Oxygen and carbon isotope ratios in the martian atmosphere

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.     

Early Estimation of Seismic Hazard for Strong Earthquakes in Taiwan

A shakemap system providing rapid estimates of strong ground shaking could be useful for emergency response providers in a damaging earthquake. A hybrid procedure, which combines site-dependent ground motion prediction models and the limited observations of the Real-Time Digital stream output system (RTD system operated by Central Weather Bureau, CWB), was set up to provide a high-resolution shakemap in a near-real-time manner after damaging earthquakes in Taiwan. One of the main factors that affect the result of ground motion prediction analysis is the existence of site effects. The purpose of this paper is to investigate the local site effects and their influence in the ground shaking and then establish an early estimation procedure of potential hazard for damaging earthquakes. Based on the attenuation law, the site effects of each TSMIP station are discussed in terms of a bias function that is site and intensity-level dependent function. The standard deviation of the site-dependent ground motion prediction model can be significantly reduced. The nonlinear behavior of ground soil is automatically taken into account in the intensity-level dependent bias function. Both the PGA and the spectral acceleration are studied in this study. Based on the RTD data, event correctors are calculated and applied to precisely estimate the shakemap of damaging earthquakes for emergency response.     

Large-scale Mechanical Redistribution of Orthopyroxene and Plagioclase in the Basement Sill, Ferrar Dolerites, McMurdo Dry Valleys, Antarctica: Petrological, Mineral-chemical and Field Evidence for Channelized Movement of Crystals and Melt

The Jurassic Ferrar dolerite sills of the McMurdo Dry Valleys,Antarctica represent the plumbing system for flood basalt eruptionsassociated with the breakup of Gondwana. Among the Ferrar sills,the 350–450 m thick cumulate-textured Basement Sill isdifferentiated into a Lower Marginal Zone (LMZ) gabbronorite,a thick Lower Zone (LZ) orthopyroxene–plagioclase orthocumulatepyroxenite, a strongly layered mela- to leuco-gabbronorite MiddleZone (MZ), a thick Upper Zone (UZ) gabbronorite with ferrogabbroicpods, and an Upper Marginal Zone (UMZ) gabbronorite. Texturesand mineral compositions in the LZ pyroxenite and MZ–UZgabbronorites are nearly identical, the main distinction beingthe greater relative proportion of plagioclase in the MZ–UZgabbronorites, and of pigeonite in the UZ. Most orthopyroxenein the LZ, MZ and UZ occurs as sub-euhedral, normally zonedprimocrysts, commonly with rounded plagioclase inclusions. Plagioclaseis usually sub-euhedral and normally zoned, but can containsodic cores interpreted to be xenocrystic. Orthopyroxene andfeldspar compositions thoughout the sill are generally fairlyuniform, and resemble the compositions of micro-phenocrystsin the chilled margins. We infer that the sill was filled bya c. 1250°C slurry of orthopyroxene + plagioclase phenocrystsor primocrysts that subsequently unmixed in response to buoyancyforces. The LZ websterite contains numerous anorthosite to gabbronoriteschlieren, veins and pipes (< 2 m diameter), which we interpretas fossil segregation channels. Textures and mineral compositionsin these felsic channels are very similar both to UZ and MZgabbronorites, and to the groundmass separating accumulatedorthopyroxene primocrysts in the LZ and MZ. We infer that plagioclase-charged,hydrous pore melt from the pyroxenite may have segregated, pooledand ascended through these conduits to feed growth of the UZgabbronorite. Detailed mapping shows that the pipes are separatedby about 15 m on average. Calculations suggest that this numberdensity of conduits could have drained the LZ cumulates of theirinterstitial melt + plagioclase in about 8 days. Sequences (eachc. 5–10 m thick) of layered leuco-gabbronorite in theMZ could represent intra-cumulate sills that formed from plagioclase-richslurries ascending in segregation channels. Fe–Ti-richpyroxenitic veins and pods (some pegmatitic) and an unusualcoarse-grained plagioclase facies occur at the contacts betweenmassive leuco-gabbronorite layers in the MZ. Discordant ferro-pegmatitepods and dykes occur throughout the UZ. We interpret these Fe-richpegmatoidal rocks as evolved residual melts expelled from thecompacting gabbronoritic cumulates of the MZ and UZ. KEY WORDS: Ferrar; cumulates; differentiation; Antarctica; layering     

Description de deux nouvelles Cyclotelles (Bacillariophyceae) de milieux alcalins et eutrophes:Cyclotella costei nov. sp. etCyclotella wuethrichiana nov. sp.

Two new species of the genus Cyclotella are presented which have been discovered during ecological and paleoecological research studies in the littoral zone of two small alkaline eutrophic lakes in France (Lake Paladru) and in Switzerland (Lake Le Loclat). These new species are namedCyclotella costei nov. sp. andCyclotella wuethrichiana nov. sp.     

