Air Flow Structure Over Short-gravity Breaking Water Waves

Despite its importance for momentum and mass transfer across the air–sea interface, the dynamics of airflow over breaking waves is largely unknown. To fill this gap, velocity and vorticity distributions above short-gravity breaking waves have been measured in a wind-wave tank. A Digital Particle Image velocimetry technique (DPIV) was developed to accomplish these measurements above single breaking waves, propagating in mechanically-generated wave groups and forced by the wind. By varying the wind speed and initial characteristics of the groups, the airflow structure was captured over waves at different stages of the breaking process, and breaking with various intensities. The instantaneous airflow that separates from a sharp breaking crest is very similar to that occurring over a backward facing step. The separation bubble is however strongly unsteady: the steeper the wave crest and the larger the Reynolds number based on the crest-height, the higher the separated layer and the farther downwind the reattachment point. Instantaneous flow topology displays specific features of three-dimensional separation patterns. The tangential stress above the wave profile does not exhibit spikes at reattachment but grows progressively downwind from zero at reattachment to a value at the next crest approximately that found at the upwind breaking crest. Static pressure measurements revealed that large pressure falls are generated by vortices in the separated layer, as found in separated flows over solids. This study may provide useful data for theoretical and numerical modelling of the flow and associated phenomena.     

La lune mange-t-elle les couleurs?

The hydrogen radicals play an important role in the photochemistry of the troposphere of the Earth. The chemistry of OH, HO₂ and H₂O₂ is linked directly to the photodissociation of O₃ through the production of O(¹D). Gaseous H₂O₂ (hydrogen peroxide may be removed by heterogeneous reactions involving aerosols and liquid water. During the day and the night the solubility of ambient H₂O₂ in water is estimated and the oxidant capacity of H₂O₂ may explain the bleaching properties of the dew used in the past. This phenomenon may also explain some old maxims concerning the properties of the Moon's light to corrupt colors.     

Temperature effect on the photodissociation rates in the atmospheres of Mars and Venus

The available solar flux at a given altitude in the atmospheres of Mars and Venus is attenuated mainly by CO₂ (molecular absorption and Rayleigh scattering) with an extra contribution due to SO₂ on Venus. The dissociation cross section of CO₂ depends on temperature. At temperatures appropriate for these atmospheres (～250°K), the cross sections are about 15% lower than those at room conditions (Y.L. Yung and W.B. De More, 1982, Icarus, 51, 199). It is shown that this temperature effect cannot be neglected in the evaluation of photolysis rates. Calculations of the photodissociation coefficients of CO₂, SO₂, HCl, and H₂O are presented. For example, at the surface of Mars, the coefficient of H₂O is nearly multiplied by a factor of 10!     

The Saharan Metacraton

This article introduces the name “Saharan Metacraton” to refer to the pre-Neoproterozoic––but sometimes highly remobilized during Neoproterozoic time––continental crust which occupies the north-central part of Africa and extends in the Saharan Desert in Egypt, Libya, Sudan, Chad and Niger and the Savannah belt in Sudan, Kenya, Uganda, Congo, Central African Republic and Cameroon. This poorly known tract of continental crust occupies 5,000,000 km² and extends from the Arabian-Nubian Shield in the east to the Tuareg Shield to the west and from the Congo craton in the south to the Phanerozoic cover of the northern margin of the African continent in southern Egypt and Libya. The term “metacraton” refers to a craton that has been remobilized during an orogenic event but is still recognizable dominantly through its rheological, geochronological and isotopic characteristics. Neoproterozoic remobilization of the Saharan Metacraton was in the forms of deformation, metamorphism, emplacement of igneous bodies, and probably local episodes of crust formation related to rifting and oceanic basin development. Relics of unaffected or only weakly remobilized old lithosphere are present as exemplified by the Archean to Paleoproterozoic charnockites and anorthosites of the Uweinat massif at the Sudanese/Egyptian/Libyan boarder. The article explains why the name “Saharan Metacraton” should be used, defines the boundaries of the metacraton, reviews geochronological and isotopic data as evidence for the presence of pre-Neoproterozoic continental crust, and discusses what happened to the Saharan Metacraton during the Neoproterozoic. A model combining collisional processes, lithospheric delamination, regional extension, and post-collisional dismembering by horizontal shearing is proposed.     

