Screening of polymers on selected Hawaii soils for erosion reduction and particle settling

In recent years, high‐molecular‐weight anionic polyacrylamides (PAMs) have been tested on a variety of soils, primarily in temperate climates. However, little information is available regarding the effectiveness of PAM for preventing soil loss through runoff in tropical settings. Screening tests were performed using three negatively charged PAMs and one positively charged PAM on five Hawaii soils (two Oxisols, one Vertisol, and two Aridisols) to determine erosion loss, sediment settling, and aggregate stability. A laboratory‐scale rainfall simulator was used to apply erosive rainfall at intensities from 5 to 8·5 cm h^?1 at various PAM doses applied in both dry and solution forms. Soil detachment due to splash and runoff, as well as the runoff and percolate water volumes, were measured for initial and successive storms. The impact of PAM on particle settling and aggregate stability was also evaluated for selected soil‐treatment combinations. Among the PAMs, Superfloc A‐836 was most effective, and significantly reduced runoff and splash sediment loss for the Wahiawa Oxisol and Pakini Andisol at rates varying between 10 and 50 kg ha^?1. Reduced runoff and splash sediment loss were also noted for PAM Aerotil‐D when applied in solution form to the Wahiawa Oxisol. Significant reductions in soil loss were not noted for either the Lualualei Vertisol or the Holomua Oxisol. It is believed that the high montmorillonite content of the Lualualei Vertisol and the low cation‐exchange capacity of the Holomua Oxisol diminished the effectiveness of the various PAMs tested. The polymers were also found to enhance sediment settling of all soils and helped improve their aggregate stability. This screening study shows the potential use of PAM for tropical soils for applications such as infiltration enhancement, runoff reduction, and enhanced sedimentation of detention ponds. Copyright © 2005 John Wiley & Sons, Ltd.     

Chemical abundances determined from meteor spectra: I. Ratios of the main chemical elements

Abstract— Relative chemical abundances of 13 meteoroids were determined by averaging the composition of the radiating gas along the fireball path that originated during their penetration into the Earth's atmosphere. Mg, Fe, Ni, Cr, Mn, and Co abundances, relative to Si, are similar to those reported for CI and CM carbonaceous chondrites and interplanetary dust particles. In contrast, relative abundances of Ca and Ti in meteor spectra indicate that these elements suffer incomplete evaporation processes. The chemical composition of all meteoroids studied in this work differs from that of 1P/Halley dust.     

Analytical solutions of one‐dimensional infiltration before and after ponding

This paper is a continuation of previous research, which obtained a convenient solution for arbitrary surface fluxes before ponding. By means of Fourier Transformation this has been extended to derive analytical solutions of a linearized Richards' equation for arbitrary input fluxes after surface saturation. Copyright © 2003 John Wiley & Sons, Ltd.     

Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

Commentary

This discussion on a report by Mascle and Mascle provides some information on the structure of the Apenninic orogenic belt. A number of structural scenarios can be recognized in the Apenninic fold belt; chaotic, melange-like, thrusted sheets are or are not associated with deeper compressional structures affecting coherent stratigraphic sequences at least as old as Trias. Variations and combinations of these structural frames cannot be simply summarized by a scheme, but can be used as basic category in a comparison of ocean ic-subduction complexes.     

Validation of Jason and Envisat Altimeter Dual Frequency Rain Flags

New rain flags based on the dual frequency capabilities of the new Jason Poseidon-2 and Envisat RA2 altimeters have been tested, developed and adopted for the operational processing of the altimeter data. Their validation conducted during the calibration/validation phases of the satellites is presented here. The Jason flag is validated by comparison with the TOPEX one, using the Tandem mission. The results show a very good agreement between the two sensors and the two rain flags The Envisat flag is validated by comparison with both Jason and TOPEX using global and collocated data sets. The results show similar performances for the three sensors. The f relations estimated during the calibration-validation period and presented here have been given to the altimeter ground processing facilities for operational use.     

Food Deserts in the Prairies? Supermarket Accessibility and Neighborhood Need in Edmonton,Canada*

The U.S. and U.K. literatures have discussed “food deserts,” reflecting populated, typically urban, low‐income areas with limited access to full‐service supermarkets. Less is known about supermarket accessibility within Canadian cities. This article uses the minimum distance and coverage methods to determine supermarket accessibility within the city of Edmonton, Canada, with a focus on high‐need and inner‐city neighborhoods. The results show that for 1999 both of these areas generally had higher accessibility than the remainder of the city, but six high‐need neighborhoods had poor supermarket accessibility. We conclude by examining potential reasons for differences in supermarket accessibility between Canadian, U.S., and U.K. cities.     

Where the buffalo roam: Boundaries and the politics of scale in the yellowstone region

For more than twenty years, the state of Montana has pursued a controversial policy of lethal control to manage winter migrations of bison from Yellowstone National Park. In the late 1990s, as the state and a number of federal agencies attempted to cooperatively outline a more palatable scenario for bison management, local environmental groups became active participants in the debate. This paper examines the strategies pursued by these organizations in the course of their attempt to construct a new, ecosystem-level territorial space and jurisdictional scale for bison, and places their struggle within the context of existing work in geography on the politics of scale. Ultimately, the failure of their efforts illustrates some of the important constraints faced by social groups that attempt to create new territorial regimes and new scales of resistance in the interstices of existing political structures.     

Flood Damage Reduction Program (FDRP) in Québec: Case Study of the Chaudiére River

This study presents the evolution of agreements between the governments of Canadaand Québec on flood damage reduction. In Québec, the implementation of a regulation about building in floodplains came about in 1983–1984. Today, this regulation takes the form of a policy called ``Policy of shores, littoral and floodplain protection'. Municipalities must adopt rules that concur with the principles of this policy.The Chaudiére River basin was selected for analysis of urban developmentduring the period following the application of building rules in flood-risk areas.Despite the ban on building in the strong current zone (0–20 year return periodflood zone), many buildings, essentially residential, have been erected in thiszone. These new constructions generally account for a low percentage of thetotal property value in the 0–100 year flooding area, but are legal since theyare connected to a water and sewage network that existed prior to the officialfloodplain regulation.Flood damage along the Chaudiére River will tend to increase for two reasons.Firstly, while respecting the policy mentioned above, sites are still available infloodplains for future development. Secondly, no structural flood protection workshave been erected in view of the fact they are only marginally profitable from anbenefit-cost point of view.