Asteroid Differentiation: Pyroclastic Volcanism to Magma Oceans

Abstract— Asteroid differentiation was driven by a complex array of magmatic processes. This paper summarizes theoretical and somewhat speculative research on the physics of these processes. Partial melts in asteroids migrate rapidly, taking < 10⁶ years to reach surface regions. On relatively small (<100 km) asteroids with sufficient volatiles in partial melts (<3000 ppm), explosive volcanism accelerated melts to greater than escape velocity, explaining the apparent lack of basaltic components on the parent asteroids of some differentiated meteorites. Partial melting products include the melts (some eucrites, angrites), residues (lodranites, ureilites), and unfractionated residues (acapulcoites). The high liquidus temperatures of magmatic iron meteorites, the existence of pallasites with only olivine, and the fact that enstatite achondrites formed from ultramafic magmas argue for the existence of magma oceans on some asteroids. Asteroidal magma oceans would have been turbulently convective. This would have prevented crystals nucleated at the upper cooling surface (the only place for crystal nucleation in a low-pressure body) from settling until the magma became choked with crystals. After turbulent convection slowed, crystals and magma would have segregated, leaving a body stratified from center to surface as follows: a metallic core, a small pallasite zone, a dunite region, a feldspathic pyroxenite, and basaltic intrusions and lava flows (if the basaltic components had not been lost by explosive volcanism). The pallasite and dunite zones probably formed from coarse (0.5–1 cm) residual olivine left after formation of the magma ocean at >50% partial melting of the silicate assemblage. Iron cores crystallized dendritically from the outside to the inside. The rapid melt migration rate of silicate melts suggests that ²⁶Al could not be responsible for forming asteroidal magma oceans because it would leave the interior before a sufficient amount of melting occurred. Other heat sources are more likely candidates. Our analysis suggests that if Earth-forming planetesimals had differentiated they were either small (<100 km) and poor in volatiles (<1000 ppm) or they were rich in volatiles and large enough (>300 km) to retain the products of pyroclastic eruptions; if these conditions were not met, Earth would not have a basaltic component.     

Lunar surface geochemistry: Global concentrations of Th, K, and FeO as derived from lunar prospector and Clementine data

Accurate estimates of global concentrations of Th, K, and FeO have an important bearing on understanding the bulk chemistry and geologic evolution of the Moon. We present empirical ground-truth calibrations (transformations) for Lunar Prospector gamma-ray spectrometer data (K and Th) and a modified algorithm for deriving FeO concentrations from Clementine spectral reflectance data that incorporates an adjustment for TiO₂ content. The average composition of soil samples for individual landing sites is used as ground-truth for remotely sensed data. Among the Apollo and Luna sites, Apollo 12 and 14 provide controls for the incompatible-element-rich compositions, Apollo 16 and Luna 20 provide controls for the feldspathic and incompatible-element-poor compositions, and Apollo 11, 15, and 17, and Luna 16 and 24 provide controls for Fe-rich compositions. In addition to these Apollo and Luna sample data we include the composition of the feldspathic lunar meteorites as a proxy for the northern farside highlands to extend the range of the calibration points, thus providing an additional anorthositic end-member composition. These empirical ground-truth calibrations for Lunar Prospector Th and K provide self consistency between the existing derived data and lunar-sample data. Clementine spectral-reflectance data are used to construct a TiO₂-sensitive FeO calibration that yields higher FeO concentrations in areas of high-Fe, low-Ti, mare-basalt-rich surfaces than previous FeO algorithms. The data set so derived is consistent with known sample compositions and regolith mixing relationships.     

