Micromorphological Analysis of Coastal Sediments from Willapa Bay, Washington, USA: A Technique for Analysing Inferred Tsunami Deposits

Tsunami deposits are provisionally distinguished in the field on the basis of anomalous sand horizons, fining-up and fining-landward, coupled with organic-rich, fragmented `backwash' sediments. In this paper, micromorphological features of a sediment sequence previously interpreted as being of tsunami origin are described. These characteristics are shown to be consistent with the macro-scale features used elsewhere, but show additional details not seen in standard stratigraphies, including possible evidence for individual waves, possibly wave-magnitude progression, organic fragment alignment and intraclast microstructures. Although replication and more complete studies are needed, this analysis confirms the identification of a tsunami in Willapa Bay in ca.1700 AD, while demonstrating a widely applicable technique for confirming or refuting possible tsunami deposits.     

A quantitative evaluation of Playfair's law and its use in testing long‐term stream erosion models

Playfair's law (J. Playfair, illustrations of the Huttonian Theory of the Earth, 1802) requires any two tributaries in a river network to lower at the same rate near their junction. Although this law holds exactly at the junction, it is unclear how well it holds in the vicinity of the junction. This issue has practical importance because Playfair's law has been used to estimate parameters for detachment‐limited models of erosion. If the incision rate of a stream is modelled as βA^mSⁿ, where β is an erodibility parameter, A is the area drained by the stream, and S is the local gradient of the channel, then the ratio of the parameters m/n can be estimated from junctions by assuming that Playfair's law holds over the distance used to determine S for each tributary. In this paper, Playfair's law and associated m/n estimates are evaluated for simulated basins with constant and temporally varying uplift rates (or baselevel lowering rates). The results demonstrate that estimates of m/n may be biased for basins with upward‐concave stream profiles because the local slope must be approximated with an average upstream slope. In addition, when uplift rate varies temporally, knickpoints are shown to travel through the basins with constant vertical velocity. Because incision rates vary within the basin, Playfair's law only holds exactly at the junctions. These effects are more important when slopes are measured over longer distances. Finally, measurement techniques are presented which address these potential biases. Copyright © 2001 John Wiley & Sons, Ltd.     

Micellar-Enhanced Ultrafiltration and Air Stripping for Surfactant-Contaminant Separation and Surfactant Reuse

Micellar-enhanced ultrafiltration (MELT) and air stripping were evaluated for surfactant-contaminant separation and surfactant recovery. Two linear alkyl diphenyloxide disulfonate (DPDS) surfactants were evaluated with the contaminants naphthalene and trichloroethylene. A separation model developed from micellar partitioning principles showed a good correlation to batch MEUF studies, whereas flux analysis highlighted concentration polarization effects in relation to hydrophobe length. MEUF effectively concentrated the surfactant-contaminant system (93 to 99 percent retention); however, this did not result in surfactant-contaminant separation. Batch and continuous flow air stripping models were developed based upon air/water ratio, surfactant concentration, and Micellar partitioning; model predictions were validated by experimental data. Sensitivity analyses illustrated the decline in contaminant-surfactant separation with increasing surfactant concentration (e.g., TCE removal efficiency declines from 83 percent to 37 percent as C-16 DPDS concentration increases from 0 to 55 mM). This effect is greater for more hydrophobic contaminants (naphthalene vs. TCE) and surfactants with greater solubilization potential (C16-DPDS vs. C-12 DPDS). The resulting design equations can account for this effect and thus properly size air strippers to achieve the desired removal efficiency in the presence of surfactant micelles. Proper selection and design of surfactant-contaminant separation and surfactant recovery systems are integral to optimizing surfactant-enhanced subsurface remediation.     

Gulf of Mexico hydrocarbon seep communities—IX. Sterol biosynthesis of seep mussels and its implications for host-symbiont association

The sterol analysis of six hydrocarbon seep mussels (mytilid II and mytilid Ib) from the Alaminos Canyon in the Gulf of Mexico is reported. The sterol composition of the mussel-symbiotic bacteria complex reflects a preponderant synthesis of 4α-methyl sterols (seep mytilid II), and a predominant biosynthesis of 4-desmethyl sterols with some amounts of 4α-methyl sterols (seep mytilid Ib). This suggests a methane-based symbiotic relationship between the mussels and methanotrophic bacteria. It also suggests that the biosynthesis of sterols in the mussel-bacteria complex is completed to the level of cholest-5-en-3ß-ol (mytilid II) or 5α-cholestan-3ß-ol (mytilid Ib).     

Thermal analysis in the laser-heated diamond anvil cell

A new technique actively controls thermal radiation and monitors sample properties during laser-heating in a diamond anvil cell. The technique can be described as a qualitative application of thermal analysis. Discontinuities in temperature, laser power, visible thermal radiation, or in their derivatives as functions of time can be associated with the enthalpy of phase transitions (such as melting) or with changes in maternal properties (such as emissivity).The technique is illustrated with melting experiments on iron-magnesium-silicate perovskite. Temperature corrections associated with these experiments are discussed and the results are briefly reviewed.