fluxes. While benthic nutrient fluxes have been assessed at several sites in northern San Francisco Bay, such data across a Delta–Bay transect have not previously been determined. Average September rates of DIN (nitrate, nitrite, ammonium) flux were net positive across all sites, while March DIN flux indicated net uptake of DIN at some sites. Denitrification rates based on the N₂/Ar ratio approach were between 0.6 and 1.0 mmol m^?2 day^?1, similar to other mesotrophic estuarine sediments. Coupled nitrification–denitrification was the dominant denitrification pathway in September, with higher overlying water nitrate concentrations in March resulting in denitrification driven by nitrate flux into the sediments. Estimated benthic microalgal productivity was variable and surprisingly high in Delta sediments and may represent a major source of labile carbon to this ecosystem. Variable N/P stoichiometry was observed in these sediments, with deviations from Redfield driven by processes such as denitrification, variable light/dark uptake of nutrients by microalgae, and adsorption of soluble reactive phosphorus.     

Influence of the sediment delivery ratio index on the analysis of silting and break risk in the Plasencia reservoir (Central System,Spain)

The random forest method was used to generate susceptibility maps for debris flows, rock slides, and active layer detachment slides in the Donjek River area within the Yukon Alaska Highway Corridor, based on an inventory of landslides compiled by the Geological Survey of Canada in collaboration with the Yukon Geological Survey. The aim of this study is to develop data-driven landslide susceptibility models which can provide information on risk assessment to existing and planned infrastructure. The factors contributing to slope failure used in the models include slope angle, slope aspect, plan and profile curvatures, bedrock geology, surficial geology, proximity to faults, permafrost distribution, vegetation distribution, wetness index, and proximity to drainage system. A total of 83 debris flow deposits, 181 active layer detachment slides, and 104 rock slides were compiled in the landslide inventory. The samples representing the landslide free zones were randomly selected. The ratio of landslide/landslide free zones was set to 1:1 and 1:2 to examine the results of different sample ratios on the classification. Two-thirds of the samples for each landslide type were used in the classification, and the remaining 1/3 were used to evaluate the results. In addition to the classification maps, probability maps were also created, which served as the susceptibility maps for debris flows, rock slides, and active layer detachment slides. Success and prediction rate curves created to evaluate the performance of the resulting models indicate a high performance of the random forest in landslide susceptibility modelling.     

ISPH numerical simulation of tsunami generation by submarine landslides

The present investigation focused on the numerical simulation of the gravity currents of non-Newtonian fluids by means of the incompressible smoothed particle hydrodynamics (ISPH) approach. Firstly, to solve the rheological properties of the non-Newtonian Bingham model by ISPH method, the multi-viscodensity approach has been introduced. Then, this methodology has been used to simulate the annular viscometer and landslide deformation test cases. Through simulating these test cases, the viscoplastic behavior of the non-Newtonian viscosity and propagation of tsunami waves due to underwater landslide movement have been observed. Numerical results were in good agreement with the theoretical and experimental studies and showed that this methodology can be used to investigate precisely the generation and propagation of tsunami surface waves.     

Initial Characterisation of SK01 Sanidine: A Candidate 40Ar/39Ar Reference Material

The precision and accuracy of ⁴⁰Ar/³⁹Ar dates are ultimately linked to co-irradiated reference materials of known age. Here we provide new data from the SK01 sanidine, which was analysed in three different laboratories to evaluate it as a ⁴⁰Ar/³⁹Ar reference material. Aliquots of 5 mg, incrementally heated in two laboratories, yielded indistinguishable results with a weighted mean age of 27.58 ± 0.06 Ma (95% confidence level). Single-crystal step heating and single-crystal total fusion analyses of SK01 sanidine were undertaken in the third laboratory to further test the intracrystalline homogeneity. For the seven step-heating analyses, six crystals yielded nearly concordant age spectra with ⁴⁰Ar/³⁹Ar ages ranging from 26.853 ± 0.094 Ma to 26.963 ± 0.067 Ma, whereas one crystal gave an older age of 27.774 ± 0.071 Ma with a slightly discordant age spectrum. Twenty-three single-crystal total fusion analyses yielded ⁴⁰Ar/³⁹Ar ages ranging from 27.070 ± 0.108 Ma to 27.736 ± 0.062 Ma with a dispersion of ~ 3.8%. The older ages from single-crystal total fusion dates are interpreted to reflect an inherited or excess argon component in some crystals. This is an initial characterisation of the SK01 sanidine, and additional work needs to be conducted to further evaluate the age dispersion so that it can be utilised as a ⁴⁰Ar/³⁹Ar reference material.     

