New carbonatite complexes in the Archaean In'Ouzzal nucleus (Ahaggar,Algeria): mineralogical and geochemical data

Several massifs of very old carbonatites have been discovered in the Archaean granulitic block of In'Ouzzal (Western Ahaggar, Algeria). These carbonatites are original since they are associated with Silica — saturated syenitic magmatism and present, in the late stages of evolution, a very uncommon mineralogy, with silicate minerals, especially wollastonite, allanite, and quartz. The mineralogy, C and O isotopes and R.E.E. distributions indicate that the late stages of crystallization occurred under high SiO₂ activities, and produced the uncommon mineralogy and extremely high R.E.E. concentrations in phosphate minerals apatite and britholite. Interaction with continental crust is a possible mechanism to explain the original features of these carbonatite complexes.     

Evolution of organic matter indicators in response to major environmental changes: The case of a formerly cut-over peat bog (Le Russey, Jura Mountains, France)

To assess whether the biochemical characteristics of peat can provide clues for past ecosystem changes or not, a study was carried out combining elemental analysis, micro-morphological counts and neutral monosaccharide determination of peat organic matter (OM) and the dominant living plants from a formerly cut-over peat bog in the Jura Mountains. Peat profiles (up to 50 cm depth) from two distinctive zones (bare peat, FRA and a regenerating stage, FRC) were compared with the reference profile (FRD) taken from an unexploited area of the bog. The results show contrasting OM composition along the profiles. In the upper sections of the FRD and FRC profiles, high C/N ratios and sugar contents (in the same range as in the source plants) and the large predominance of well preserved plant tissues indicate good preservation of primary biological inputs. In contrast, in peat from the FRA profile and deeper levels of the FRC profile, lower C/N ratios, lower amounts of sugars and a predominance of amorphous OM and mucilage suggest more extensive OM degradation. These features delineate a clear threshold between an uppermost “new” regenerating peat section and an “old” catotelm peat below. Nevertheless, even in the latter, the sugar contents remain relatively high (>80 mg/g) compared with other organic and mineral soils. Analysis of typical peat-forming plants and of bulk peat and fine grained fractions allowed identification of the following source indicators: xylose and arabinose for Cyperaceae; rhamnose, galactose and mannose for mosses; and ribose (and to a lesser extent, hemicellulosic glucose) possibly for microbial synthesis.     

微粒暗色包体中锆石的形态演化及其制约机制

在浙江青田钙碱性花岗岩的微粒暗色包体中存在着３种不同类型的锆石,其中,Ａ类错石具有最小的、但变化范围最大的Ｉ_（ｐｒ）,Ｉ_（ｐｙ）和Ｉ_（ｅｌ）值;Ｃ类锆石与Ａ类锆石相反,具有最大的、但变化范围最小的 Ｉ_（ｐｒ）, Ｉ_（ｐｙ）和 Ｉ_（ｅｌ）值; Ｂ类锆石的晶型特征介于 Ａ类锆石与Ｃ类锆石之间．锆石的电子探针分析表明,微量元素（Ｈｆ, Ｕ, Ｙ, Ｔｈ）含量从 Ａ类锆石至 Ｃ类锆石呈现为连续增大的演化趋势,且伴随着含量的变化范围亦趋于增大．这些特征反映了Ａ类锆石、Ｂ类锆石和Ｃ类锆石依次形成于包体岩浆冷凝过程的不同阶段或包体岩浆侵入过程的不同空间位置．根据晶体的ＵＯ_２／ＨｆＯ_２,ＴｈＯ_2／Ｙ_2Ｏ_３,ＵＯ_２／（ＴｈＯ_２＋Ｙ_２Ｏ_３）比值分别与 Ｉ_（ｐｒ）, Ｉ_（ｐｙ）和 Ｉ_（ｅｌ）数值里显著的正相关性,可以认为锆石晶型变化是由于在不同锆石晶面上微量元素的差异性分配造成的．结合微粒暗色包体的岩石学特征和锆石的晶型和成分标型特征,可以推测包体岩浆可能同源于产生寄主花岗岩浆的部分熔融区,为该区残留物质部分熔融作用而分离出来的熔体。     

Millennial-scale variations in hydrography and biogeochemistry in the Eastern Equatorial Pacific over the last 100 kyr

