Predicting the impact of land use on the major element and nutrient fluxes in coastal Mediterranean rivers: The case of the Têt River (Southern France)

This study presents a detailed discrimination between the natural and anthropogenic sources of dissolved major elements in the Têt River, a typical small coastal river in the south of France. The main objectives were to quantify the materials that were released by human activities in the basin, and to determine the specific element inputs for the major land use forms. The dissolved material fluxes were estimated by weekly monitoring over a hydrological year (2000–2001) along the major water gauging stations, and the flux relationships were examined in the context of anthropogenic and natural basin characteristics as determined by a Geographical Information System (GIS). Intensive agricultural land use in the form of fruit tree cultures and vineyards has a strong control on the dissolved element fluxes in the river. Area specific element releases for these cultures are greatest for SO₄, with an estimated average of about 430 ± 18 keq km⁻² a⁻¹. This is ?11 times the natural SO₄ release by rock weathering. Also for K, NO₃, PO₄ and Mg, the specific releases were ?6 times the natural weathering rates (respectively about 44, 60, 4 and 265 keq km⁻² a⁻¹). Waste-waters are the other major source of anthropogenic elements in the river. They have an important role for the fluxes of inorganic P and N, but they are also a considerable source of Cl and Na to the river. For example, the average annual release of Cl is around 150 moles/inhabitant in the rural basin parts. Further downstream, however, where population density strongly increases, industrial effluents can enhance this value (>300 moles/inhabitant). The waste-waters contribute more than 70% of the dissolved inorganic N export to the sea, although their contribution to the average DOC export is almost negligible (3%).     

Experimental study of D/H isotopic fractionation factor of water adsorbed on porous silica tubes

This paper presents D/H isotopic fractionation factor measurements of water adsorbed on porous silica tubes in isotopic equilibrium with water vapor. The fractionation factor is measured as a function of vapor pressure ranging from 10% to 80% RH (relative humidity) at room temperature. It is shown that the fractionation factor between the adsorption film or nanometrically confined water and vapor is smaller than that between bulk liquid water and vapor. A qualitative analysis relates this deuterium depletion to a modification of the zero-point energy of the water isomers in the adsorbed/confined state. Furthermore, the behavior of the fractionation factor with RH shows two different linear trends. The transition between the two (at 60% RH) may indicate the transition from a two-dimensional adsorbed water to a three-dimensional water network.     

Evidence for fault-related directionality and localized site effects from strong motion recordings of the 2003 Boumerdes (Algeria) earthquake: Consequences on damage distribution and the Algerian seismic code

The Algiers–Boumerdes region has been struck by a destructive magnitude 6.8 (M_w) earthquake on May 21, 2003. The study presented in this paper is based on main shock strong motions from 13 stations of the Algerian accelerograph network. A maximum 0.58g peak ground acceleration (PGA) has been recorded at 20 km from the epicenter, only about 150 m away from a PGA of 0.34g, with both a central frequency around 5 Hz, explained by a strong very localized site effect, confirmed by receiver function technique results showing peaks at 5 Hz with amplitudes changing by a factor of 2. Soil amplifications are also evidenced at stations located in the quaternary Mitidja basin, explaining the higher PGA values recorded at these stations than at stations located on firm soil at similar distances from the epicenter. A fault-related directionality effect observed on the strong motion records and confirmed by the study of the seismic movement anisotropy, in agreement with the N65 fault plan direction, explains the SW–NE orientation of the main damage zone. In the near field, strong motions present a high-frequency content starting at 3 Hz with a central frequency around 8 Hz, while in the far field their central frequency is around 3 Hz, explaining the high level of damage in the 3- to 4-story buildings in the epicentral zone. The design spectra overestimate the recorded mean response spectra, and its high corner frequency is less than the recorded one, leading to a re-examination of the seismic design code that should definitively integrate site-related coefficient, to account for the up to now neglected site amplification, as well as a re-modeling of the actual design spectra. Finally, both the proposed Algerian attenuation law and the worldwide laws usually used in Algeria underestimate the recorded accelerations of the 6.8 (M_w) Boumerdes earthquake, clearly showing that it is not possible to extrapolate the proposed Algerian law to major earthquakes.     

Optical studies of natural deformation microstructures in feldspars (gneiss and pegmatites from Occitania,southern France)

Natural deformation microstructures of feldspars have been investigated optically in augen gneisses and pegmatites from southern France that exhibit microstructures due to polyphase deformation. This deformation was produced in both cases under a pressure of about 2 Kb and a temperature decreasing from about 550° to 200–300°C.In microcline, recrystallization, tension gashes and shear planes are the most important microstructures observed. In plagioclase, shear planes and kink-bands prevail. The development of these structures is controlled primarily by three parameters: temperature, influence of the surrounding material and amount of bulk strain. The orientation of the planes of anisotropy of the minerals with respect to the compression axis is also important. Some perthitic patterns are ascribed to deformation.     