A simple model of a supernova

In this paper we formulate the problem of the collapse of a spherically-symmetric, radiating body in general relativity. The requirement that the metric and its normal derivative be continuous across the boundary imposes conditions upon the evolution of the star and allows identification of physical phenomena measured by a distant observer. A solution to Einstein's field equations for the exterior of a spherically-symmetric radiating body is that derived originally by Vaidya in 1951. By requiring the continuity described above we identify the mass, luminosity, velocity, and time increment measured by a distant observer in terms of the metric parameters evaluated in a frame comoving with the outer boundary. We also assume that the interior metric is a sum of products of functions of the radius and time. The continuity requirements allow the evolution of two of the three functions of time to be determined. The evolution of the third function, describing the motion of the core, is determined by the imposition of an equation of state at the center. The adiabatic index derived from the Baym-Bethe-Pethick equation of state was used to provide this last equation. A major result is obtaining an analytic solution to Einstein's field equations describing the core of a collapsing star. As a consequence of this solution we found that for the relatively small values of the adiabatic index (_max1.6), the star smoothly made the transition to a final collapsed state. Neither bounce nor shock wave was obtained. Also, there is a readily understood connection between the adiabatic index, and such parameters of the edge of the core as the velocity and acceleration. Finally, the analytic solutions provide the time-scales for the collapse which are significantly different from that of free-fall. The retarding effects of pressure upon the collapse are apparent. It is hoped that such analytic solutions will provide insight into more complicated dynamic systems in general relativity.     

Mercury content of the Springfield coal, Indiana and Kentucky

With pending regulation of mercury emissions in United States power plants, its control at every step of the combustion process is important. An understanding of the amount of mercury in coal at the mine is the first step in this process. The Springfield coal (Middle Pennsylvanian) is one of the most important coal resources in the Illinois Basin. In Indiana and western Kentucky, Hg contents range from 0.02 to 0.55 ppm. The variation within small areas is comparable to the variation on a basin basis. Considerable variation also exists within the coal column, ranging from 0.04 to 0.224 ppm at one Kentucky site. Larger variations likely exist, since that site does not represent the highest whole-seam Hg nor was the collection of samples done with optimization of trace element variations in mind. Estimates of Hg capture by currently installed pollution control equipment range from 9–53% capture by cold-side electrostatic precipitators (ESP) and 47–81% Hg capture for ESP + flue-gas desulfurization (FGD). The high Cl content of many Illinois basin coals and the installation of Selective Catalytic Reduction of NO_x enhances the oxidation of Hg species, improving the ability of ESPs and FGDs to capture Hg.     

Derelict fishing nets in Puget Sound and the Northwest Straits: Patterns and threats to marine fauna

Derelict fishing gear remains in the marine environment for years, entangling, and killing marine organisms worldwide. Since 2002, hundreds of derelict nets containing over 32,000 marine animals have been recovered from Washington’s inland waters. Analysis of 870 gillnets found many were derelict for years; most were recovered from northern Puget Sound and high-relief rocky habitats and were relatively small, of recent construction, in good condition, stretched open, and in relatively shallow water. Marine organisms documented in recovered gillnets included 31,278 invertebrates (76 species), 1036 fishes (22 species), 514 birds (16 species), and 23 mammals (4 species); 56% of invertebrates, 93% of fish, and 100% of birds and mammals were dead when recovered. For all taxa, mortality was generally associated with gillnet effectiveness (total area, age and condition, and suspension in the water). Mortality from derelict fishing gear is underestimated at recovery and may be important for species of economic and conservation concern.     

The opening of the Woodlark Basin, subduction of the Woodlark spreading system, and the evolution of Northern Melanesia since mid-pliocene time

