Identification of Multiple Sources of Groundwater Contamination by Dual Isotopes

Chlorinated solvents are one of the most commonly detected groundwater contaminants in industrial areas. Identification of polluters and allocation of contaminant sources are important concerns in the evaluation of complex subsurface contamination with multiple sources. In recent years, compound‐specific isotope analyses (CSIA) have been employed to discriminate among different contaminant sources and to better understand the fate of contaminants in field‐site studies. In this study, the usefulness of dual isotopes (carbon and chlorine) was shown in assessments of groundwater contamination at an industrial complex in Wonju, Korea, where groundwater contamination with chlorinated solvents such as trichloroethene (TCE) and carbon tetrachloride (CT) was observed. In November 2009, the detected TCE concentrations at the study site ranged between nondetected and 10,066 µg/L, and the CT concentrations ranged between nondetected and 985 µg/L. In the upgradient area, TCE and CT metabolites were detected, whereas only TCE metabolites were detected in the downgradient area. The study revealed the presence of separate small but concentrated TCE pockets in the downgradient area, suggesting the possibility of multiple contaminant sources that created multiple comingling plumes. Furthermore, the variation of the isotopic (δ¹³C and δ³⁷Cl) TCE values between the upgradient and downgradient areas lends support to the idea of multiple contamination sources even in the presence of detectable biodegradation. This case study found it useful to apply a spatial distribution of contaminants coupled with their dual isotopic values for evaluation of the contaminated sites and identification of the presence of multiple sources in the study area.     

Nonlinear response estimates of RC frames using linear analysis of SDOF systems

An approximate‐simple method for nonlinear response estimates of reinforced concrete frames subjected to near‐field and far‐field records is presented in this paper. The approximate method is based on equivalent single‐degree‐of‐freedom and linear multi‐degree‐of‐freedom models. In this procedure, the nonlinear maximum roof displacement is estimated using an effective period factor and elastic response spectrum with an equivalent damping. The effective period factor was proposed for far‐field and near‐field ground motion records. For regions of high seismicity, the maximum roof displacement can be estimated by applying an effective period factor of 2.3 and 2.1 for near‐field and far‐field records, respectively, and 9% damped displacement response spectrum. For regions of moderate seismicity, a lower effective period factor of 1.9 and 1.8, for near‐field and far‐field records, respectively, can be applied to estimate the maximum roof displacement. A relationship between linear and nonlinear response of multi‐degree‐of‐freedom systems was also proposed to obtain estimates of the maximum inter‐story drift of nonlinear responding reinforced concrete frames. In addition, the effects of number of ground motion records used in the analyses on the scatters of results were investigated. The required number of ground motions to produce a reliable response was proposed. Copyright © 2013 John Wiley & Sons, Ltd.     

Sensitivity of interfacial hydraulics to the microtopographic roughness of water‐lain gravels

Flow within the interfacial layer of gravel‐bed rivers is poorly understood, but this zone is important because the hydraulics here transport sediment, generate flow structures and interact with benthic organisms. We hypothesized that different gravel‐bed microtopographies generate measurable differences in hydraulic characteristics within the interfacial layer. This was tested using a high density of spatially and vertically distributed, velocity time series measured in the interfacial layers above three surfaces of contrasting microtopography. These surfaces had natural water‐worked textures, captured in the field using a casting procedure. Analysis was repeated for three discharges, with Reynolds numbers between 165000 and 287000, to evaluate whether discharge affected the impact of microtopography on interfacial flows. Relative submergence varied over a small range (3.5 to 8.1) characteristic of upland gravel‐bed rivers. Between‐surface differences in the median and variance of several time‐averaged and turbulent flow parameters were tested using non‐parametric statistics. Across all discharges, microtopographic differences did not affect spatially averaged (median) values of streamwise velocity, but were associated with significant differences in its spatial variance, and did affect spatially averaged (median) turbulent kinetic energy. Sweep and ejection events dominated the interfacial region above all surfaces at all flows, but there was a microtopographic effect, with Q2 and Q4 events less dominant and structures less persistent above the surface with the widest relief distribution, especially at the highest Reynolds number flow. Results are broadly consistent with earlier work, although this analysis is unique because of the focus on interfacial hydraulics, spatially averaged ‘patch scale’ metrics and a statistical approach to data analysis. An important implication is that observable differences in microtopography do not necessarily produce differences in interfacial hydraulics. An important observation is that appropriate roughness parameterizations for gravel‐bed rivers remain elusive, partly because the relative contributions to flow resistance of different aspects of bed microtopography are poorly constrained. © 2014 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.     