Surface sealing as influenced by slope angle and position of simulated stones in the top layer of loose sediments

The influence of five different slope angles and two different positions of simulated stones in the top layer of a sandy and a silty sediment on surface sealing intensity is examined in the laboratory. Sealing intensity is assessed by studying changes of percolation rate through a sediment layer with simulated rainfall duration and by measuring cohesion of the 5 mm thick upper sediment layer, a measure of seal strength, by means of a torvane. Slope has a negative influence on sealing intensity. For a constant per cent of simulated stone cover, sealing intensity is lowest in the case of stones placed on the sediment surface compared to the case of stones pushed into the surface layer. Explanations for these findings are given and some implications are further discussed.     

Etude des Déformations et Inclinaisons du Sous-sol: Développements Instrumentaux et Applications dans la Région Sismique d’Arette,France

We present a modified version of a tilt and strain meter conceived to have great sensibility and good stability. These instruments were deployed in a cave at the seismic Pyrenean region of Arette (France). We set in evidence several types of phenomena, of which deformations brought about by water recharge filling up fissures on the massif are of importance. Owing to the redundance in the data, the study of the co-seismic deformations allows one to separate instrumental displacements and local readjustments from regional motions.     

The Néel transition and magnetic properties of terrestrial,synthetic, and lunar ilmenites

The magnetic susceptibility of a terrestrial, synthetic and lunar ilmenite specimen has been measured from 4 to 300 K. All specimens had a single Néel temperature transition which ranged from 56 to 57.7 K. In one case the powdered specimen was partially aligned in the magnetic field prior to the susceptibility measurements and the Néel transition was observed to shift to 60 K indicating magnetic anisotropy. A study of several magnetic parameters calculated from the experimental data showed gross impurities in the terrestrial specimen, single-domain to multi-domain metallic iron in the synthetic specimen, and a small amount of superparamagnetic metallic iron in the lunar sample. No multidomain iron was observed in the lunar ilmenite. The results of electron spin resonance measurements were also in general agreement with these findings. Because of the absence of Fe³⁺ compared to most terrestrial samples it is suggested that the anisotropic magnetic parameters be determined on lunar ilmenite when a large enough single crystal becomes available.     

87Rb-86Sr age of rocks from the Apollo 15 landing site and significance of internal isochrons

Internal isochrons for two Apollo 15 rocks give an age of(3.34 ± 0.09)and(3.46 ± 0.04) × 10⁹ years with an identical⁸⁷Sr/⁸⁶Sr initial ratio of 0.69928. Considering the possibility for the line obtained in a⁸⁷Sr/⁸⁶Sr,⁸⁷Rb/⁸⁶Sr diagram to be a mixing line, the significance of these results are discussed.     

Présentation d'un capteur classeur de particules à lame unique et d'un capteur absolu permettant de l'étalonner

Résumé Dans le capteur monolame à un seul jet proposé ici, l'air est projeté obliquement sur la lame de verre en amont du jet; ce capteur permet ainsi d'obtenir un prélèvement de particules classées suivant leurs dimensions sur une grande surface d'une seule lame. Par ailleurs ce capteur, en plexiglas, permet de surveiller la lame en cours de prélèvement. Les coefficients de captation pour des gouttelettes de différentes dimensions ont été déterminés en comparant les prélèvements obtenus avec le capteur monolame à ceux obtenus avec un capteur à deux jets identiques en série, réalisé afin de permettre un comptage de toutes les gouttelettes déposées sur les parois intérieures. On a de la même façon déterminé les coefficients de captation d'un cascade impactor. Les coefficients du capteur monolame et du cascade impactor sont trouvés assez peu différents, et leurs valeurs restent comprises entre 40 et 86% pour des gouttelettes de 1 à 30 de rayon. Enfin un paragraphe de cette communication indique comment peut être utilisé le capteur monolame lors de prélèvements dans un nuage.

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Summary In the monoslide and monojet impactor here proposed, the air is obliquely projected on the slide, up the jet; thus this impactor gives samples of particles classified according to their sizes on a large surface of only one slide. On another way, this impactor, made of plexiglas, allows the supervision of the slide during the sampling. The different size droplets sampling coefficients have been determined by comparison of samples obtained with an impactor having two identical jets in series, this impactor being realized in order to permit a counting of all the droplets settled in the interior walls. On the same way the sampling coefficients of a cascade impactor have been determined. The monoslide impactor coefficients and these of the cascade impactor have been found nearly identical and their values remain included between 40 and 86% for 1 to 30 radius droplets. Lastly a paragraph of this paper shows how the monoslide impactor can be used when sampling in a cloud.