Authigenic zeolites and their relation to silica diagenesis in ODP Site 661 sediments (Leg 108, Eastern Equatorial Atlantic)

At ODP Site 661 from the continental margin of Northwest Africa, authigenic clinoptilolites were investigated in detail. Based on chemical data, crystal size and shape and their intergrowth with associated mineral phases, two types of clinoptilolite (type A and B) occur representing different diagenetic conditions under which the formation of zeolites took place. Clinoptilolite type A was found in a sediment section comprises numerous hiatuses and stratigraphically condensed sediments and could have been formed during early diagenesis. In contrast, clinoptilolite type B was precipitated in Campanian sediments during later diagenesis, after the transformation from opal-A to opal-CT had taken place. At Site 661, the silica source for the authigenesis of both clinoptilolite types is biogenic opal. Volcanic ash material occurs, but in low amounts and thus is not a prerequisite for the formation of clinoptilolite at Site 661.

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Zusammenfassung In der ODP-Bohrung 661 (Leg 108) vom Kontinentalrand vor Nordwest-Afrika wurden authigene Klinoptilolith-Kristalle mit Hilfe der Rasterelektronenmikroskopie, Röntgendiffraktometrie und Mikrosonde im Detail untersucht. Anhand der Kristallgrößen und -formen, ihren Verwachsungen mit anderen Mineralphasen und ihren chemischen Zusammensetzungen wurden 2 Klinoptilolithtypen (Typ A und B) unterschieden. Typ A wurde in stratigraphisch kondensierten Sedimenten nachgewiesen und könnte im Zuge von frühdiagenetischen Porenwasserreaktionen entstanden sein. Klinoptilolithtyp B, welcher vorwiegend in den campanen Sedimenten der ODP-Bohrung 661 vorkommt, wurde während der späteren Silikatdiagenese nach der Transformation von Opal-A in Opal-CT gebildet. Als Silikatquelle für die Kristallisation beider Klinoptilolithtypen wurden überwiegend biogene Opalskelette benutzt. Vulkanisches Aschenmaterial, welches ebenfalls ein Potential für die Klinoptilolithentstehung bildet, wurde nur in einem Horizont nachgewiesen und hatte keinen wesentlichen Einfluß auf die Klinoptilolithentstehung.

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Résumé Des cristaux de clinoptilolite authigène, provenant du site ODP 661 (marge continentale nord-ouest-africaine), ont fait l'objet d'une étude détaillée par microscopie électronique, diffractométrie X et microsonde. Les données chimiques, la taille et la forme des cristaux ainsi que leur intercroissance avec d'autres phases minérales permettent de distinguer 2 types (A et B) de clinoptinolite, qui correspondent aux conditions diagénétiques différentes dans lesquelles les zéolites se sont formées. La clinoptilolite de type A a été rencontrée dans une succession de sédiments stratigraphiquement condensés; elle pourrait s'être formée au début de la diagenèse. La clinoptilolite de type B, par contre, rencontrée surtout dans les sédiments campaniens a précipité au cours des stades tardifs de la diagenèse, après la transformation de l'opale A en opale CT. Au site 661, la source de silice nécessaire à la formation authigène des deux types de clinoptilolite est constituée par l'opale biogénique. Les cendres volcaniques qui pourraient éventuellement être à l'origine de la formation de clinoptilolite, n'ont été rencontrées que dans un seul horizon et n'ont joué aucun rôle en l'occurence.

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L'évaluation quantitative des anomalies géochimiques en sols résiduels: une aide pour le choix des prospects

Geochemical soil prospecting is carried out before the drilling stage and is therefore a factor in a decision involving quite considerable expense. Hence the need for accurate assessment of the value of anomalies. Two techniques are proposed here.Surface-content curves of anomalies very clearly reveal characteristics such as the sampling grid, background, top and distribution of values. To make decision-making easier, different curves can be drawn on the same diagram for comparison.A calculation of the amount of metal contained in the anomalous zone expressed in tonnes, as proposed by Solovov, is a very interesting idea. Four examples confirm that for a stable metal (Pb) under surface conditions, the figure obtained is of the same order of magnitude as that for the mineralisation at depth. In other words, geochemical sampling of residual soil could be used to calculate the tonnage per metre of depth, in this case at the level z = 0 in relation to the surface.

Résumé

La prospection géochimique en sol s'effectue avant le stade des forages, c'est donc un élément de décision pour des dépenses non négligeables. Une évaluation correct de l'intérêt des anomalies est donc nécessaire; deux techniques sont proposées.Le tracé de courbes teneurs-surfaces anomales permet une très bonne illustration de caractères tels que maille d'échantillonnage, background, top, répartition des teneurs. Les courbes reportées sur un même graphique peuvent être facilement comparées entre elles, ce qui rend plus aisées les décisions.Un calcul en tonnes du métal contenu dans l'anomalie, comme l'a proposé P.A. Solovov, est d'un grand intérêt. On vérifie sur quatre exemples que pour un métal stable dans les conditions superficielles (Pb), l'ordre de grandeur du chiffre obtenu est bien le même que celui de la minéralisation en profondeur. En d'autres termes, l'échantillonnage géochimique en sol résiduel permettrait le calcul du tonnage au mètre d'approfondissement, en l'occurrence au niveau z = 0 par rapport au sol.L'évaluation quantitative des anomalies géochimiques en sols résiduels, peut done constituer un outil important d'aide à la décision pour choisir les meilleurs prospects.     