Magnetic anomaly and seismological data define segments of active seafloor spreading and associated magnetic lineations trending ENE in the Woodlark Basin. The total opening rate has been approximately 6 cm/yr for the last 1 m.y. Spreading rates diminish by over 10% from east to west along the Woodlark spreading system implying a pole of current opening 15°–20° to the west. Commencement of seafloor spreading in the basin has apparently been time-transgressive, beginning prior to 3.5 m.y. in the east, and at successively later times to the west. Earthquake focal mechanisms and geological evidence suggest that the land areas bounding the western end of the Woodlark Basin are undergoing tensional deformation. We believe that eventually the Woodlark Basin plate boundary will propagate westward through the d'Entrecasteaux Islands into the Papuan peninsula. Hitherto unreported shallow seismicity associated with the northern margin of the NE-trending section of the Woodlark Rise probably reflects partial decoupling of the Woodlark and Solomon basins, possibly due to mechanical difficulties in subducting the young Woodlark lithosphere.Analysis of the relative motions between the Solomon, Indo-Australian, and Pacific plates shows that the Woodlark spreading system has been subducted at high rates (> 10 cm/yr) beneath the Solomon Islands during the opening of the Woodlark Basin. Several tectonic and geological features limited to the region of interaction of the Woodlark Basin with the Solomon Trench and arc may be symptomatic of ridge subduction. These features include high heat flow in the Solomon Trench, which shoals to 4 km; low levels of seismicity and only shallow hypocenters; and voluminous eruptions of high olivine basalts and basaltic andesites extremely close to the trench axis. This close association in space and time of an unusual volcanic suite with ridge subduction implies a strong dependence of the petrogenesis on the tectonic regime.A combination of this study of the Woodlark Basin and the previous study of the Bismarck Basin (Taylor, 1979) provides a reconstruction of the positions of the continents, ocean basins, and island chains in northern Melanesia for mid-Pliocene time. In accepting the existence of a Solomon plate, we can explain the trench-like structure off the Trobriand margin of New Guinea, the occurrence of Late Cenozoic calc-alkaline volcanism along the Papuan peninsula, and the presence of intermediate depth seismicity beneath the north Papuan peninsula. The rapid changes in relative motions along or across the New Ireland-Solomons chain over the past 3.5 m.y. may explain the spatial and temporal changes in igneous activity observed on these islands.     

Deep analyses of nulling in Arecibo pulsars reveal further periodic behaviour

Numerous studies of conal pulsars, e.g. B1133+16, have revealed fluctuation features and a steady null fraction. Sensitive Arecibo observations provide an unprecedented ability to detect nulls and confirm previously found fluctuation features. By replacing each pulse with a scaled version of the average profile, we were able to quench all subpulse modulation, dubbed pulse-modulation quelling (PMQ). It was surprising to note that the low-frequency feature observed in the natural longitude resolved fluctuation spectra (LRF) persisted in the PMQ LRFs. It appears that we can conclude, then, that in the natural pulse sequence the nulls themselves reflect whatever underlying periodicity is responsible for the low-frequency feature. Conversely, the aggregate fluctuation power of the low-frequency feature changes little whether the pulse modulation is quelled or not, implying that the feature fluctuations are produced by the nulls!     

Co-development of Jurassic I-type and A-type granites in southern Hunan,South China: Dual control by plate subduction and intraplate mantle upwelling