Découverte d''une frayère de poissons téléosteens dans des diatomites messiniennes du Djebel Murdjadjo (environs d''Oran, Algérie)

A new locality of Messinian fossil fish has been found in the diatomite outcropping in the surroundings of the former “Ferme Giraud”, in the Murdjadjo Massif (near Oran, Algeria). It has yielded an oligospecific fish fauna, including five species indicative of a littoral marine environment that may have occurred in a gulf bottom. This was probably linked to a brackish lagoon, as indicated by the diatom flora.     

The “Taourirt” magmatic province, a marker of the closing stage of the Pan-African orogeny in the Tuareg Shield: review of available data and Sr–Nd isotope evidence

The Tuareg Shield, located between the Archaean to Palaeoproterozoic Saharan metacraton and the West African craton, is composed of 23 recognized terranes that welded together during the Neoproterozoic Pan-African orogeny (750–520 Ma). Final convergence occurred mainly during the 620–580 Ma period with the emplacement of high-K calc-alkaline batholiths, but continued until 520 Ma with the emplacement of alkali-calcic and alkaline high-level complexes. The last plutons emplaced in central Hoggar at 539–523 Ma are known as the “Taourirt” province. This expression is redefined and three geographical groups are identified: the Silet-, Laouni- and Tamanrasset-Taourirts. The Silet-Taourirts are cross-cutting Pan-African island arc assemblages while the two others intrude the Archaean–Palaeoproterozoic LATEA metacraton. The Taourirts are high-level subcircular often nested alkali-calcic, sometimes alkaline, complexes. They are aligned along mega-shear zones often delimiting terranes. Mainly granitic, they comprise highly differentiated varieties such as alaskite (Silet-Taourirts) and topaz–albite leucogranite (Tamanrasset-Taourirts). Different subgroups were defined on the basis of REE patterns and major and other trace elements. The Taourirt province displays a wide transition from dominant alkali-calcic to minor alkaline granite varieties. Sr isotopes indicate that these complexes were affected by fluid circulation during the Ordovician along shear zones probably contemporaneous to the beginning of the Tassilis sandstone deposition. Nd isotope systematic indicates a major interaction with the upper crust during the emplacement of highly differentiated melts, particularly in samples showing seagull wing-shaped REE patterns. On the other hand, all Taourirt plutons are strongly contaminated by the lower crust: _Nd vary from −2 to −8 and T_DM from 1200 to 1700 Ma. This implies the presence of an old crust at depth, also below the Silet-Taourirts, which are emplaced within Pan-African island arc assemblages. A model is proposed for the genesis of the Taourirt province where reworking of the mega-shear zones, which dissected the LATEA metacraton, provoked a linear delamination of the lithospheric mantle, asthenosphere uprise and partial melting of the lower crust (or strong interaction with), giving rise to a mixed source.     

Contrasting origin of post-collisional high-K calc-alkaline and shoshonitic versus alkaline and peralkaline granitoids. The use of sliding normalization

Abundant high-K calc-alkaline (HKCA) magmatism appears to be post-collisional and often shifts to shoshonitic or alkaline–peralkaline compositions in the final stages of orogeny. The nature and the causes of this transition are studied on the basis of 308 major element and of 86 unpublished trace element (including REE) analyses of the Pan-African granitoids from the Tuareg shield (Adrar des Iforas, Mali and Aïr, Niger). This database covers a wide variety of magmas from subduction-related to intraplate-type including abundant HKCA batholiths. Literature data from geodynamically well-constrained cases are also included. In addition to a conventional geochemical approach of the studied magmatism, the sliding normalization method is proposed. This tool aims at comparing magmatic series: each studied rock is normalized to the interpolated composition of the reference series that has the same SiO₂ content as the sample. This method amplifies differences in sources and in fractionation processes and allows comparison of rocks from basic to acid composition. Two distinct juvenile sources are proposed: a previously enriched phlogopite-K richterite bearing lithospheric mantle or a lower juvenile crustal equivalent for HKCA-shoshonitic magmas, and a lowest lithospheric-upper asthenospheric OIB-type mantle for alkaline-peralkaline magmatism. The first source is melted only shortly after its generation when the lithosphere was still hot, which restricts HKCA magmatism mainly to post-collisional settings. The second asthenospheric/lowest lithosphere source is by definition close to its melting temperature and can generate magma ubiquitously both in space and time. The main melting triggers are lithospheric major structures which are not only operative in a post-collisional setting but also in other environments such as intraplate setting. Geochemistry thus gives indications about the nature of the source and on geotectonic settings. However, the latter is a second rank information, which is partly model-dependant. The post-collisional period differs from other settings by a propensity to generate large amounts of magma of various kinds, among which HKCA magmatism is volumetrically the most prominent.