Metal corrosion and argillite transformation at the water-saturated,high-temperature iron–clay interface: A microscopic-scale study

In this study, microscopic and spectroscopic techniques (scanning electron microscopy coupled with energy-dispersive X-ray analysis, Raman microspectroscopy, micro X-ray fluorescence spectroscopy, micro X-ray fine structure adsorption spectroscopy, and micro laser-induced breakdown spectroscopy) were combined to decipher the chemical and mineralogical properties of a saturated Fe–clay interface reacted at 90 °C and 50 bar for 8 months. The results collectively confirm the presence of a corrosion layer and a clay transformation layer. The corrosion layer is made of a magnetite-containing internal sublayer and a Fe-phyllosilicate external sublayer enriched in Na, with traces of goethite presumably resulting from sample reaction with air. The clay transformation layer is made of predominantly Ca-rich siderite (FeCO₃). It is depleted in Al and K, suggesting dissolution of rock-forming minerals. The corroded thickness determined from the amount of Fe in corrosion and transformation layers and assuming zero porosity equals 19 ± 9 μm. These data indicate that the interfacial clay was transformed by dissolution of calcite and clay minerals and precipitation of siderite close to the original surface. Silica released upon clay dissolution diffused into the corrosion layer and coprecipitated with oxidized Fe to form Fe-phyllosilicate.     

Submesoscale vortex structures at the entrance of the Gulf of Lions in the Northwestern Mediterranean Sea

The meanders of a baroclinic coastal current in the Northwestern Mediterranean Sea have already been reported in the literature. These meanders can be surrounded by vortices. Such vortices have been observed in the western part of the Gulf of Lions but the location and the mechanism of their formation are poorly documented. In this paper, we use the current measurements of a one-year experiment, which was conducted in the eastern part of the Gulf of Lions to detect and characterize the vortex activity. A vortex detection algorithm based on few velocity data was developed. Current measurements were available at the sea surface (HF radars) and in the water column from 50 to 140 m depth (four current meter moorings). SST images and hydrologic data were also used. Results focus on observations that are coherent 50 m and at the surface. Vortices are anticyclonic, of submesoscale size and present maximal velocities of 30–50 cm/s. The drift speed of the vortices is comparable to but less than the velocity of the Northern Current. These observations enable to estimate the minimum vortex occurrence in this area. The presence of vortex structures is strongly correlated with a specific sequence of wind patterns.     

Mediterranean Sea and anthropogenic influences on ambient vibration amplitudes in the low-frequency and high-frequency domains in the Algiers region

Ambient vibrations have been continuously recorded at Dar El Beida, about 20 km from Algiers (Algeria). This data set allows determining that, in the low-frequency domain (<1 Hz), ambient vibration sources are mainly linked to Mediterranean Sea effects, while in the high-frequency domain, they are closely related to anthropogenic activity. Climatic conditions have an influence on the ambient vibration spectral amplitudes in the low-frequency domain, which is not the case in the high-frequency domain. The limit between the low-frequency and high-frequency domain, based on natural versus anthropogenic activity, is not clear cut and lies between 1.25 and 1.50 Hz. Variations of H/V peak amplitudes in the low-frequency domain are clearly linked to the climatic conditions. In the high-frequency domain, H/V peaks are not related to climatic conditions and cannot be clearly related to anthropogenic source changes.     

A new experimental technique for extracting liquids from peridotite at very low degrees of melting: application to partial melting of depleted peridotite

A new technique that allows extraction of liquids from peridotite at degrees of melting as low as 0.2 wt% is presented. Microfractures that formed in the graphite sample container at the beginning of the experiments were used as traps for the liquid phase. Glass-filled cracks (or 'microdikes') unaffected by quench crystallisation were produced in all experiments and were analysed using standard electron microprobe techniques. Reversal experiments demonstrated that, at moderate degrees of melting (4.4 and 6.5 wt%), the segregated liquid was in equilibrium with the neighbouring peridotite. At very low degrees of melting (0.3 wt%), the liquid in the microdikes failed to fully equilibrate with the peridotite after 5 days and the sandwich technique was used in combination with the microdike technique to approach more closely the equilibrium composition of near-solidus partial melts. The microdike technique was used to study melting of a depleted peridotite at 1 GPa and 1,220 to 1,360 °C.Editorial responsibility: T.L. Grove