Contribution to the origin of the Serguza lead-zinc-pyrite deposit,Northern Iraq

The origin of the Serguza lead-zinc deposit of the Northern Thrust Zone has been suggested to be epigenetic, hydrothermal, structurally controlled by a post Tertiary major fault zone. Reinterpretation of previously obtained data and the evaluation of the present results have provided enough evidence to argue for a different mode of formation. Based upon trace element content of the ore minerals, dating of galena, ore and country rock texture, and the results of the detailed geochemical and geophysical prospecting in the area, it seems that the deposit is strata-bound, stratigraphically controlled within the Triassic dolomites. Its simple mineralogy, chemistry, and other features are comparable with other early Alpine strata-bound leadzinc deposits of the Mediterranean Belt.     

Flood risk analyses—how detailed do we need to be?

Applied flood risk analyses, especially in urban areas, very often pose the question how detailed the analysis needs to be in order to give a realistic figure of the expected risk. The methods used in research and practical applications range from very basic approaches with numerous simplifying assumptions up to very sophisticated, data and calculation time demanding applications both on the hazard and on the vulnerability part of the risk. In order to shed some light on the question of required model complexity in flood risk analyses and outputs sufficiently fulfilling the task at hand, a number of combinations of models of different complexity both on the hazard and on the vulnerability side were tested in a case study. The different models can be organized in a model matrix of different complexity levels: On the hazard side, the approaches/models selected were (A) linear interpolation of gauge water levels and intersection with a digital elevation model (DEM), (B) a mixed 1D/2D hydraulic model with simplifying assumptions (LISFLOOD-FP) and (C) a Saint-Venant 2D zero-inertia hyperbolic hydraulic model considering the built environment and infrastructure. On the vulnerability side, the models used for the estimation of direct damage to residential buildings are in order of increasing complexity: (I) meso-scale stage-damage functions applied to CORINE land cover data, (II) the rule-based meso-scale model FLEMOps+ using census data on the municipal building stock and CORINE land cover data and (III) a rule-based micro-scale model applied to a detailed building inventory. Besides the inundation depths, the latter two models consider different building types and qualities as well as the level of private precaution and contamination of the floodwater. The models were applied in a municipality in east Germany, Eilenburg. It suffered extraordinary damage during the flood of August 2002, which was well documented as were the inundation extent and depths. These data provide an almost unique data set for the validation of flood risk analyses. The analysis shows that the combination of the 1D/2D model and the meso-scale damage model FLEMOps+ performed best and provide the best compromise between data requirements, simulation effort, and an acceptable accuracy of the results. The more detailed approaches suffered from complex model set-up, high data requirements, and long computation times.     

Interplay of orbital forcing and tectonic pulses in the Cambrian Iberian platform, NE Spain

The stratigraphy of carbonate/shale couplets, cycles and cycle-stacking patterns in a Cambrian shallow water platform (Iberian Chains, NE Spain) are related to sea-level changes driven by orbital forcing and by tectonic pulses. The interplay of both effects can be discriminated in the Iberian fault-controlled platform, in which the tectonic activity can be analysed by accurate and detailed biostratigraphic correlations based on trilobite zonation. The stratigraphic hierarchy of rhythmically interbedded limestones and shales, in two coeval but structurally separated geodynamic settings, yields cycle ratios of 1.44 :1. This ratio is supported by time thickness and spectral analysis, which is based on a graphic method of analysis: the Map of Grey Lines. The cycle ratio seems to be evidence for orbital forcing by obliquity and precession cycles predicted for early Paleozoic time. Carbonate/shale couplets, the smallest rhythmic units recognisable in the field, represent short-term, periodic fluctuations in supply of terrigenous sediments and carbonate productivity of uncertain origin, which could be associated with one of several harmonics of the former orbital cycles. The pulsating tectonic activity was approximated by using a quantitative analysis of tectonically induced subsidence (Shaw method). Recurrence frequencies of tectonic pulses were estimated and dated by biostratigraphy. As a result, tectonic disturbances in the Cambrian Iberian platform show an episodic periodicity comparable to that of orbital eccentricity cycles, which could mask their recognition. Received: 15 November 1999 / Accepted: 9 February 2000     

Quantification of mineral matter in the Argonne Premium Coals using interactive Rietveld-based X-ray diffraction

The mineral matter in the eight reference North American coal samples of the Argonne Premium Coal series has been investigated on a quantitative basis using X-ray diffraction (XRD) techniques. X-ray diffraction data obtained from electronic low-temperature (oxygen–plasma) ash (LTA) residues, from ashes produced by heating the coals in air at 370°C, and also from the raw coals themselves, were evaluated using an interactive data processing system ( ™) based on Rietveld interpretation methods. The results from the three types of material (LTA, 370°C ash and raw coal) were compared for each sample. This allowed the components present in the raw coals in crystalline form to be recognised separately from mineral artifacts produced, particularly in the low-rank coals, from interaction of organically associated elements (Ca, S, etc.) during the two ashing processes.After the allowance for the production of any artifacts, the quantitative mineral assemblages identified from XRD of the raw coals were found to be consistent, even for coals having a relatively low ash percentage (around 5%), with the results obtained from the respective mineral concentrates prepared by the ashing methods. The effects of heating the coal to 370°C could also be distinguished, relative to the raw coal or the LTA, through changes in components such as pyrite and the clay minerals.Although some areas of uncertainty exist, particularly with magnesium in the low-rank coals, the calculated chemical compositions of the coal ash derived from the mineral mixtures identified for each coal were also found to be consistent with the results of direct chemical analysis of the respective coal ash materials.     

