Geochemistry,Zircon U–Pb Analysis,and Biotite 40Ar/39Ar Geochronology of the Maoling Gold Deposit,Liaodong Rift,NE China

The Maoling gold deposit is located in the southwestern part of the Liaodong rift, NE China, and has estimated reserves of 25 t. In this paper we present the results of an investigation into the geochronology and geodynamic mechanisms of igneous activity and metallogenesis within the Maoling gold deposit. New zircon U–Pb age data, biotite ⁴⁰Ar/³⁹Ar age data, whole‐rock geochemistry, and Hf isotopic analyses are presented in order to constrain the petrogenesis and mineralization of the deposit. Zircon U–Pb dating of the Wolongquan biotite monzogranite and Maoling biotite granite yielded mean ages of 194.0 ± 1.1 Ma and 196.1 ± 1.1 Ma, respectively. All the granites are characteristically high‐K calc‐alkaline, enriched in light rare earth elements and large ion lithophile elements, and depleted in high field strength elements, which is consistent with the geochemical characteristics of arc‐type magmas. The Hf isotope characteristics indicate that the granites formed by partial melting of early Paleoproterozoic crustal material. In addition, biotite ⁴⁰Ar/³⁹Ar dating indicates that the Maoling gold deposit formed at 188.9 ± 1.2 Ma, implying that the mineralization was related to both the granite intrusions. Taking into account previous data on S–Pb–O–H isotopes and our new age data, the Maoling deposit can be classified as an intrusion‐related gold deposit. Taking into account the geology of the study area and adjacent regions, we propose that the Maoling gold deposit and its associated granitic intrusions formed in a geodynamic setting that was dominated by subduction of the Paleo‐Pacific Plate beneath the Eurasian continent.     

Fluid Inclusions and Hydrogen,Oxygen, and Lead Isotopes of the Antuoling Molybdenum Deposit,Northern Taihang Mountains,China

The Antuoling Mo deposit is a major porphyry‐type deposit in the polymetallic metallogenic belt of the northern Taihang Mountains, China. The processes of mineralization in this deposit can be divided into three stages: an early quartz–pyrite stage, a middle quartz–polymetallic sulfide stage, and a late quartz–carbonate stage. Four types of primary fluid inclusions are found in the deposit: two‐phase aqueous inclusions, daughter‐mineral‐bearing multiphase inclusions, CO₂–H₂O inclusions, and pure CO₂ inclusions. From the early to the late ore‐forming stages, the homogenization temperatures of the fluid inclusions are 300 to >500°C, 270–425°C, and 195–330°C, respectively, with salinities of up to 50.2 wt%, 5.3–47.3 wt%, and 2.2–10.4 wt% NaCl equivalent, revealing that the ore‐forming fluids changed from high temperature and high salinity to lower temperature and lower salinity. Moreover, based on the laser Raman spectra, the compositions of the fluid inclusions evolved from the NaCl–CO₂–H₂O to the NaCl–H₂O system. The δ¹⁸O_H2O and δD values of quartz in the deposit range from +3.9‰ to +7.0‰ and ?117.5‰ to ?134.2‰, respectively, reflecting the δD of local meteoric water after oxygen isotopic exchange with host rocks. The Pb isotope values of the sulfides (²⁰⁸Pb/²⁰⁴Pb, 36.320–37.428; ²⁰⁷Pb/²⁰⁴Pb, 15.210–15.495; ²⁰⁶Pb/²⁰⁴Pb, 16.366–17.822) indicate that the ore‐forming materials originated from a mixed upper mantle–lower crust source.     

Instrumentation Development for In Situ 40Ar/39Ar Planetary Geochronology

The chronology of the Solar System, particularly the timing of formation of extra‐terrestrial bodies and their features, is an outstanding problem in planetary science. Although various chronological methods for in situ geochronology have been proposed (e.g., Rb‐Sr, K‐Ar), and even applied (K‐Ar), the reliability, accuracy, and applicability of the ⁴⁰Ar/³⁹Ar method makes it by far the most desirable chronometer for dating extra‐terrestrial bodies. The method however relies on the neutron irradiation of samples, and thus a neutron source. Herein, we discuss the challenges and feasibility of deploying a passive neutron source to planetary surfaces for the in situ application of the ⁴⁰Ar/³⁹Ar chronometer. Requirements in generating and shielding neutrons, as well as analysing samples are described, along with an exploration of limitations such as mass, power and cost. Two potential solutions for the in situ extra‐terrestrial deployment of the ⁴⁰Ar/³⁹Ar method are presented. Although this represents a challenging task, developing the technology to apply the ⁴⁰Ar/³⁹Ar method on planetary surfaces would represent a major advance towards constraining the timescale of solar system formation and evolution.     

Effect of pore geometry on Gassmann fluid substitution

Although there is no assumption of pore geometry in derivation of Gassmann's equation, the pore geometry is in close relation with hygroscopic water content and pore fluid communication between the micropores and the macropores. The hygroscopic water content in common reservoir rocks is small, and its effect on elastic properties is ignored in the Gassmann theory. However, the volume of hygroscopic water can be significant in shaly rocks or rocks made of fine particles; therefore, its effect on the elastic properties may be important. If the pore fluids in microspores cannot reach pressure equilibrium with the macropore system, assumption of the Gassmann theory is violated. Therefore, due to pore structure complexity, there may be a significant part of the pore fluids that do not satisfy the assumption of the Gassmann theory. We recommend that this part of pore fluids be accounted for within the solid rock frame and effective porosity be used in Gassmann's equation for fluid substitution. Integrated study of ultrasonic laboratory measurement data, petrographic data, mercury injection capillary pressure data, and nuclear magnetic resonance T₂ data confirms rationality of using effective porosity for Gassmann fluid substitution. The effective porosity for Gassmann's equation should be frequency dependent. Knowing the pore geometry, if an empirical correlation between frequency and the threshold pore‐throat radius or nuclear magnetic resonance T₂ could be set up, Gassmann's equation can be applicable to data measured at different frequencies. Without information of the pore geometry, the irreducible water saturation can be used to estimate the effective porosity.     