Sea-level estimates during the last deglaciation based on δO and accelerator mass spectrometry C ages measured in Globigerina bulloides

Coupled measurements of δ¹⁸O and accelerator mass spectrometry (AMS) ¹⁴C in a particular species of planktonic foraminifera may be used to calculate sea-level estimates for the last deglaciation. Of critical importance for this type of study is a knowledge of the seasonality of foraminiferal growth, which can be provided by δ¹⁸O measurements of modern shells (core tops, plankton tows). Isotopic (δ¹⁸O, AMS-¹⁴C dating) and faunal records (transfer function sea surface temperature) were obtained from two cores in the North Atlantic at about 37°N. The locations were chosen to obtain high sedimentation rate records removed from the major ice-melt discharge areas of the last deglaciation. Based upon Globigerina bulloides data, four δ¹⁸O-based sea-level estimates were calculated: −67 ± 7 m at 12,200 yr B.P. and −24 ± 8 m at about 8200 yr B.P. for core SU 81-18; −83 ± 10 m at 12,200 yr B.P. and −13 ± 11 m at about 8500 yr B.P. for core SU 81-14. Using a second working hypothesis concerning the seasonability of G. bulloides growth, it is suggested that the sea-level rose by about 40 m during the millennium which followed 14,500 yr B.P.     

Effects of rock fragment size and cover on overland flow hydraulics,local turbulence and sediment yield on an erodible soil surface

The interactions between overland flow hydraulics and sediment yield were studied in flume experiments on erodible soil surfaces covered by rock fragments. The high erodibility of a non-cohesive fine sediment (D₅₀ + 0·09mm) permitted the effects of local turbulence and scour on sediment yield to be examined. Overland flow hydraulics and sediment yield were compared for experiments with pebble (D₅₀ + 1·5cm) and cobble (D₅₀ + 8·6cm) rock fragment covers. Cover percentages range from 0 to 99 per cent. Rock fragment size strongly affects the relations between flow hydraulics and rock fragment cover. For pebbles spatially-averaged hydraulic parameters (flow velocity, flow depth, effective flow width, unit discharge, total shear stress, Darcy-Weisbach friction factor, percentage grain friction and grain shear stress) vary most rapidly within cover percentages at low covers (power functions). In contrast, for cobbles these parameters vary most rapidly within cover percentages at high covers (exponential functions). As the type of the function that describes the relation between flow hydraulics and cover percentage can be deduced from the ratio of rock fragment height to flow depth, the continuity equation can be employed to determine the actual coefficients of the functions, provided the regression of one hydraulic parameter (e.g. flow velocity) with cover percentage is known and a good estimate exists for two values of another hydraulic variable for a low and a high cover percentage. The variation of sediment yield with cover percentage is also strongly dependent on rock fragment size, but neither the convex-upward relation for pebbles, nor the positive relation for cobbles can be solely attributed to the spatially averaged hydraulics of sheet-flow. Rock fragments induce local turbulence that leads to scour hole development on the stoss side of the rock fragments while deposition commonly occurs in the wake. This local scour and deposition substantially affects sediment yield. However, scour dimensions cannot be predicted by spatially averaged flow hydraulics. An adjustment of existing scour formulas that predict scour around bridge piers is suggested. Sediment yield from non-cohesive soils might then be estimated by a combination of sediment transport and scour formulas.     

Uniform-hazard response spectra—An alternative approach

An alternative method is presented for generating uniform-hazard response spectra making use of a seismic hazard curve expressing annual probability of exceedance as a function of Peak Ground Acceleration (PGA), a set of normalized (PGA = 1g) mean response spectra, and a coefficient-of-variation function for the random normalized spectral values in terms of period T. The practice of using mean + 1σ normalized response spectra, scaled to specified PGA levels, is discussed and associated mean return periods are evaluated.     