Determining heterogeneous deformation for granitic rocks in the northern thrust in Wadi Mubarak belt,Eastern Desert,Egypt

Finite-strain was studied in the mylonitic granitic and metasedimentary rocks in the northern thrust in Wadi Mubarak belt to show a relationship to nappe contacts between the old granitic and metavolcano-sedimentary rocks and to shed light on the heterogeneous deformation for the northern thrust in Wadi Mubarak belt. We used the R_f/ϕ and Fry methods on feldspar porphyroclasts, quartz and mafic grains from 7 old granitic and 7 metasedimentary samples in the northern thrust in Wadi Mubarak belt. The finite-strain data shows that old granitic rocks were moderate to highly deformed and axial ratios in the XZ section range from 3.05 to 7.10 for granitic and metasedimentary rocks. The long axes (X) of the finite-strain ellipsoids trend W/WNW and E/ENE in the northern thrust in Wadi Mubarak belt. Furthermore, the short axes (Z) are subvertical associated with a subhorizontal foliation. The value of strain magnitudes mainly constants towards the tectonic contacts between the mylonitic granite and metavolcano-sedimentary rocks. The data indicate oblate strain symmetry (flattening strain) in the mylonitic granite rocks. It is suggested that the accumulation of finite strain was formed before or/and during nappe contacts. The penetrative subhorizontal foliation is subparallel to the tectonic contacts with the overlying nappes and foliation was formed during nappe thrusting.     

Reaction Textures in a Suite of Spinel Granulites from the Eastern Ghats Belt, India: Evidence for Polymetamorphism, a Partial Petrogenetic Grid in the System KFMASH and the Roles of ZnO and Fe2O3

Spinel granulites, with or without sapphirine, occur as lensesin garnetiferous quartzofeldspathic gneisses (leptynites) nearGokavaram in the Eastern Ghats Belt, India. Spinel granulitesare mineralogically heterogeneous and six mineral associationsoccur in closely spaced domains. These are (I) spinel–quartz–cordierite,(II) spinel–quartz–cordierite–garnet–orthopyroxene–sillimanite,(III) spinel–cordierite–orthopyroxene–sillimanite,(IV) spinel–quartz–sapphirine–sillimanite–garnet,(V) spinel–quartz-sapphirine–garnet and (IV) rhombohedral(Fe–Ti) oxide–cordierite–orthopyroxene–sillimanite.Common to all the associations are a porphyroblastic garnet(containing an internal schistosify defined by biotite, sillimaniteand quartz), perthite and plagioclase. Spinel contains variableamounts of exsolved magnetite and is distinctly Zn rich in thesapphirine-absent associations. X_Mg in the coexisting phasesdecreases in the order cordierite–biotite–sapphirine–orthopyroxene–spinel–garnet–(Fe–Ti)oxides. Textural criteria and compositional characteristicsof the phases document several retrograde mineral reactionswhich occurred subsequent to prograde dehydration melting reactionsinvolving biotite, sillimanite, quartz, plagioclase and spinel.The following retrograde mineral reactions are deduced: (1)spinel + quartz cordierite, (2) spinel + quartz garnet + sillimanite,(3) garnet + quartz cordierite + orthopyroxene, (4) garnet+ quartz + sillimanite cordierite, (5) spinel + cordierite orthopyroxene + sillimanite, (6) spinel + sillimanite + quartz sapphirine, (7) spinel + sapphirine + quartz garnet + sillimanite,and (8) spinel + quartz sapphirine + garnet. A partial petrogeneticgrid for the system FeO–MgO–Al₂O₃–SiO₂–K₂O–H₂Oat high fo₂, has been constructed and the effects of ZnO andFe₂O₃ on this grid have been explored Combining available experimentaland natural occurrence data, the high fo₂ invariant points inthe partial grid have been located in P–T space. Geothermobarometricdata and consideration of the deduced mineral reactions in thepetrogenetic grid show that the spinel granulites evolved throughan anticlockwise P–T trajectory reaching peak metamorphicconditions >9 kbar and 950C, followed by near-isobaric cooling(dT/dP = 150C/kbar). This was superimposed by an event of near-isothermaldecompression (dT/dP = 15C/kbar). The studied spinel granulites,therefore, preserve relic prograde mineral associations andreaction textures despite being metamorphosed at very high temperatures,and bear evidence of polymetamorphism. KEY WORDS: spinel granulite; Eastern Ghats; India; polymetamorphism; geothermometry; geobarometry Corresponding author