In this study, we use records of nitrogen isotope ratios (δ¹⁵N), UK’37 temperature estimates, organic carbon and opal percentages from high-resolution sediment cores located in the eastern equatorial Pacific (EEP) to explore the mechanisms linking millennial-scale changes in low-latitude sea surface temperature, water column denitrification and surface productivity to the timing of northern or southern polar climate during the last 100,000 yr. Our results support a hypothesis that the Southern Hemisphere, and its connection to the low latitudes via shallow subsurface ocean circulation, has a primary influence on the biogeochemistry of the EEP. In addition, our results suggest that, during the last glacial stage, denitrification rates fluctuated on millennial timescales in response to water-column ventilation rather than upstream oxidant demand in intermediate-depth waters.However, due to the poor age constraints available for Marine Isotopic Stage (MIS) 3, the EEP sedimentary data presented here could support two conflicting mechanisms, one driven by enhanced intermediate overturning circulation in the Southern Ocean during Heinrich Events/Antarctic Warm Events, implying that subsurface flow rates control thermocline ventilation, and a second one consistent with more sluggish intermediate circulation during Antarctic Warm Events and giving a central role to the temperature control on oxygen solubility in Southern Ocean surface waters.     

Effects of short-term ecosystem experimental warming on water-extractable organic matter in an ombrotrophic Sphagnum peatland (Le Forbonnet, France)

In a future warmer world, peatlands may change from a carbon sink function to a carbon source function. This study tracks changes in water-extractable organic matter (WEOM) after 1 year of in situ experimental warming using open top chambers (OTCs). WEOM was studied in the upper peat layers (0–10 cm) through analysis of water-extractable organic carbon (WEOC), stable C isotopic composition (δ¹³C), specific UV absorbance at 280 nm and sugar composition of cores taken from an open bog (DRY sites) and a transitional poor fen (WET sites). At the DRY sites, the impact of OTCs was weak with respect to WEOM parameters, whereas at the WET sites, the air warming treatment led to a decrease in peat water content, suggesting that the supply of heat by OTCs was used mainly for evapotranspiration. OTCs at the WET sites also induced a relative enrichment at the surface (0–5 cm depth) of aliphatic and/or aromatic compounds with concomitant decrease in WEOC, as a result of decomposition. On the contrary, WEOC and sugar content increased in the deeper peat layer (7.5–10 cm depth) probably as a result of increased leaching of phenolic compounds by roots, which then inhibits microbial activity. The different response to experimental warming at DRY and WET sites suggests that the spatial variability of moisture is critical for understanding of the impact of global warming on the fate of OM and the carbon cycle in peatlands.     

Continental climate in the East Siberian Arctic during the last interglacial: Implications from palaeobotanical records

To evaluate the consequences of possible future climate changes and to identify the main climate drivers in high latitudes, the vegetation and climate in the East Siberian Arctic during the last interglacial are reconstructed and compared with Holocene conditions. Plant macrofossils from permafrost deposits on Bol'shoy Lyakhovsky Island, New Siberian Archipelago, in the Russian Arctic revealed the existence of a shrubland dominated by Duschekia fruticosa, Betula nana and Ledum palustre and interspersed with lakes and grasslands during the last interglacial. The reconstructed vegetation differs fundamentally from the high arctic tundra that exists in this region today, but resembles an open variant of subarctic shrub tundra as occurring near the tree line about 350 km southwest of the study site. Such difference in the plant cover implies that, during the last interglacial, the mean summer temperature was considerably higher, the growing season was longer, and soils outside the range of thermokarst depressions were drier than today. Our pollen-based climatic reconstruction suggests a mean temperature of the warmest month (MTWA) range of 9–14.5 °C during the warmest interval of the last interglacial. The reconstruction from plant macrofossils, representing more local environments, reached MTWA values above 12.5 °C in contrast to today's 2.8 °C. We explain this contrast in summer temperature and soil moisture with a combination of summer insolation higher than present and climatic continentality in arctic Yakutia stronger than present as result of a considerably less inundated Laptev Shelf during the last interglacial.     

