Preliminary study on the dissolved and colloidal organic carbon in the Zhujiang River estuary

ＩＮＴＲＯＤＵＣＴＩＯＮＥｓｔｕａｒｉｅｓｃｏｍｐｒｉｓｅａｍａｊｏｒｂｉｏｇｅｏｃｈｅｍｉｃａｌｉｎｔｅｒｆａｃｅｃｏｎｎｅｃｔｉｎｇｔｈｅｌａｎｄａｎｄｔｈｅｓｅａ (Ｍａｎ ｔｏｕｒａ,1 987) .Ｔｈｅｂｅｈａｖｉｏｒａｎｄｆａｔｅｏｆａｐａｒｔｉｃｕｌａｒｒｉｖｅｒ ｂｏｒｎｅｓｕｂｓｔａｎｃｅｉｎｔｒｏｄｕｃｅｄｉｎｔｏａｎｅｓｔｕａｒｙｉｓｄｅｔｅｒｍｉｎｅｄｔｏａｌａｒｇｅｅｘｔｅｎｔｂｙｔｈｅｂｉｏｇｅｏｃｈｅｍｉｃａｌｐｒｏｐｅｒｔｉｅｓｏｆｔｈｅｓｕｂｓｔａｎｃｅａｓｗｅｌｌａｓｐ…     

Analysis of seafloor backscatter strength dependence on the survey azimuth using multibeam echosounder data

The sediment backscatter strength measured by multibeam echosounders is a key feature for seafloor mapping either qualitative (image mosaics) or quantitative (extraction of classifying features). An important phenomenon, often underestimated, is the dependence of the backscatter level on the azimuth angle imposed by the survey line directions: strong level differences at varying azimuth can be observed in case of organized roughness of the seabed, usually caused by tide currents over sandy sediments. This paper presents a number of experimental results obtained from shallow-water cruises using a 300-kHz multibeam echosounder and specially dedicated to the study of this azimuthal effect, with a specific configuration of the survey strategy involving a systematic coverage of reference areas following “compass rose” patterns. The results show for some areas a very strong dependence of the backscatter level, up to about 10-dB differences at intermediate oblique angles, although the presence of these ripples cannot be observed directly—neither from the bathymetry data nor from the sonar image, due to the insufficient resolution capability of the sonar. An elementary modeling of backscattering from rippled interfaces explains and comforts these observations. The consequences of this backscatter dependence upon survey azimuth on the current strategies of backscatter data acquisition and exploitation are discussed.     

Inorganic arsenic speciation in the waters of the Penzé estuary (NW France): Seasonal variations and fluxes to the coastal area

Over this one-year study, the variations of inorganic As species were examined monthly along the salinity gradient of the Penzé estuary (NW France) in relation with different biogeochemical parameters. In most cases, dissolved As exhibited a non-conservative behaviour which resulted from the competition between two major processes. In the upstream section of the estuary, a strong input of both total inorganic As and As(III) occurred. Then, the removal of the same species, under precipitation of iron oxides/oxyhydroxides, was observed in the low-salinity range (S < 10). Using our experimental data, the fluxes of the various As species were estimated for the first time in estuarine waters. Inputs from the river were mainly constituted of particulate As (∼70%). Conversely, dissolved species were predominant in the net fluxes (∼65%) and As(III) accounted for ∼15% of the dissolved net flux.     

Kinetic and equilibrium studies of copper-dissolved organic matter complexation in water column of the stratified Krka River estuary (Croatia)

An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (K_i^equ), total ligands concentration (L_iT) and association/dissociation rate constants (k_i¹,k_i^- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K₁^equ: 11.2–13.0, log K₂^equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k₁¹:6.1–20 × 10³ (M s)^− 1, k₂¹: 1.3–6.3 × 10³ (M s)^− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µM_C, i.e. 1 mg_CL^− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).     

Oxygen and organic carbon fluxes in sediments of the Bay of Biscay

The relationship between particulate organic carbon (POC) concentrations measured in modern sediment and fluxes of exported POC to the sediment surface needs to be understood in order to use POC content as a proxy of paleo-environmental conditions. The objective of our study was to compare POC concentrations, POC mineralization rates calculated from O₂ consumption and POC burial rates. Benthic O₂ distributions were determined in 58 fine-grained sediment cores collected at different periods at 14 stations in the southeastern part of the Bay of Biscay with depths ranging from 140 to 2800 m. Depth-dependent volume-specific oxygen consumption rates were used to assess rates of aerobic oxidation of organic matter (OM), assuming that O₂ consumption solely was related to heterotrophic activity at the sediment–water interface. Heterogeneity of benthic O₂ fluxes denoted changes in time and space of fresh organic material sedimentation. The most labile fraction of exported POC engendered a steep decrease in concentration in the upper 5 mm of vertical O₂ profiles. The rupture in the gradient of O₂ microprofile may be related to the bioturbation-induced mixing depth of fast-decaying carbon. Average diffusive O₂ fluxes showed that this fast-decaying OM flux was much higher than buried POC, although diffusive O₂ fluxes underestimated the total sediment oxygen demand, and thus the fast-decaying OM flux to the sediment surface. Sedimentary POC burial was calculated from sediment mass accumulation rate and the organic carbon content measured at the top of the sediment. The proportion of buried POC relative to total exported POC ranged at the most between 50% and 10%, depending on station location. Therefore, for a narrow geographic area like the Bay of Biscay, burial efficiency of POC was variable. A fraction of buried POC consisted of slow-decaying OM that was mineralized within the upper decimetres of sediment through oxic and anoxic processes. This fraction was deduced from the decrease with depth in POC concentration. At sites located below 500 m water depth, where the fast-decaying carbon did not reach the anoxic sediment, the slow-decaying pool may control the O₂ penetration depth. Only refractory organic material was fossilized in sedimentary records at locations where labile OM did not reach the anoxic portion of the sediment.     

