Jupiter: New retrieved thermal profiles and ammonia distributions

New thermal profiles of Jupiter are retrieved from recent far infrared spectral measurements and for H₂ mixing ratios varying from 0.8 to 0.94. The effective temperature corresponding to the inferred thermal profile is 123.15 ± 0.35°K. Far-infrared brightness temperature spectra computed from these profiles are compared to experimental data including measurements made at high spectral resolution in the NH₃ν₂ band at 10 μm and in NH₃ pure rotational bands between 40 and 110 μm. It is found that a strong depletion of NH₃ does occur in the Jovian stratosphere and that ammonia seems to be undersaturated in the upper troposphere.     

Cosmic ray ionization of the Jovian atmosphere

An approximate form of the Boltzmann equation has been used to obtain local ionization rates due to the absorption of galactic cosmic rays in the Jovian atmosphere. It is shown that the muon flux component of the cosmic ray-induced cascade may be especially importannt in ionizing the atmosphere at levels where the total number density exceeds 10¹⁹ cm^?3 (well below the ionospheric layers produced by solar euv). A model containing both positive and negative ion reactions has been employed to compute equilibrium electron and ion number densities. Peak electron number densities on the order of 10³ cm^?3 may be expected even at relatively low magnetic latitudes. The dominant positive ions are NH₄⁺ and C_nH_m⁺ cluster ions, with n ? 2; it is suggested that the absorption of galactic cosmic ray energy at such relatively high pressures in the Jovian atmosphere $\text{(M ? 10}{}^{18}\text{to}\text{10}{}^{20}\text{cm}{}^{\mathrm{?3}}\text{)}$ and the subsequent chemical reactions may be instrumental in the local formation of complex hydrocarbons.     

Laboratory simulation of infrared astrophysical features

Laboratory infrared emission and absorption spectra have been taken of terrestrial silicates, meteorites and lunar soils in the form of micrometer and sub-micrometer grains. The emission spectra were taken in a way that imitates telescopic observations. The purpose was to see which materials best simulate the 10 m astrophysical feature.The emission spectra of dunite, fayalite and Allende give a good fit to the 10 m broadband emission feature of comets Bennett and Kohoutek. A study of the effect of grain size on the presence of the 10 m emission feature of dunite shows that for particles larger than 37 m no feature is seen.The emission spectrum of the Murray meteorite, a Type 2 carbonaceous chondrite, is quite similar to the intermediate resolution spectrum of comet Kohoutek in the 10 m region. Hydrous silicates or amorphous magnesium silicates in combination with high-temperature condensates, such as olivine or anorthite, would yield spectra that match the intermediate resolution spectrum of comet Kohoutek in the 10 m region. Glassy olivine and glassy anorthite in approximately equal proportions would also give a spectrum that is a good fit to the cometary 10 m feature.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6 8 September, 1978.     

Modelling weathering processes at the catchment scale: The WITCH numerical model

A numerical model of chemical weathering in soil horizons and underlying bedrock (WITCH) has been coupled to a numerical model of water and carbon cycles in forest ecosystems (ASPECTS) to simulate the concentration of major species within the soil horizons and the stream of the Strengbach granitic watershed, located in the Vosges Mountains (France). For the first time, simulations of solute concentrations in soil layers and in the catchment river have been performed on a seasonal basis. The model is able to reproduce the concentrations of most major species within the soil horizons, as well as catching the first-order seasonal fluctuations of aqueous calcium, magnesium and silica concentrations. However, the WITCH model underestimates concentrations of Mg²⁺ and silica at the spring of the catchment stream, and significantly underestimates Ca²⁺ concentration. The deficit in calculated calcium can be compensated for by dissolution of trace apatite disseminated in the bedrock. However, the resulting increased Ca²⁺ release yields important smectite precipitation in the deepest model layer (in contact with the bedrock) and subsequent removal of large amount of silica and magnesium from solution. In contrast, the model accurately accounts for the concentrations of major species (Ca, Mg and silica) measured in the catchment stream when precipitation of clay minerals is not allowed. The model underestimation of Mg²⁺ and H₄SiO₄ concentrations when precipitation of well crystallized smectites is allowed strongly suggests that precipitation of well crystallized clay minerals is overestimated and that more soluble poorly crystallized and amorphous materials may be forming. In agreement with observations on other watersheds draining granitic rocks, this study indicates that highly soluble trace calcic phases control the aqueous calcium budget in the Strengbach watershed.     

