Uncertainties of geochemical modeling during CO<Subscript>2</Subscript> sequestration applying batch equilibrium calculations

One of the uncertainties in the field of carbon dioxide capture and storage (CCS) is caused by the parameterization of geochemical models. The application of geochemical models contributes significantly to calculate the fate of the CO₂ after its injection. The choice of the thermodynamic database used, the selection of the secondary mineral assemblage as well as the option to calculate pressure dependent equilibrium constants influence the CO₂ trapping potential and trapping mechanism. Scenario analyses were conducted applying a geochemical batch equilibrium model for a virtual CO₂ injection into a saline Keuper aquifer. The amount of CO₂ which could be trapped in the formation water and in the form of carbonates was calculated using the model code PHREEQC. Thereby, four thermodynamic datasets were used to calculate the thermodynamic equilibria. Furthermore, the equilibrium constants were re-calculated with the code SUPCRT92, which also applied a pressure correction to the equilibrium constants. Varying the thermodynamic database caused a range of 61% in the amount of trapped CO₂ calculated. Simultaneously, the assemblage of secondary minerals was varied, and the potential secondary minerals dawsonite and K-mica were included in several scenarios. The selection of the secondary mineral assemblage caused a range of 74% in the calculated amount of trapped CO₂. Correcting the equilibrium constants with respect to a pressure of 125 bars had an influence of 11% on the amount of trapped CO₂. This illustrates the need for incorporating sensitivity analyses into reaction pathway modeling.     

Engineering geological data in support of municipal land use planning—a case study in Analandia, southeast Brazil

This paper presents a method for transforming the information of an engineering geological map into useful information for non-specialists involved in land-use planning. The method consists of classifying the engineering geological units in terms of land use capability and identifying the legal and the geologic restrictions that apply in the study area. Both informations are then superimposed over the land use and a conflict areas map is created. The analysis of these data leads to the identification of existing and forthcoming land use conflicts and enables the proposal of planning measures on a regional and local scale. The map for the regional planning was compiled at a 1:50,000 scale and encompasses the whole municipal land area where uses are mainly rural. The map for the local planning was compiled at a 1:10,000 scale and encompasses the urban area. Most of the classification and operations on maps used spatial analyst tools available in the Geographical Information System. The regional studies showed that the greater part of Analandia’s territory presents appropriate land uses. The local-scale studies indicate that the majority of the densely occupied urban areas are in suitable land. Although the situation is in general positive, municipal policies should address the identified and expected land use conflicts, so that it can be further improved.     

Morphosedimentary analysis of the Limoeiro Stream (center-northern Minas Gerais State,Brazil): clues to the eastward tilting of southern Espinhaco range sites

The morphosedimentary evolution of a sector of the southern Espinhaco range (northern Minas Gerais State, Brazil) and its regional neotectonic setting are presented herein. The studied site is a stream at base level flowing along the western border of the range. Its identification was accomplished by using remote sensing techniques including the analysis of 3D slope models generated with shuttle radar topography mission images. The main geomorphological features of the identified site were surveyed in a 1:500 scale. In addition, seven stratigraphic logs are described. A regional geologic compilation and facies diagrams were used as a basis for the integration of the geomorphological and stratigraphic data, which produced some conclusions about the recent tectonic reactivations at the eastern border of Sao Francisco Craton. The results point to a local eastward tilting of the Espinhaco range. This fact is in accordance with previous findings in neighboring areas and results in the asymmetric evolution of the fluvial valley, as well as the regional relief.     

A Truncated Pareto Model to Estimate the Under Recovery of Large Diamonds

The metallurgical recovery processes in diamond mining may, under certain circumstances, cause an under-recovery of large diamonds. In order to predict high quantiles or tail probabilities we use a Bayesian approach to fit a truncated Generalized Pareto Type distribution to the tail of the data consisting of the weights of individual diamonds. Based on the estimated tail probability, the expected number of diamonds larger than a specified weight can be estimated. The difference between the expected and observed frequencies of diamond weights above an upper threshold provides an estimate of the number of diamonds lost during the recovery process.     

A Dutch multi-date land use database: Identification of real and methodological changes

Land cover and land use are important information sources for environmental issues. One of the most important changes at the Earth's surface concerns land cover and land use. Knowledge about the location and type of these changes is essential for environmental modeling and management. Remote sensing data in combination with additional spatial data are recognized as an important source of information to detect these land cover and land use changes.     

Morphological similarities between DBM and a microeconomic model of sprawl

We present a model that simulates the growth of a metropolitan area on a 2D lattice. The model is dynamic and based on microeconomics. Households show preferences for nearby open spaces and neighbourhood density. They compete on the land market. They travel along a road network to access the CBD. A planner ensures the connectedness and maintenance of the road network. The spatial pattern of houses, green spaces and road network self-organises, emerging from agents individualistic decisions. We perform several simulations and vary residential preferences. Our results show morphologies and transition phases that are similar to Dieletric Breakdown Models (DBM). Such similarities were observed earlier by other authors, but we show here that it can be deducted from the functioning of the land market and thus explicitly connected to urban economic theory.     