Retardation of dissolved radiocarbon through a carbonated matrix

Spiked solutions (¹⁴C and ³H) were passed through two columns, one filled with silica and one with a mixture of silica and carbonate sand. Significant delay of ¹⁴C vs. ³H appeared in the second material and leads to a reduction of the relative flow rate which reaches 40%. Three types of effects causing modifications of the ¹⁴C transfer are analysed: (i) flow rate, (ii) sediment aging (iii) solution chemical composition and load. The reside with respect to water is governed by a linear process (assuming a constant number of reacting sites on the matrix) and kinetic process (where mass transfer effects are significant). It is also shown that much less than one mono-molecular layer of solid carbonate is involved and a distribution coefficient was estimated for these dynamic runs. Under field conditions, the interaction between ¹⁴C species (in the mobile and in the stationary phases) make ages obtained by ¹⁴C overestimated.     

Eruptive history of the Colima volcanic complex (Mexico)

The evolution of the Colima volcanic complex can be divided into successive periods characterized by different dynamic and magmatic processes: emission of andesitic to dacitic lava flows, acid-ash and pumice-flow deposits, fallback nuées ardentes leading to pyroclastic flows with heterogeneous magma, plinian air-fall deposits, scoriae cones of alkaline and calc-alkaline nature. Four caldera-forming events, resulting either from major ignimbrite outbursts or Mount St. Helens-type eruptions, separate the main stages of development of the complex from the building of an ancient shield volcano (25 × 30 km wide) up to two summit cones, Nevado and Fuego.The oldest caldera, C1 (7–8 km wide), related to the pouring out of dacitic ash flows, marks the transition between two periods of activity in the primitive edifice called Nevado I: the first one, which is at least 0.6 m.y. old, was mainly andesitic and effusive, whereas the second one was characterized by extrusion of domes and related pyroclastic products. A small summit caldera, C2 (3–3.5 km wide), ended the evolution of Nevado I.Two modern volcanoes then began to grow. The building of the Nevado II started about 200,000 y. ago. It settled into the C2 caldera and partially overflowed it. The other volcano, here called Paleofuego, was progressively built on the southern side of the former Nevado I. Some of its flows are 50,000 y. old, but the age of its first outbursts is not known. However, it is younger than Nevado II. These two modern volcanoes had similar evolutions. Each of them was affected by a huge Mount St. Helens-type (or Bezymianny-type) event, 10,000 y. ago for the Paleofuego, and hardly older for the Nevado II. The landslides were responsible for two horseshoe-shaped avalanche calderas, C3 (Nevado) and C4 (Paleofuego), each 4–5 km wide, opening towards the east and the south. In both cases, the activity following these events was highly explosive and produced thick air-fall deposits around the summit craters.The Nevado III, formed by thick andesitic flows, is located close to the southwestern rim of the C3 caldera. It was a small and short-lived cone. Volcan de Fuego, located at the center of the C4 caldera, is nearly 1500 m high. Its activity is characterized by an alternation of long stages of growth by flows and short destructive episodes related to violent outbursts producing pyroclastic flows with heterogeneous magma and plinian air falls.The evolution of the primitive volcano followed a similar pattern leading to formation of C1 and then C2. The analogy between the evolutions of the two modern volcanoes (Nevado II–III; Paleofuego-Fuego) is described. Their vicinity and their contemporaneous growth pose the problem of the existence of a single reservoir, or two independent magmatic chambers, after the evolution of a common structure represented by the primitive volcano.     

Development of a hydrodynamic model of the Bay of Biscay. Validation of hydrology

The hydrology of the Bay of Biscay was investigated using the regional ocean model MARS3D (Model for Application at Regional Scale). The simulated hydrology is compared to a set of various data encompassing monthly climatology, remote sensing SST, CTD casts, and coastal salinity measurements. Special focus was put on the validation over the continental shelf. This paper reports that despite some misfits, the climatological hydrology and its seasonal variability are correctly simulated. Various statistics computed over the period from 1999–2004 highlight different aspects of the hydrology. The biases and root mean square errors (RMSE) remain very weak at all depths when comparing salinity (<0.1 and <0.6 psu respectively). The predicted temperature shows a global overestimation of temperature (bias of around 0.8 °C) and the maximum errors are located near the thermocline (rmse of 1 °C at 20–40 m). The model is shown to properly reproduce the annual dynamics of sea surface temperature, as well as the dynamics of large river plumes observed by high frequency time series from coastal salinity gauges. The misfits highlighted by these various comparisons between model and observations are attributed to heat fluxes and mixing parameterisation.