Tripartite climate reversal in Central Europe 5600-5300 years ago

The history of variations in water level of Lake Constance, as reconstructed from sediment and pollen analysis of a sediment sequence from the archaeological site of Arbon-Bleiche 3, shows an abrupt rise in lake level dendrochronologically dated to 5375 yr ago (5320 yr relative to AD 1950). This event, paralleled by the destruction of the Neolithic village by fire, provoked the abandonment of this prehistoric lake-shore location established in the former shallow bay of Arbon-Bleiche, and was the last of a series of three episodes of successively higher lake level, the first occurring at 5600-5500 cal yr B.P. The dendrochronologically dated rise event was synchronous with an abrupt increase in atmospheric ¹⁴C. This supports the hypothesis of an abrupt climate change forced by varying solar activity. Moreover, the three successive episodes of higher lake level between 5600 and 5300 cal yr B.P. at Arbon-Bleiche 3 coincided with climatic cooling and/or changes in moisture conditions in various regions of both hemispheres. This period corresponds to the mid-Holocene climate transition (onset of the Neoglaciation) and suggests inter-hemispheric linkages for the climate variations recorded at Arbon-Bleiche 3. This mid-Holocene climate reversal may have resulted from complex interactions between changes in orbital forcing, ocean circulation and solar activity. Finally, despite different seasonal hydrological regimes, the similarities between lake-level records from Lake Constance and from Jurassian lakes over the mid-Holocene period point to time scale as a crucial factor in considering the possible impact of climate change on environments.     

Phytoliths as indicators of pedogenesis and paleoenvironmental changes in the Brazilian cerrado

This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed.     

Optimization of nonconventional wells under uncertainty using statistical proxies

The determination of the optimal type and placement of a nonconventional well in a heterogeneous reservoir represents a challenging optimization problem. This determination is significantly more complicated if uncertainty in the reservoir geology is included in the optimization. In this study, a genetic algorithm is applied to optimize the deployment of nonconventional wells. Geological uncertainty is accounted for by optimizing over multiple reservoir models (realizations) subject to a prescribed risk attitude. To reduce the excessive computational requirements of the base method, a new statistical proxy (which provides fast estimates of the objective function) based on cluster analysis is introduced into the optimization process. This proxy provides an estimate of the cumulative distribution function (CDF) of the scenario performance, which enables the quantification of proxy uncertainty. Knowledge of the proxy-based performance estimate in conjunction with the proxy CDF enables the systematic selection of the most appropriate scenarios for full simulation. Application of the overall method for the optimization of monobore and dual-lateral well placement demonstrates the performance of the hybrid optimization procedure. Specifically, it is shown that by simulating only 10% or 20% of the scenarios (as determined by application of the proxy), optimization results very close to those achieved by simulating all cases are obtained.     

Zircon geochronology and Sm–Nd isotopic study: Further constraints for the Archean and Paleoproterozoic geodynamical evolution of the southeastern Guiana Shield, north of Amazonian Craton, Brazil

The eastern part of the Guiana Shield, northern Amazonian Craton, in South America, represents a large orogenic belt developed during the Transamazonian orogenic cycle (2.26–1.95 Ga), which consists of extensive areas of Paleoproterozoic crust and two major Archean terranes: the Imataca Block, in Venezuela, and the here defined Amapá Block, in the north of Brazil.

Pb-evaporation on zircon and Sm–Nd on whole rock dating were provided on magmatic and metamorphic units from southwestern Amapá Block, in the Jari Domain, defining its long-lived evolution, marked by several stages of crustal accretion and crustal reworking. Magmatic activity occurred mainly at the Meso-Neoarchean transition (2.80–2.79 Ga) and during the Neoarchean (2.66–2.60 Ga). The main period of crust formation occurred during a protracted episode at the end of Paleoarchean and along the whole Mesoarchean (3.26–2.83 Ga). Conversely, crustal reworking processes have dominated in Neoarchean times. During the Transamazonian orogenic cycle, the main geodynamic processes were related to reworking of older Archean crust, with minor juvenile accretion at about 2.3 Ga, during an early orogenic phase. Transamazonian magmatism consisted of syn- to late-orogenic granitic pulses, which were dated at 2.22 Ga, 2.18 Ga and 2.05–2.03 Ga. Most of the ε_Nd values and T_DM model ages (2.52–2.45 Ga) indicate an origin of the Paleoproterozoic granites by mixing of juvenile Paleoproterozoic magmas with Archean components.

