We need to understand chemical recycling at convergent margins and how chemical interactions between subducted slab and the
overlying mantle wedge affect mantle evolution and magmagenesis. This requires distinguishing contributions from recycled
individual subducted components as well as those contributed by the mantle. We do this by examining magmatic products generated
at different depths above a subduction zone, in an intra-oceanic arc setting. The Guguan cross-chain in the intra-oceanic
Mariana arc overlies subducted Jurassic Pacific plate lithosphere at depths of ~125--230 km and erupts mostly basalt. Basalts
from rear-arc volcanoes are more primitive than those from the magmatic front, in spite of being derived by lower degrees
of melting of less-depleted mantle. Rear-arc magmas also show higher temperatures and pressures of equilibration. Coexisting
mineral compositions become more MORB- or OIB-like with increasing height above the subduction zone. Trace element and isotopic
variations indicate that the subduction component in cross-chain lavas diminishes with increasing depth to the subduction
zone, except for water contents. There is little support for the idea that melting beneath the Mariana Trough back-arc basin
depleted the source region of arc magmas, but melting to form rear-arc volcanoes may have depleted the source of magmatic
front volcanoes. Enrichments in rear-arc lavas were not caused by sediment melting; the data instead favor an OIB-type mantle
that has been modestly affected by subduction zone fluids. Our most important conclusion is that sediment fluids or melts
are not responsible for the K--h relationship and other cross-chain chemical and isotopic variations. We speculate that an
increasing role for supercritical fluids released from serpentinites interacting with modestly enriched mantle might be responsible
for cross-chain geochemical and isotopic variations.
Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users. 相似文献
The Palaeoproterozoic (1.90–1.60 Ga) crust of central Fennoscandia was intruded repeatedly by dolerite dikes and sills during the Neo- and Mesoproterozoic eons. We report 17 new baddeleyite U–Pb dates comprising six generations of dolerites (in Ma):
Blekinge-Dalarna dolerites
946–978
Protogine Zone dolerites
1,215–1,221
Central Scandinavian Dolerite Group
1,264–1,271
Tuna dikes and age equivalents in Dalarna
1,461–1,462
Värmland dolerites
~1,568
Breven-Hällefors dolerites
~1,595
The favoured tectonic model implies that the majority of these suites were related to active margin processes somewhere west (and possibly south) of the Fennoscandian Shield. Dolerite intrusions are interpreted to reflect discrete events of back-arc extension as the arc retreated oceanward. Initial Hf and Nd isotope compositions of the dolerite swarms fall between CHUR and normal-depleted mantle, and suggest a variably depleted and re-enriched mantle as the source for the here investigated 1.6 to 0.95 Ga old mafic rocks. Repeated recycling of older crustal components, mainly sediments (dominated by material with short residence ages) in earlier subduction systems may have been very efficient at producing geochemically and isotopically variably enriched lithospheric mantle sections beneath the Fennoscandian Shield.
We describe the development of a mid-infrared camera intended for use at the Palomar 5-m telescope and at the NASA Infrared Telescope Facility. The camera is based on Rockwell's HF-16 128×128 Si:As BIB array. This array is unusual in that it has a well depth of approximately 30 million electrons; this will allow the use of traditional broadband astronomical filters (N and Q) while keeping a reasonable field-of-view. Measured array performance indicates that it has a read noise of 1100 electrons and shows non-linearities of <1% up to 65% of full well. In this paper, we discuss the array and its operating characteristics and we give a brief overview of the camera design.National Research Council research associate at JPLSummer Undergraduate Research Fellow at JPL 相似文献
About half the diamonds studied from the Cenozoic placer deposits along the Namibian coast belong to the peridotitic suite. The peridotitic mantle source is heterogeneous ranging from lherzolitic to strongly Ca depleted (down to 0.24 wt.% CaO in garnet) and shows large variations in Cr/Al ratio, illustrated by very low to very high Cr2O3 contents in garnet (2.6–17.3 wt.%). The Cr-rich end of this range includes exceptionally high Cr2O3 contents in Mg-chromite (70.7 wt.%) and clinopyroxene (3.6 wt.%). Garnet-olivine thermometry appears to indicate two groups, one that equilibrated at temperatures between 1200 and 1220°C and a second between 960 and 1100°C. Combined estimates of pressure and temperature based on garnet-orthopyroxene pairs indicate a large variance in geothermal gradients, corresponding to 38–42 mW/m2 surface heat flow.
