Water-poverty relationships in the coastal town of Mbour (Senegal): Relevance of GIS for decision support

Coastal area is always a zone with complex problems. Due to the attraction they exert, are facing many social problems. Therefore, a coastal city is usually a city with problems. Its extension, caused by the influx of people from different backgrounds, creates an increased demand for services. One of the problems frequently encountered, especially in Senegal, is access to water. The problem of access to water is poorly treated, without being correlated with the urban evolution, i.e. with increasing population and demand growth. The water resource is facing numerous complications such as the lack of integrated management, integration issues at the governance level, where the local factor is often forgotten.The town of Mbour, object of our study, does not come out of that lot, being an attractive coastal city, from an African country. This indicates the need for an integrated management oriented from local to a global basis and not vice versa. The study presented in this paper indicates that a large proportion of the population has not access to a verified drinking water system and uses water from wells or standpipes. Half of the surveyed population (50%) has no access to a water supply system. The water poverty map of the town overlaps with that of the general poverty excepting few neighborhoods. This means that even areas that are not affected by poverty have a very low or poor access to water, which so far remains the perverse effect of the reform of the Senegalese water sector in 1995.     

Influence of Thermal Effects on the Wind Field Within the Urban Environment

Micrometeorological conditions in the vicinity of urban buildings strongly influence the requirements that are imposed on building heating and cooling. The goal of the present study, carried out within the Advance Tools for Rational Energy Use towards Sustainability (ATREUS) European research network, is the evaluation of the wind field around buildings with walls heated by solar radiation. Two computational fluid dynamics (CFD) codes were validated against extensive wind-tunnel observations to assess the influence of thermal effects on model performance. The code selected from this validation was used to simulate the wind and temperature fields for a summer day in a specific region of the city of Lisbon. For this study, the meteorological data produced by a non-hydrostatic mesoscale atmospheric model (MM5) were used as boundary conditions for a CFD code, which was further applied to analyze the effects of local roughness elements and thermodynamic conditions on the air flow around buildings. The CFD modelling can also provide the inflow parameters for a Heating, Ventilation and Air Conditioning (HVAC) system, used to evaluate the building energy budgets and to predict performance of the air-conditioning system. The main finding of the present three-dimensional analyses is that thermal forcing associated with the heating of buildings can significantly modify local properties of the air flow.     

Short-Term Periodicities in Sunspot Activity and Flare Index Data during Solar Cycle 23

The short-term periodicities in sunspot numbers, sunspot areas, and flare index data are investigated in detail using the Date Compensated Discrete Fourier Transform (DCDFT) for the full disk of the Sun separately over the rising, the maximum, and the declining portions of solar cycle 23 (1996 – 2006). While sunspot numbers and areas show several significant periodicities in a wide range between 23.1 and 36.4 days, the flare index data do not exhibit any significant periodicity. The earlier conclusion of Pap, Tobiska, and Bouwer (1990, Solar Phys. 129, 165) and Kane (2003, J. Atmos. Solar-Terr. Phys. 65, 1169), that the 27-day periodicity is more pronounced in the declining portion of a solar cycle than in the rising and maximum ones, seems to be true for sunspot numbers and sunspot area data analyzed here during solar cycle 23.     

Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens

X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [Fe^II₄Fe^III₂(OH)₁₂CO₃: GR1(CO₃)], which completely converted into ferrous-carbonate hydroxide (Fe^II₂(OH)₂CO₃: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO₃) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO₃) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO₃) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)₂ phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)₂ nanoparticles as oligomers binding to the edges of Fe(OH)₆ octahedra at the edges of the octahedral layers of Fe(OH)₂. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.     