The Archean Amapá Block is limited in at southwest by the Carecuru Domain, a granitoid-greenstone terrane that had a geodynamic evolution mainly during the Paleoproterozoic, related to the Transamazonian orogenic cycle. In this latter domain, a widespread calc-alkaline magmatism occurred at 2.19–2.18 Ga and at 2.15–2.14 Ga, and granitic magmatism was dated at 2.10 Ga. Crustal accretion was recognized at about 2.28 Ga, in agreement with the predominantly Rhyacian crust-forming pattern of the eastern Guiana Shield. Nevertheless, T_DM model ages (2.50–2.38 Ga), preferentially interpreted as mixed ages, and ε_Nd < 0, point to some participation of Archean components in the source of the Paleoproterozoic rocks. In addition, the Carecuru Domain contains an oval-shaped Archean granulitic nucleus, named Paru Domain. In this domain, Neoarchean magmatism at about 2.60 Ga was produced by reworking of Mesoarchean crust, as registered in the Amapá Block. Crustal accretion events and calc-alkaline magmatism are recognized at 2.32 Ga and at 2.15 Ga, respectively, as well as charnockitic magmatism at 2.07 Ga.

The lithological association and the available isotopic data registered in the Carecuru Domain suggests a geodynamic evolution model based on the development of a magmatic arc system during the Transamazonian orogenic cycle, which was accreted to the southwestern border of the Archean Amapá Block.     

On the origin of rock fragment mulches on Vertisols: A case study from the Ethiopian highlands

Many Vertisols in Tigray, Ethiopia, typically carry a discontinuous rock fragment (RF, size 0.5–> 40 · 10^− 2 m) cover with 10 to 100 RFs m^− 2. Such RF mulches are of agricultural and environmental significance because they influence the water balance in the underlying soils and the crop yield. Natural RF concentrations are mostly considered as eolian or hydraulic lag deposits, or as the result of lateral transport over the soil surface from a rock outcrop, upslope. In cultivated areas RF mulches can develop by tillage.This paper presents the case of a natural RF mulch whose lithology indicates that the RFs are up-squeezed by the local Vertisol. The study site is located in the pass of Enda Maryam, Tigray, Northern Ethiopia (39°8′ E and 13°36′ N). A circular area of 10 m diameter, about 200 m away from the water divide in the valley has been cleared annually between 01/1999 and 05/2003. During this period, 625 RFs, 17 being > 7.5 · 10^− 2 m in size, totalling a mass of nearly 62 kg, have been collected. After correction for measurement procedures, the rate of RF up-warping by the Vertisol at Enda Maryam is assessed at 5 RFs m^− 2 in 3 years. At this rate of appearance, the formation of current RF concentrations on top of active valley Vertisols is only a matter of 10^1–2 years, provided the availability of RFs below the soil surface.Although important underground displacements were measured in the Vertisol between 01/1999 and 05/2002, the supposed link between up-squeezing of RFs and plastic deformations of ‘chimney’, ‘diapir’ or ‘intrusion’-like type in the Vertisol could not be evidenced. Instead, RFs are clearly concentrated on the soil surface as well as in depth, along the existing vertical desiccation cracks, often > 1 m deep which display polygonal configurations at the soil surface. Further, bundles of slickensides containing some RFs, have been mapped at the base of the Vertisol. The slickenside configuration suggests that the RF-bearing substrate is being scraped off.While the underground displacement of RFs along active slickensides seems normal, the process of RFs ascending in ‘upright’ position in the edge of desiccation cracks needs explanation. The closure of a desiccation crack is a peristaltic-like movement, following ascent or descent of the capillary fringe. It is hypothesized that this movement gradually pushes the RF to the surface or to another place or level in the soil profile where the crack closes in last instance.The apparent young age of the valley Vertisol mulches in Ethiopia might indicate the very recent formation of yearly recurrent desiccation cracks of Vertisols in the area. Available information confirms that most valleys in the study area used to be perennially marshy. Under these conditions no movements of RFs in the soil profile are expected to occur. Gullying, leading to pronounced seasonal desiccation of the Vertisols, started in several cases not more than 50 years ago.     

Review of the neotectonics of the Eastern Turkish–Armenian Plateau by geomorphic analysis of digital elevation model imagery

Digital elevation model (DEM) images provide synoptic views of the Earth’s surface allowing the analysis of landforms of still active tectonic and volcanic structures at regional scale. A DEM at 250 m pixel size constitutes regional scale data particularly efficient to investigate the late Miocene–Quaternary deformation of the Eastern Turkish–Armenian Plateau in the Arabian–Eurasian area of convergence. Geomorphic analysis of the DEM image associated with review of fault-plane solutions of earthquakes show that faults are mostly strike-slip with small vertical component. Here we show that the orientations of the tectonic and volcanic structures fit with a tectonic regime characterized by N–S shortening and E–W lengthening, consistent with westward escape of Anatolia perpendicular to the direction of the Arabia–Eurasia shortening. The uniform uplift of the plateau, the predominance of strike-slip faulting, the lack of major thrusts and the occurrence of normal faults do not support a model of going-on crustal thickening due to intracontinental convergence. On the contrary, our observations can be better interpreted in terms of lithospheric thinning and mantle upwelling related to gravity escape of Anatolia.