Pétrographie et géochimie comparées des pellets phosphatés et de leur gangue dans le gisement phosphaté de Ras-Draâ (Tunisie). Implications sur la genèse des pellets phosphatés

Paléocène-Early Eocene phosphate outcrop in the Ras-Draâ deposit (Tunisia) comprises alternances of P-rich strata (P₂O₅ ≥ 18%) and P-poor ones (P₂O₅ ≤ 2%). In phosphate rich strata, P is concentrated in rounded grains—so-called pellets—(28% ≤ P₂O₅ ≤ 38%) embedded in a matrix—so-called exogangue—much poorer in P (P₂O₅ # 7%) than pellets. The study of pellets (whose size lies mainly between 100 and 500 μm), of their surrounding matrix and of poorly phosphatic sediments, interlayered between the phosphatic strata, has been performed by optical microscopy and various chemical analyses, ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectroscopy) and punctual chemical analyses by EDS (Energy Dispersive Spectroscopy). Mineralogical and chemical studies of the Tunisian phosphatic pellets show that the basic mineralogical component of these grains is carbonate-fluor-apatite, or francolite. The structural formula of a representative specimen of francolite in the basin is as follows: (Ca_4.63Mg_0.13Na_0.22)(PO₄)_2.51(CO₃)_0.48(OH_0.77F_0.23). The mineralogy of the constituents of the sediment surrounding pellets comprises carbonates, clays, silica (opal, quartz). Microscopic observations of Ras-Draâ phosphorites, added to geochemical results, establish that pellets are small bodies, allochtonous to their matrix and whose composition is independent of that of this matrix. Fecal cylindrical bodies and subspherical pellets, the latest being supposed to proceed from the fecal bodies by fragmentation, are considered to have been formed by fishes, as P-rich and organic matter-rich faeces. These faeces turn out to be resistant to mechanical dispersion and to chemical diffusion of soluble elements from and in direction of sea water. This closeness is responsible for the strong reducing conditions having prevailed inside and during the pellets diagenesis.     

Hercynite–quartz-bearing granulites from Brejões Dome area, Jequié Block, Bahia, Brazil: Influence of charnockite intrusion on granulite facies metamorphism

In the present study, we describe and discuss the geology of aluminous–magnesian granulites and associated garnet-bearing charnockitic granulite from the Brejões Dome area, located in the Jequié Block, part of the São Francisco Craton in Bahia, Brazil. Investigation of metamorphic mineral assemblages allows the evaluation of P–T conditions for the formation of these rocks, and therefore to obtain constraints for the better understanding of the geological evolution of the area. We conclude that the rocks from the Brejões Dome area were formed under granulite facies conditions of low to intermediate pressure (5–8 kbar). Temperatures determined in samples of aluminous–magnesian granulites collected away from the dome are in the order of 850 °C, similar to those determined elsewhere in the southern part of the Itabuna–Salvador–Curaçá Orogen. However, samples of the same rock type collected close to the Brejões Dome are hercynite + quartz-bearing and record higher temperatures of about 900–1000 °C. It is suggested that the intrusion of the Brejões charnockite diapir was responsible for a local increase in temperature above the peak temperature of regional granulite metamorphism.     

Estimation de la température maximale d'enfouissement du Toarcien et du Callovo-Oxfordien au centre du bassin de Paris par les marqueurs organiques

The thermal history of the central part of the Paris basin is reconstructed using C₃₁ hopane $\mathrm{S}/\mathrm{R}$ isomerisation ratios and organic matter transformation ratios measured on Lower Toarcian and Callovo-Oxfordian samples. Maximum burial palaeotemperatures range between 90 and 115?°C for the Toarcian shales, and between 75 and 95?°C for the Callovo-Oxfordian samples, from the East to the centre of the basin, respectively. The amount of Late Cretaceous erosion was evaluated to be between ca. 400 to 600 m in the eastern part of the studied area and 100 to 300 m in the centre of the basin. To cite this article: C. Ménétrier et al., C. R. Geoscience 337 (2005).     

Amphibolite facies conditions in the oceanic crust: example of amphibolitized flaser-gabbro and amphibolites from the Chenaillet ophiolite massif (Hautes Alpes,France)

Petrological and mineralogical data on amphibolitized gabbros from an Alpine ophiolite massif (Chenaillet Massif, France) are presented. Comparison with metagabbros dredged from the ocean floor shows that synkinematic amphibolite facies conditions may be reached in gabbros after their initial crystallization in the vicinity of the ridge. It is suggested that sub-horizontal plastic flow took place in the gabbroic layer near the axis of a slowly spreading ocean ridge before the intrusion of diabase dykes. This thermo-tectonic regime which at the Chenaillet produced flaser-gabbros and layers of foliated amphibolites with brown hornblende and pargasite, probably also affected most of the other ophiolitic gabbros of the Piemont zone prior to the low-temperature/high-pressure Alpine metamorphism.