Two types of spatially and temporally associated Jurassic granitic rocks, I-type and A-type, occur as pluton pairs in several locations in southern Hunan Province, South China. This paper aims to investigate the genetic relationships and tectonic mechanisms of the co-development of distinct granitic rocks through petrological, geochemical and geochronological studies. Zircon LA-ICPMS dating results yielded concordant U–Pb ages ranging from 180 to 148 Ma for the Baoshan and Tongshanling I-type granodiorites, and from 180 to 158 Ma for the counterpart Huangshaping and Tuling A-type granites. Petrologically, the I-type granodiorites consist of mafic minerals such as hornblende whereas the A-type granites are dominated by felsic minerals (e.g., quartz, K-feldspar and plagioclase). Major and trace element analyses indicate that the I-type granodiorites have relatively low SiO₂ (64.5–71.0%) and relatively high TiO₂ (0.28–0.51%), Al₂O₃ (13.8–15.5%), total FeO (2.3–4.7%), MgO (1.3–2.6%) and P₂O₅ (0.10–0.23%) contents, and the A-type granites are characterized by high concentrations of Rb (212–1499?ppm), Th (18.3–52.6?ppm), U (11.8–33.6?ppm), Ga (20.0–36.6?ppm), Y (27.1–134.0?ppm) and HREE (20.3–70.0?ppm), with pronounced negative Eu anomalies (Eu/Eu*?=?0.01–0.15). Moreover, the I-type granodiorites are classified as collision-related granites emplaced under a compressional environment, whereas the A-type granites are within-plate granites generated in an extensional setting. Zircon Hf isotopic compositions vary substantially for these granitic rocks. The I-type granodiorites are characterized by relatively young Hf model ages (T_DM1?=?1065–1302 Ma, T_DM^C =1589–2061 Ma) and moderately negative εHf(t) values (–5.9 to –11.5), whereas the A-type granites have very old model ages (T_DM1?=?1454–2215 Ma, T_DM^C?=?2211–2974 Ma) and pronounced negative εHf(t) values (–15.8 to –28.3). These petrochemical and isotopic characteristics indicate that the I-type granodiorites may have been derived from a deep source involving mantle-derived juvenile (basaltic) and crustal (pelitic) components, whereas the A-type granites may have been sourced from melting of meta-greywacke in the crust. This study proposes that the pressure and temperature differences in the source regions caused by combined effects of intra-plate mantle upwelling and plate subduction are the major controlling factors of the co-development of the two different types of magmas. Crustal anatexis related to lithospheric delamination and upwelling of hot asthenosphere under a high pressure and temperature environment led to the formation of the I-type magmas. On the other hand, the A-type magmas were formed from melting of the shallower part of the crust, where extensional stress was dominant and mantle-crust interaction was relatively weak. Rifts and faults caused by mantle upwelling developed from surface to depth and successively became channels for the ascending I- and A-type magmas, resulting in the emplacement of magmas in adjacent areas from sources at different depths.     

Ultracataclasis, sintering, and frictional melting in pseudotachylytes from East Greenland

Large volumes of pseudotachylyte (an intrusive, fault-related rock interpreted to form by a combination of cataclasis and melting) occur in Tertiary normal faults and accommodation zones along 400 km of the East Greenland volcanic rifted margin. Analysis of representative pseudotachylyte samples reveals a wide range of mesoscopic and microscopic textures, mineralogies, and chemistries in the aphanitic pseudotachylyte matrix. Three distinct types of pseudotachylyte (referred to as angular, rounded and glassy) are identified based on these characteristics. Angular pseudotachylyte (found primarily in dike-like reservoir zones) is characterized by angular grains visible on all scales, with micron-scale fragments of mica and amphibole. Its matrix is enriched in Fe₂O₃, MgO, and TiO₂ relative to the host rock, with minor increases in CaO, K₂O, and small decreases in Na₂O. Rounded pseudotachylyte is found in reservoir zones, injection veins (pseudotachylyte-filled extension fractures), and fault veins (small faults with pseudotachylyte along their surfaces). It is characterized by smooth-surfaced, compacted grains on microscopic scales, and encloses rounded, interpenetrative lithic clasts on outcrop scale. Its matrix is enriched in Fe₂O₃, MgO, TiO₂, and Al₂O₃ relative to the host rock, with minor depletion in Na₂O and K₂O. Glassy pseudotachylyte is found primarily along fault surfaces. Its matrix is characterized by isotropic, conchoidally fractured material containing microscopic, strain-free amphibole phenocrysts, and is enriched in TiO₂, Al₂O₃, K₂O, Fe₂O₃, MgO, CaO, and Na₂O relative to the host rock. These observations suggest that angular pseudotachylyte was produced by cataclasis, with enrichment in metallic oxides resulting from preferential crushing of mechanically weak amphibole and mica minerals found in the gneissic host rock. Cataclasis and concomitant frictional heating resulted in the textural and chemical modification of angular pseudotachylyte by sintering or melting, producing rounded and glassy pseudotachylyte, respectively. Compositional and textural observations constrain the temperatures reached during frictional heating (700–900°C) which in turn delimit the amount of frictional heat imparted to the pseudotachylytes during slip. Our results suggest that the East Greenland pseudotachylytes formed during small seismic events along faults at shallow crustal levels. Consistent relative ages and widespread occurrence of pseudotachylyte-bearing faults in East Greenland suggest that widespread microseismicity accompanied the early development of this volcanic rifted margin.