Biogenic nanoparticulate UO2: Synthesis, characterization, and factors affecting surface reactivity

The surface reactivity of biogenic, nanoparticulate UO₂ with respect to sorption of aqueous Zn(II) and particle annealing is different from that of bulk uraninite because of the presence of surface-associated organic matter on the biogenic UO₂. Synthesis of biogenic UO₂ was accomplished by reduction of aqueous uranyl ions, by Shewanella putrefaciens CN32, and the resulting nanoparticles were washed using one of two protocols: (1) to remove surface-associated organic matter and soluble uranyl species (NAUO2), or (2) to remove only soluble uranyl species (BIUO2). A suite of bulk and surface characterization techniques was used to examine bulk and biogenic, nanoparticulate UO₂ as a function of particle size and surface-associated organic matter. The N₂-BET surface areas of the two biogenic UO₂ samples following the washing procedures are 128.63 m² g⁻¹ (NAUO2) and 92.56 m² g⁻¹ (BIUO2), and the average particle sizes range from 5-10 nm based on TEM imaging. Electrophoretic mobility measurements indicate that the surface charge behavior of biogenic, nanoparticulate UO₂ (both NAUO2 and BIUO2) over the pH range 3-9 is the same as that of bulk. The U L_III-edge EXAFS spectra for biogenic UO₂ (both NAUO2 and BIUO2) were best fit with half the number of second-shell uranium neighbors compared to bulk uraninite, and no oxygen neighbors were detected beyond the first shell around U(IV) in the biogenic UO₂. At pH 7, sorption of Zn(II) onto both bulk uraninite and biogenic, nanoparticulate UO₂ is independent of electrolyte concentration, suggesting that Zn(II) sorption complexes are dominantly inner-sphere. The maximum surface area-normalized Zn(II) sorption loadings for the three substrates were 3.00 ± 0.20 μmol m⁻² UO₂ (bulk uraninite), 2.34 ± 0.12 μmol m⁻² UO₂ (NAUO2), and 2.57 ± 0.10 μmol m⁻² UO₂ (BIUO2). Fits of Zn K-edge EXAFS spectra for biogenic, nanoparticulate UO₂ indicate that Zn(II) sorption is dependent on the washing protocol. Zn-U pair correlations were observed at 2.8 ± 0.1 Å for NAUO2 and bulk uraninite; however, they were not observed for sample BIUO2. The derived Zn-U distance, coupled with an average Zn-O distance of 2.09 ± 0.02 Å, indicates that Zn(O,OH)₆ sorbs as bidentate, edge-sharing complexes to UO₈ polyhedra at the surface of NAUO2 nanoparticles and bulk uraninite, which is consistent with a Pauling bond-valence analysis. The absence of Zn-U pair correlations in sample BIUO2 suggests that Zn(II) binds preferentially to the organic matter coating rather than the UO₂ surface. Surface-associated organic matter on the biogenic UO₂ particles also inhibited particle annealing at 90 °C under anaerobic conditions. These results suggest that surface-associated organic matter decreases the reactivity of biogenic, nanoparticulate UO₂ surfaces relative to aqueous Zn(II) and possibly other environmental contaminants.     

Insects as zoogeomorphic agents: an extended review

Insects are the largest and most diverse group of living organisms on Earth, playing a critical but underestimated role as agents of geomorphic change. Burrowing insects create micro-scale landforms such as subterranean tunnels and surface mounds and, by this way, exert an influence on hydrology, soil erosion and sediment transfer at a wider landscape scale. However, social insects represented by ants and termites were the main taxa studied as geomorphic agents and ecosystem engineers. This article proposes an extended and critical literature review of insects as zoogeomorphic agents, with reference to various taxonomic orders and families of insects having a burrowing behaviour. It provides a large overview of their primary and secondary impacts on Earth surface systems, both supported by naturalistic evidence and available quantitative data. Some evolutionary insights are discussed based on fossil evidence of geomorphic work by insects and, at finer temporal scale, on recent advances in radiometric and luminescence dating of insect mounds. Finally, this article explores the fruitful links between geomorphology and entomology, and suggests several research perspectives in order to develop an integrated understanding of the importance of insects in Earth surface processes and landforms. © 2020 John Wiley & Sons, Ltd.     