Statistical models for shear strength of RC beam‐column joints using machine‐learning techniques

This paper proposes a new set of probabilistic joint shear strength models using the conventional multiple linear regression method, and advanced machine‐learning methods of multivariate adaptive regression splines (MARS) and symbolic regression (SR). In order to achieve high‐fidelity regression models with reduced model errors and bias, this study constructs extensive experimental databases for reinforced and unreinforced concrete joints by collecting existing beam‐column joint subassemblage tests from multiple sources. Various influential parameters that affect joint shear strength such as material properties, design parameters, and joint configuration are investigated through tests of statistical significance. After performing a set of regression analyses, the comparison of simulation results indicates that MARS approach is the best estimation method. Moreover, the accuracy of analytical predictions of the derived MARS model is compared with that of existing joint shear strength relationships. The comparison results show that the proposed model is more accurate compared to existing relationships. This joint shear strength prediction model can be readily implemented into joint response models for evaluation of earthquake performance and inelastic responses of building frames. Copyright © 2014 John Wiley & Sons, Ltd.     

Seismic design and testing of the bottom vertical boundary elements in steel plate shear walls. Part 1: design methodology

This research investigates the seismic design method and the cyclic inelastic behavior of the bottom column, also called the vertical boundary element (VBE), in steel plate shear walls (SPSWs). This study consists of two parts. This Part 1 paper discusses the anticipated pushover responses for properly designed SPSWs and the possible inelastic responses of the bottom VBE at various levels of inter‐story drift. Considering both the tension field action of the infill panel and the sway action of the boundary frame, this study develops a simplified method to compute the flexural and shear demands in the bottom VBE. Based on the superposition method, this approach considers various plastic hinge forming locations at different levels of inter‐story drift. One of the key performance‐based design objectives is to ensure that the top ends of the bottom VBEs remain elastic when the SPSWs are subjected to the maximum considered earthquake. This paper presents the comprehensive design procedures for the bottom VBE. Furthermore, this study conducted cyclic performance evaluation tests of three full‐scale two‐story SPSWs at the Taiwan National Center for Research on Earthquake Engineering in 2011 to validate the effectiveness of the proposed design methods. The experimental program, cyclic inelastic responses of the SPSWs and bottom VBEs, and numerical simulations are presented in Part 2. Copyright © 2014 John Wiley & Sons, Ltd.     

Understanding river dune splitting through flume experiments and analysis of a dune evolution model

Forecasts of water level during river floods require accurate predictions of the evolution of river dune dimensions, because the hydraulic roughness of the main channel is largely determined by the bed morphology. River dune dimensions are controlled by processes like merging and splitting of dunes. Particularly the process of dune splitting is still poorly understood and – as a result – not yet included in operational dune evolution models. In the current paper, the process of dune splitting is investigated by carrying out laboratory experiments and by means of a sensitivity analysis using a numerical dune evolution model. In the numerical model, we introduced superimposed TRIAS ripples (i.e. triangular asymmetric stoss side‐ripples) on the stoss sides of underlying dunes as soon as these stoss sides exceed a certain critical length. Simulations with the model including dune splitting showed that predictions of equilibrium dune characteristics were significantly improved compared to the model without dune splitting. As dune splitting is implemented in a parameterized way, the computational cost remains low which means that dune evolution can be calculated on the timescale of a flood wave. Subsequently, we used this model to study the mechanism of dune splitting. Literature showed that the initiation of a strong flow separation zone behind a superimposed bedform is one of the main mechanisms behind dune splitting. The flume experiments indicated that besides its height also the lee side slope of the superimposed bedform is an important factor to determine the strength of the flow separation zone and therefore is an important aspect in dune splitting. The sensitivity analysis of the dune evolution model showed that a minimum stoss side length was required to develop a strong flow separation zone. Copyright © 2014 John Wiley & Sons, Ltd.     