Climatic consequences of gradual desertification in the semi-arid area of Northeast Brazil

The climatic impacts of gradual desertification in the semi-arid area of Northeast Brazil (SANEB) were evaluated using the MM5 regional model. Simulations for the rainy season of SANEB (March, April, and May) were performed. Desertification simulations were grouped into three numerical runs: total (all SANEB covered by desert), partial (desert areas placement based on future environmental degradation scenarios for SANEB), and random desertification (desert areas placed randomly within SANEB). Total desertification led to a pronounced and significant precipitation reduction in large parts of SANEB. Climatic impacts of partial desertification were guided by the southward expansion of desert areas. For intermediate desertification extensions, a dipole pattern with precipitation reduction (increase) in the northern (southern) areas of SANEB was found. Random desertification led to climatic impacts spread over the whole SANEB. In both partial and random desertification, a quasi-linear precipitation reduction was found as desertification extension increases.     

Rotational atmospheric circulation during North Atlantic-European winter: the influence of ENSO

The dominant variability modes of the North Atlantic-European rotational flow are examined by applying a principal component analysis (PCA/EOF) to the 200?hPa streamfunction mid-winter anomalies (Jan?CFeb monthly means). The results reveal that, when this norm is used, the leading mode (EOF1) does not correspond to the traditional North Atlantic Oscillation (NAO, which appears in our analysis as the second leading mode, EOF2) but is the local manifestation of the leading hemispheric streamfunction EOF. The regression of this regional mode onto the global SST field exhibits a clear El Ni?o signature, with no signal over the Atlantic, while the associated upper height anomalies resemble the Tropical/Northern Hemisphere (TNH) pattern. East of North America, this TNH-like wavetrain produces a meridional dipole-like pattern at lower levels. Although in some ways this pattern resembles the NAO (EOF2), the dynamics of these two modes are very different in that only EOF2 is associated with a latitudinal shift of the North Atlantic stormtrack. Thus, the choice of the streamfunction norm in the EOF analysis allows the separation of two different phenomena that can produce similar dipolar surface pressure anomalies over the North Atlantic but that have different impact on European climate. These two modes also differ on their contribution to variability at lower levels: while NAO-EOF2 is mostly confined to the North Atlantic, TNH-EOF1 has a more annular, global character. At upper levels NAO-EOF2 also produces a global pattern but with no annular structure, reminiscent of the ??circumglobal?? teleconnection.     

Temporal vulnerability in hazardscapes: Flood memory-networks and referentiality along the North Carolina Neuse River (USA)

Social models of population vulnerability to disasters increasingly include the notion that vulnerability has a strong temporal component. While this temporality is typically conceptualized as objective (making vulnerability “dynamic,” “multiscalar,” and/or “historical”), it consistently fails to acknowledge that among stakeholders managing hazardscapes temporality is also a social process in which subjective experience of time may play a role in creating situations of population vulnerability. This paper proposes that the temporal situatedness of a population relative to past hazard events and the quality with which stakeholders engage hazard memory-chains combine to significantly influences its vulnerability to natural hazards. It is proposed that this temporal vulnerability is characterized by shared, population level potential for surprise and can be evaluated by exploration of time-series depth and temporal reference points in historical ecological narratives and documents. Based on ethnohistoric research conducted from 2002 to 2006 in flood-prone eastern North Carolina (USA), it is illustrated how temporal vulnerability was relatively higher in the Neuse River watershed located at the City of Kinston than surrounding watersheds. Due to the combination of factors including the damming of the Neuse River in the 1980s, outdated official floodplain maps, relatively unmonitored floodplain development, the stochastic timing of flood events (placing the last major flood more than a generation away), technological optimism, and turnover of floodplain officials and residents, local stakeholders were seriously misinformed about the space-time risks involved both before and after the disaster of Hurricane Floyd (1999) happened. To deal with this inconsistency, the temporal rarity of Hurricane Floyd as a “500-year event” has been motivated and embraced by many in an effort to continue life-as-is. The paper proposes that the concept of temporal vulnerability is further explored and used as key dimension in the vulnerability sciences.     

Mediterranean migration futures: Patterns,drivers and scenarios

This study explores possible futures of Mediterranean migration based on an evaluation of past, current and future drivers of migration in the region. Since 1950, structural shifts in the political economy of the region have fundamentally changed the Mediterranean migration map. Particularly the rise of Gulf economies and south European growth and EU expansion has transformed the northern Mediterranean and the Gulf into new immigration poles. The main drivers of these changes are economic and political. Contrary to conventional beliefs, the role of environmental and also demographic factors seems comparatively limited, probabilistic and indirect. Future climate change and environmental stress may affect internal movement but are unlikely to result in massive international migration. Under most scenarios, Turkey and other North African countries may well evolve into immigration countries coinciding with increasing immigration from sub-Saharan Africa to the entire Mediterranean.