The trace-element composition of peridotitic garnet inclusions (determined by SIMS) also indicates large diversity. Two principal groups, corresponding to different styles of metasomatic source enrichment, are recognized. The first group ranges from extremely LREEN-depleted patterns, through trough-shaped REEN to sinusoidal patterns with the position of the first peak gradually moving from the LREEN to the MREEN. This series of REE patterns is interpreted to reflect a range of metasomatic agents with decreasing LREE/HREE. Only in the case of the two garnets with REEN peaking at Sm–Eu is this process connected with enrichment in Zr, without significant introduction of Y and Ti. The metasomatism responsible is interpreted as reflecting percolation of CHO-fluids through harzburgite under sub-solidus conditions. A second group of garnets shows an increase from LREEN–MREEN and almost flat (lherzolitic garnet) to moderately declining MREEN–HREEN at super-chondritic levels. This second style of metasomatism is caused by an agent carrying HFSE and showing only moderate enrichment in LREE over HREE, which points towards silicate melts. 相似文献
The present paper provides C- and N-stable isotope characteristics, N-contents and N-aggregation states for alluvial diamonds of known paragenesis from placers along the Namibian coast. The sample set includes diamonds with typical peridotitic and eclogitic inclusions and the recently reported “undetermined” suite of Leost et al. [Contrib. Mineral. Petrol. 145 (2003) 15] which resulted from infiltration of high temperature, carbonate-rich melts. δ13C-values range from −20.3‰ to −0.5‰ (n=48) for peridotitic diamonds and from −38.5‰ to −1.6‰ (n=45) for eclogitic diamonds. Diamonds belonging to the “undetermined” suite span a narrower range in δ13C from −8.5‰ to −2.7‰ (n=13). When compared with previous studies, diamonds from Namibia are characterised by unusually low proportions of N-free (i.e. Type II) peridotitic and eclogitic diamonds (3% and 2%, respectively) and an unprecedented high proportion of N-rich diamonds (15% and 73%, respectively, have N-contents >600 ppm). δ15N-values for diamonds of the peridotitic, eclogitic and “undetermined” suites range from −10‰ to +13‰ without correlations with either N-content or δ13C. The similarity in N-isotopic composition and the N-rich character of diamonds belonging to the eclogitic, peridotitic and “undetermined” suites is striking and suggests a close genetic relationship. We propose that a large part of the diamonds mined in Namibia formed during metasomatic events of similar style that introduced carbon and nitrogen into a range of different host lithologies. 相似文献
A series of ozone transects measured each year from 1987 to 1990 over thewestern Pacific and eastern Indian oceans between mid-November andmid-Decembershows a prominent ozone maximum reaching 50–80 ppbv between 5 and 10 kmin the 20° S–40° S latitude band. This maximum contrasts with ozonemixing ratios lower than20 ppbv measured at the same altitudes in equatorial regions. Analyses witha globalchemical transport model suggest that these elevated ozone values are part ofa large-scale tropospheric ozone plume extending from Africa to the western Pacific acrosstheIndian ocean. These plumes occur several months after the peak in biomassburninginfluence and during a period of high lightning activity in the SouthernHemispheretropical belt. The composition and geographical extent of these plumes aresimilar to theozone layers previously encountered during the biomass burning season in thisregion.Our model results suggest that production of nitrogen oxides from lightningstrokes sustains the NOx (= NO+NO2) levels and the ozonephotochemical productionrequired in the upper troposphere to form these persistent elevated ozonelayers emanating from biomass burning regions. 相似文献
Gabbroic cumulates drilled south of the Kane Transform Fault on the slow-spread Mid-Atlantic Ridge preserve up to three discrete magnetization components. Here we use absolute age constraints derived from the paleomagnetic data to develop a model for the magmatic construction of this section of the lower oceanic crust. By comparing the paleomagnetic data with mineral compositions, and based on thermal models of local reheating, we infer that magmas that began crystallizing in the upper mantle intruded into the lower oceanic crust and formed meter-scale sills. Some of these magmas were crystal-laden and the subsequent expulsion of interstitial liquid from them produced ‘cumulus’ sills. These small-scale magmatic injections took place over at least 210?000 years and at distances of ∼3 km from the ridge axis and may have formed much of the lower crust. This model explains many of the complexities described in this area and can be used to help understand the general formation of oceanic crust at slow-spread ridges. 相似文献