Geophysical constraints on deep weathering and water storage potential in the Southern Sierra Critical Zone Observatory

The conversion of bedrock to regolith marks the inception of critical zone processes, but the factors that regulate it remain poorly understood. Although the thickness and degree of weathering of regolith are widely thought to be important regulators of the development of regolith and its water‐storage potential, the functional relationships between regolith properties and the processes that generate it remain poorly documented. This is due in part to the fact that regolith is difficult to characterize by direct observations over the broad scales needed for process‐based understanding of the critical zone. Here we use seismic refraction and resistivity imaging techniques to estimate variations in regolith thickness and porosity across a forested slope and swampy meadow in the Southern Sierra Critical Zone Observatory (SSCZO). Inferred seismic velocities and electrical resistivities image a weathering zone ranging in thickness from 10 to 35 m (average = 23 m) along one intensively studied transect. The inferred weathering zone consists of roughly equal thicknesses of saprolite (P‐velocity < 2 km s^?1) and moderately weathered bedrock (P‐velocity = 2–4 km s^?1). A minimum‐porosity model assuming dry pore space shows porosities as high as 50% near the surface, decreasing to near zero at the base of weathered rock. Physical properties of saprolite samples from hand augering and push cores are consistent with our rock physics model when variations in pore saturation are taken into account. Our results indicate that saprolite is a crucial reservoir of water, potentially storing an average of 3 m³ m^?2 of water along a forested slope in the headwaters of the SSCZO. When coupled with published erosion rates from cosmogenic nuclides, our geophysical estimates of weathering zone thickness imply regolith residence times on the order of 10⁵ years. Thus, soils at the surface today may integrate weathering over glacial–interglacial fluctuations in climate. Copyright © 2013 John Wiley & Sons, Ltd.     

Paleoflood events recorded by speleothems in caves

Speleothems are usually composed of thin layers of calcite (or aragonite). However, cemented detrital materials interlayered between laminae of speleothemic carbonate have been also observed in many caves. Flowstones comprising discontinuous carbonate layers form due to flowing water films, while flood events introduce fluviokarstic sediments in caves that, on occasion, are recorded as clayey layers inside flowstones and stalagmites. This record provides a potential means of understanding the frequency of palaeofloods using cave records. In this work, we investigate the origin of this type of detrital deposit in El Soplao Cave (Northern Spain). The age of the lowest aragonite layer of a flowstone reveals that the earliest flood period occurred before 500 ka, though most of the flowstone formed between 422 +69/‐43 ka and 400 +66/‐42 ka. This suggests that the cave was periodically affected by palaeoflood events that introduced detrital sediments from the surface as a result of occasional extreme rainfall events, especially at around 400 ka. The mineralogical data enable an evolutionary model for this flowstone to be generated based on the alternation of flood events with laminar flows and carbonate layers precipitation that can be extrapolated to other caves in which detrital sediments inside speleothems have been found. Copyright © 2014 John Wiley & Sons, Ltd.     

Evaluating flash-flood warnings at ungauged locations using post-event surveys: a case study with the AIGA warning system

Abstract

This article presents a comparison between real-time discharges calculated by a flash-flood warning system and post-event flood peak estimates. The studied event occurred on 15 and 16 June 2010 at the Argens catchment located in the south of France. Real-time flood warnings were provided by the AIGA (Adaptation d’Information Géographique pour l’Alerte en Crue) warning system, which is based on a simple distributed hydrological model run at a 1-km² resolution using radar rainfall information. The timing of the warnings (updated every 15 min) was compared to the observed flood impacts. Furthermore, “consolidated” flood peaks estimated by an intensive post-event survey were used to evaluate the AIGA-estimated peak discharges. The results indicated that the AIGA warnings clearly identified the most affected areas. However, the effective lead-time of the event detection was short, especially for fast-response catchments, because the current method does not take into account any rainfall forecast. The flood peak analysis showed a relatively good correspondence between AIGA- and field-estimated peak values, although some differences were due to the rainfall underestimation by the radar and rainfall–runoff model limitations.

Editor Z.W. Kundzewicz; Guest editor R.J. Moore

Citation Javelle, P., Demargne, J., Defrance, D., Pansu, J. and Arnaud, P., 2014. Evaluating flash-flood warnings at ungauged locations using post-event surveys: a case study with the AIGA warning system. Hydrological Sciences Journal, 59 (7), 1390–1402. http://dx.doi.org/10.1080/02626667.2014.923970