A thermo-plastic constitutive law for brittle-plastic behavior of rocks at high temperatures

Mechanical properties of rocks change under the influence of, temperature. Stress at the onset of yielding, ultimate strength, dilatancy, strain hardening and softening, and the confining pressure at brittle-ductile transition are all reduced by the increasing temperature. This study presents a framework of constitutive modeling of thermo-brittle-plastic behavior of rocks which encompasses these changes. The constitutive law is based on a thermo-plasticity theory first proposed for metals byPrager (1958). Two phenomenological mechanisms have been identified as central for the modeling: temperature dependence of the yield locus (thermal softening), and temperature dependence of the strain-hardening function (thermally enhanced ductility). Material parameters for two rocks, Carrara marble and Westerly granite, were determined on the basis of additional hypotheses. These parameters are used in numerical simulations of triaxial tests at different temperatures. The obtained stress-strain curves compare well to the experimental results. The changes with temperature in the stress at the onset of yielding are more accurately reproduced that the evolution of hardening or softening. Suggestions for possible improvements and future research directions are indicated.     

Uptake of macroelements by the helophytePhalaris arundinacea L.

Helophytes are often incorporated into biological wastewater treatment plants. In favourable situations, they can take up large amounts of nutrients. One helophyte, the reed canarygrass (Phalaris arundinacea L.), is fast growing when supplied with sufficient light and nutrients. Experiments were carried out under natural climatic conditions in small plastic tanks filled with sand with regular additions of a balanced and concentrated nutrient solution. In the growing season (May–October), plant production reached 10.5 kg m^–2 of dry biomass, of which 66% was in the aerial parts. Maximum nutrient uptake capacity was reached just after flowering and before senescence (beginning of October): 49% N, 34% P, 52% K and 34% Mg of the input was fixed in the aerial parts, which are easily harvestable. The corresponding values for the below ground parts were 12%, 10%, 11% and 11% respectively. Excretion of K and Mg has been observed when nutrients are translocated to the storage organs.     

Post glacial lacustrine event sedimentation in an ancient mountain setting: Carboniferous Lake Malanzán (Western Argentina)

Lacustrine deposits of the Malanzán Formation record sedimentation in a small and narrow mountain paleovalley. Lake Malanzán was one of several water bodies formed in the Paganzo Basin during the Late Carboniferous deglaciation. Five sedimentary facies have been recognized. Facies A (Dropstones-bearing laminated mudstones) records deposition from suspension fall-out and probably underflow currents coupled with ice-rafting processes in a basin lake setting. Facies B (Ripple cross-laminated sandstones and siltstones) was deposited from low density turbidity currents in a lobe fringe environment. Facies C (Massive or graded sandstones) is thought to represent sedimentation from high and low density turbidity currents in sand lobes. Facies D (Folded sandstones and siltstones) was formed from slumping in proximal lobe environments. Facies E (Wave-rippled sandstones) records wave reworking of sands supplied by turbidity currents above wave base level.The Lake Malanzán succession is formed by stacked turbidite sand lobe deposits. These lobes were probably formed in proximal lacustrine settings, most likely relatively high gradient slopes. Paleocurrents indicate a dominant direction from cratonic areas to the WSW. Although the overall sequence shows a regressive trend from basin fine-grained deposits to deltaic and braided fluvial facies, individual lobe packages lack of definite vertical trends in bed thickness and grain size. This fact suggests aggradation from multiple-point sources, rather than progradation from single-point sources. Sedimentologic and paleoecologic evidence indicate high depositional rate and sediment supply. Deposition within the lake was largely dominated by event sedimentation. Low diversity trace fossil assemblages of opportunistic invertebrates indicate recolonization of event beds under stressed conditions.Three stages of lake evolutionary history have been distinguished. The vertical replacement of braided fluvial deposits by basinal facies indicates high subsidence and a lacustrine transgressive episode. This flooding event was probably linked to a notable base level rise during postglacial times. The second evolutionary stage was typified by the formation of sand turbidite lobes from downslope mass-movements. Lake history culminates with the progradation of deltaic and braided fluvial systems     

Emission of nitric oxide from soils and termite nests in a Trachypogon savanna of the Orinoco basin

Nitric oxide fluxes from soils in the Trachypogon savanna of the Orinoco basin were determined during the dry season using the static chamber method. The emission from dry soils fluctuated from 0.4 to 3 ng N m^–2 s^–1 and increased up to 25 ng N m^–2 s^–1 after moderate watering or light rain-falls (1 to 5 mm). The mean emission values are up to 6 times lower than one observed earlier at the Chaguaramas site, but up to 10 times higher than one recorded at the Guri site, indicating an important spatial variability in NO fluxes of the Venezuelan savanna region. The changes observed after the addition of nitrogen to the soil, in the form of ammonium and/or nitrate, indicate a high denitrification potential in this acidic soil. Burning of the surface vegetation produced an increase by a factor of 10 in the emission rate of NO, but the effect was relatively short in time, about 5 days. It was estimated for the savanna region that burning increases the total NO soil emission during the dry season by 15% compared to the unburnt case. Soils with termite nests emit 10 times more NO than soil without nests, but the contribution from this source is less than 2% of the total savanna soil flux.     