Physical processes controlling bacterial distribution and variability in the upper St. Lawrence estuary

The vertical structure of the water column and the spatial distribution and semidiurnal variability of bacteria were investigated at six stations in the upper St. Lawrence estuary. The σ₁ profiles indicate that the upper St. Lawrence is a partially mixed estuary. Stratification results from buoyancy input from the freshwater outflow of the St. Lawrence River, and its variability is controlled by tidal and, to a lesser extent, wind mixing. Calculations show that tidal mixing largely exceeds mixing caused by wind. Free and attached bacteria presented different patterns of spatial distribution and temporal variability. Free bacteria exhibited highest mean concentrations at the freshwater station (3.5–4.4 10⁶ml^?1) and lowest concentrations at the downstream stations (0.3–0.5 10⁶ml^?1); their numbers declined exponentially relative to salinity. Attached bacteria had highest mean concentrations (3.2–5.5 10⁶ml^?1) at salinities between 0.5 and 5 and were virtually absent at downseam stations (<0.05 10⁶ml^?1). The importance of semidiurnal variability was demonstrated Over the idal cycle, variability of attached bacteria was always greater than that of free bacteria. The analysis of causal models between salinity and free and attached bacteria, showed that the two types of bacteria are uncoupled and that both types have a strong relationship with salimity. Physical processes are thus important controlling factors of the distribution and variability of bacteria. Results suggest that large-scale processes, such as freshwater outflow and residual circulation, largely control free bacteria, whereas short-term and more local processes (e.g., sediment resuspension caused by wind) may also be important in the control of attached bacteria.     

The Japan Trench and its juncture with the Kuril Trench: cruise results of the Kaiko project, Leg 3

This paper presents the results of a detailed survey combining Seabeam mapping, gravity and geomagnetic measurements as well as single-channel seismic reflection observations in the Japan Trench and the juncture with the Kuril Trench during the French-Japanese Kaiko project (northern sector of the Leg 3) on the R/V “Jean Charcot”. The main data acquired during the cruise, such as the Seabeam maps, magnetic anomalies pattern, and preliminary interpretations are discussed. These new data cover an area of 18,000 km² and provide for the first time a detailed three-dimensional image of the Japan Trench. Combined with the previous results, the data indicate new structural interpretations. A comparative study of Seabeam morphology, single-channel and reprocessed multichannel records lead to the conclusion that along the northern Japan Trench there is little evidence of accretion but, instead, a tectonic erosion of the overriding plate. The tectonic pattern on the oceanic side of the trench is controlled by the creation of new normal faults parallel to the Japan Trench axis, which is a direct consequence of the downward flexure of the Pacific plate. In addition to these new faults, ancient normal faults trending parallel to the N65° oceanic magnetic anomalies and oblique to the Japan trench axis are reactivated, so that two directions of normal faulting are observed seaward of the Japan Trench. Only one direction of faulting is observed seaward of the Kuril Trench because of the parallelism between the trench axis and the magnetic anomalies. The convergent front of the Kuril Trench is offset left-laterally by 20 km relative to those of the Japan Trench. This transform fault and the lower slope of the southernmost Kuril Trench are represented by very steep scarps more than 2 km high. Slightly south of the juncture, the Erimo Seamount riding on the Pacific plate, is now entering the subduction zone. It has been preceded by at least another seamount as revealed by magnetic anomalies across the landward slope of the trench. Deeper future studies will be necessary to discriminate between the two following hypothesis about the origin of the curvature between both trenches: Is it due to the collision of an already subducted chain of seamounts? or does it correspond to one of the failure lines of the America/Eurasia plate boundary?     

Chemical record of the projectile in the graded fall-back sedimentary unit from the Ries Crater, Germany

The so-called “Graded Unit” comprises 17.2 m of the core from the research borehole Nördlingen 1973 and is thought to represent fall-back material, which has been sorted similar to tephra. Samples from six levels of these air-borne impact debris sediments in the Ries Crater have been analyzed for Ir, Ni, Co, Cr and Fe. The concentrations of these elements are negatively correlated with average grain size and accordingly the depth of the samples indicating the presence of a surface correlated component and are hence consistent with vapour deposition of meteoritic material on small dust grains. The largest Ir concentration found is 230 pg/g, a factor of 28 higher than the indigenous concentration. Enrichment factors in the uppermost layer of the “Graded Unit” are about 28 for Ir, approximately 2 for Fe, Co, Ni and 1.5 for Cr. If the enrichment of all elements determined were of meteoritic origin, then the “net meteoritic composition” is most closely matched by aubrites as suggested previously. However, it seems more likely that the observed concentration trends of Cr, Fe, Co and Ni are due to mineral sorting. Therefore the only as yet certain indication of meteoritic material is the presence of Ir, which is not sufficient to further constrain the nature of the projectile.     

Deccan flood basalts at the Cretaceous/Tertiary boundary?

Joint consideration of new paleomagnetic, paleontological and geochronological data from the Deccan continental flood basalts in India and critical discussion of earlier results lead us to suggest that volcanic activity may have lasted less than 1 Ma, thus possibly ranking as one of the largest volcanic catastrophes in the last 200 Ma. Available data are best satisfied if volcanism spanned the Cretaceous/Tertiary boundary, followed shortly afterwards by rifting of the Arabian Sea. These results point out the need for further work which may help in choosing between “external” and “internal” models of the Cretaceous/Tertiary boundary events.