Low post-Cenomanian denudation depths across the Brazilian Northeast: Implications for long-term landscape evolution at a transform continental margin

The Brazilian Northeast affords good opportunities for obtaining reliable timings and rates of landscape evolution based on stratigraphic correlations across a vast region. The landscape formed in the context of an episodically fluctuating but continuously falling base level since the Cenomanian. After formation of the transform passive margin in Aptian times, landscape development was further driven by a swell-like uplift with its crest situated  300 km from the coastline. The seaward flank of this swell or broad monocline between the interior Araripe and coastal Potiguar basins was eroded, and currently forms a deeply embayed plain bordered by a semi-circular, north-facing erosional escarpment. The post-Cenomanian uplift caused an inversion of the Cretaceous basins and generated a landscape in which the most elevated landforms correspond either to resistant Mesozoic sedimentary caprock, or to eroded stumps of syn-rift Cretaceous footwall uplands. Denudation in the last 90 My never exceeded mean rates of 10 m·My^− 1 and exhumed a number of Cretaceous stratigraphic unconformities. As a result, some topographic surfaces at low elevations are effectively Mesozoic land surfaces that became re-exposed in Cenozoic times. The Neogene Barreiras Formation forms a continuous and mostly clastic apron near the coast. It testifies to the last peak of erosion in the hinterland and coincided with the onset of more arid climates at  13 Ma or earlier. The semi-circular escarpment is not directly related to the initial breakup rift flanks, which had been mostly eroded before the end of the Mesozoic, but the cause and exact timing of post-Cenomanian crustal upwarping are poorly constrained. It could perhaps have been a flexural response of the low-rigidity lithosphere to sediment loads on the margin, and thus a slowly ongoing process since the late Cretaceous. Uplift could instead be the consequence of a more discrete dynamic event related either to Oligocene magmatism in the region, or to continental-scale far-field stresses determined by Andean convergence.     

Molecular study of insoluble organic matter in Kainsaz CO3 carbonaceous chondrite: Comparison with CI and CM IOM

Abstract— Kainsaz CO3 insoluble organic matter (IOM) was studied using Curie point pyrolysis, electronic paramagnetic resonance (EPR), and high‐resolution transmission electron microscopy (HRTEM) to determine the effect of thermal metamorphism on molecular chondritic fingerprints. Pyrolysis released a very low amount of products that consist of one‐ and two‐ring aromatic units with methyl, dimethyl, and ethyl substituents. Moreover, Kainsaz IOM contains two orders of magnitude fewer radicals than Orgueil, Murchison, and Tagish Lake IOM. In addition, no diradicaloids were found in Kainsaz, although they are thought to constitute a specific signature for weakly organized extraterrestrial organic compounds in contrast to terrestrial ones. HRTEM reveals a very heterogeneous structure, with microporous disordered carbon, mesoporous graphitic carbons and graphite. Graphitization likely occurs and explains the differences between Kainsaz and CI or CM IOM. Heating stress experienced by Kainsaz IOM, on the parent body and/or prior its accretion, is likely responsible for the differences in molecular and structural organizations compared with those of CI and CM IOM.     

From micro scale to boundary value problem: using a micromechanically based model

Acta Geotechnica - A 3D multi-scale approach is presented to investigate the mechanical behavior of a macroscopic specimen consisting of a granular assembly, as a boundary value problem. The core...     

Late Quaternary vegetation and climate dynamics in central-eastern Brazil: insights from a ~35k cal a bp peat record in the Cerrado biome

The late Quaternary evolution of central-eastern Brazil has been under-researched. Questions remain as to the origin of the Cerrado, a highly endangered biome, and other types of vegetation, such as the Capões – small vegetation islands of semi-deciduous and mountain forests. We investigated the factors that influenced the expansion and contraction of the Cerrado and Capões during the late Quaternary (last ~35 ka), using a multi-proxy approach: stable isotopes (δ¹³C, δ¹⁵N), geochemistry, pollen and multivariate statistics derived from a peat core (Pinheiro mire, Serra do Espinhaço Meridional). Five major shifts in precipitation, temperature, vegetation and landscape stability occurred at different timescales. Our study revealed that changes in the South Atlantic Convergence Zone (SACZ) seem to have been coeval with these shifts: from the Late Glacial Maximum to mid-Holocene the SACZ remained near (~29.6 to ~16.5k cal a bp ) and over (~16.5 to ~6.1 k cal a bp ) the study area, providing humidity to the region. This challenges previous research which suggested that climate was drier for this time period. At present, the Capões are likely to be a remnant of a more humid climate; meanwhile, the Cerrado biome seems to have stablished in the late Holocene, after ~3.1 k cal a bp .