Taphonomy of guanaco bones in Tierra del Fuego

Guanaco carcasses are deposited in great quantities in Cabo San Pablo, Tierra del Fuego (Argentina), as a result of winter stress. Taphonomic studies indicate that the gnawing action of foxes on guanaco (Lama guanicoe) carcasses produces only very tenuous marks on the bones. Lack of sustained interest in the carcasses by carnivores results in slow disarticulation. The articulated and disarticulated bones are exposed to heavy trampling by guanacos, a process that produces vertical migration of small/dense bones and fracturing of the most weathered bones. An understanding of this ongoing process is important for local archaeology, since modern bones are migrating into archaeological contexts. A regional approach to taphonomy is the most appropriate instrument to solve this and other related problems.     

Depositional mechanics of turbulent nuées ardentes (surges) from their grain sizes

The ability of turbulent nuées ardentes (surges) to transport coarse pyroclasts has been questioned on the basis that settling velocities of coarse fragments in the deposits are much too high for them to have been supported by turbulence in a dilute gas suspension. A computer model is used to evaluate the settling velocity of pyroclasts in suspensions of varying concentration and temperature. Since suspension of grains in low-concentration surges occurs if the shear velocity exceeds the settling velocity, the shear velocities related to the 16th and 84th percentiles, and the mean of the grain-size distribution are compared in surge deposits of the Vulsini, with the shear velocity necessary to move the coarsest grain on the bed surface (the Shields criterion). The results show that the settling velocities do not vary significantly in gaseous suspensions having volume concentrations lower than 15%, and that an increase in concentration to 25% is not sufficient to decrease the settling velocity of the coarser fraction, if it represents flow shear velocity. It is shown that the settling velocity of the mean grain size (M _z ) best depicts the shear velocity of a dilute turbulent suspension. Applying the results to the May 1902 paroxysmal nuées ardentes of Mount Pelée shows that the estimated mean velocities are well within the observed velocities, and sufficient to support all the clasts in dilute, turbulent suspensions.     

Carboxylic monoacids in the air of mayombe forest (Congo): Role of the forest as a source or sink

In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P _gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P _gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P _gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH₃COOH), propionic (CH₃CH₂COOH), and isobutyric (CH₃CH(CH₃)COOH) acids.By comparison of P _gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C₃ or C₄ atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×10⁹, 7.8×10⁹, and 8.4×10⁹ molecules cm^-2 s^-1 for HCOOH, CH₃COOH, and CH₃CH₂COOH, respectively. The savanna is an exogenous source of HCOOH and CH₃CH₂COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH.     

The African rain forest vegetation and palaeoenvironments during late quaternary

This review paper presents first the main pollen results on the vegetation history of the rain forest during the late Quaternary.- The Lake Bosumtwi record (Ghana) shows the disappearance of rain forest from the base of the core (ca. 28 000 yr BP) to ca. 9000 yr BP. During this time interval the vegetation was of montane type with sparse clumps of trees. There is synchronism between montane vegetation disappearance and rain forest reappearance. This phenomenon occurred abruptly around 9000 yr BP.- The Lake Barombi Mbo record (West Cameroon) shows clearly that from ca. 24 000 yr BP until the present time, rain forest persisted with limited variations, and thus, this area represents a refuge area.From these data and other, one concludes that Afromontane vegetation extended to lowland during cool and humid phases.Other palaeoenvironmental data were obtained by diverse geological analyses of the lacustrine sediments. For Bosumtwi, the relatively precise reconstruction of lake-level fluctuations permitted several palaeoclimatic interpretations for the main Holocene phases.For Barombi Mbo, the evolution of total organic carbon (TOC) and total nitrogen (TON) seems to be related mainly to temperature evolution. By comparison with present-day mountain environments, TOC and TON increase in cool environments, but decrease when warmth and humidity increase, as during Holocene time, because the recycling processes speed up in the topsoil. For the same period the alteration of the soils in the catchment produced a strong increase of kaolinite. All these change intervened ca. 9500 yr BP, which is a key date in tropical Africa.In conclusion, climatic correlations between equatorial and dry north tropical Africa illustrate how changes in the forest block must have important effects on adjacent climatic zones.