Deep massive sulphide exploration using 2D and 3D geoelectrical and induced polarization data in Skellefte mining district,northern Sweden

Geoelectrical and induced polarization data from measurements along three profiles and from one 3D survey are acquired and processed in the central Skellefte District, northern Sweden. The data were collected during two field campaigns in 2009 and 2010 in order to delineate the structures related to volcanogenic massive sulphide deposits and to model lithological contacts down to a maximum depth of 1.5 km. The 2009 data were inverted previously, and their joint interpretation with potential field data indicated several anomalous zones. The 2010 data not only provide additional information from greater depths compared with the 2009 data but also cover a larger surface area. Several high‐chargeability low‐resistivity zones, interpreted as possible massive sulphide mineralization and associated hydrothermal alteration, are revealed. The 3D survey data provide a detailed high‐resolution image of the top ～450 m of the upper crust around the Maurliden East, North, and Central deposits. Several anomalies are interpreted as new potential prospects in the Maurliden area, which are mainly concentrated in the central conductive zone. In addition, the contact relationship between the major geological units, e.g., the contact between the Skellefte Group and the Jörn Intrusive Complex, is better understood with the help of 2010 deep‐resistivity/chargeability data. The bottommost part of the Vargfors basin is imaged using the 2010 geoelectrical and induced polarization data down to ～1‐km depth.     

Seismic design and testing of buckling‐restrained braces with a thin profile

A thin‐profile buckling‐restrained brace (thin‐BRB) consists of a rectangular steel casing and a flat steel core that is parallel to a gusset plate. A thin configuration reduces the width of the restraining member and thus saves usable space in buildings. However, deformable debonding layers, which cover the steel core plate in order to mitigate the difference between the peak tensile and compressive axial forces, provide a space for the steel core to form high mode buckling waves when the thin‐BRB is under compression. The wave crests squeeze the debonding layers and produce outward forces on the inner surface of the restraining member. If the restraining member is too weak in sustaining the outward forces, local bulging failure occurs and the thin‐BRB loses its compression capacity immediately. In order to investigate local bulging behavior, a total of 22 thin‐BRB specimens with a ratio of steel core plate to restraining steel tube depth ranging from 0.3 to 0.7 and axial yield force capacities ranging from 421 kN to 3036 kN were tested by applying either cyclically increasing, decreasing, or constant axial strains. The restraining steel tube widths of all the specimens were smaller than 200 mm and were infilled with mortar with a compressive strength of 97 MPa or 55 MPa. Thirteen of the 22 thin‐BRB specimens' restraining members bulged out when the compressive core strains exceeded 0.03. A seismic design method of the thin‐BRB in preventing local bulging failure is proposed in this study. Test and finite element model (FEM) analysis results suggest that the outward forces can be estimated according to the BRB compressive strength, steel core high mode buckling wavelength, and the debonding layer thickness. In addition, the capacity of the restraining member in resisting the outward forces can be estimated by using the upper bound theory in plastic analysis. Both the FEM analysis and test results indicate that the proposed method is effective in predicting the possibility of local bulging failure. Test results indicate that the proposed design method is conservative for thin‐BRB specimens with a large steel core plate to restraining steel tube depth ratio. This paper concludes with design recommendations for thin‐BRBs for severe seismic services. Copyright © 2015 John Wiley & Sons, Ltd.     

Numerical estimation of carbonate rock properties using multiscale images

Characterizing the pore space of rock samples using three‐dimensional (3D) X‐ray computed tomography images is a crucial step in digital rock physics. Indeed, the quality of the pore network extracted has a high impact on the prediction of rock properties such as porosity, permeability and elastic moduli. In carbonate rocks, it is usually very difficult to find a single image resolution which fully captures the sample pore network because of the heterogeneities existing at different scales. Hence, to overcome this limitation a multiscale analysis of the pore space may be needed. In this paper, we present a method to estimate porosity and elastic properties of clean carbonate (without clay content) samples from 3D X‐ray microtomography images at multiple resolutions. We perform a three‐phase segmentation to separate grains, pores and unresolved porous phase using 19 μm resolution images of each core plug. Then, we use images with higher resolution (between 0.3 and 2 μm) of microplugs extracted from the core plug samples. These subsets of images are assumed to be representative of the unresolved phase. We estimate the porosity and elastic properties of each sample by extrapolating the microplug properties to the whole unresolved phase. In addition, we compute the absolute permeability using the lattice Boltzmann method on the microplug images due to the low resolution of the core plug images. In order to validate the results of the numerical simulations, we compare our results with available laboratory measurements at the core plug scale. Porosity average simulations for the eight samples agree within 13%. Permeability numerical predictions provide realistic values in the range of experimental data but with a higher relative error. Finally, elastic moduli show the highest disagreements, with simulation error values exceeding 150% for three samples.     

Gravimetric monitoring of the first field‐wide steam injection in a fractured carbonate field in Oman – a feasibility study

Gas‐Oil Gravity Drainage is to be enhanced by steam injection in a highly fractured, low permeability carbonate field in Oman. Following a successful pilot, field‐wide steam injection is being implemented, first of this type in the world. A dedicated monitoring program has been designed to track changes in the reservoir. Various observations are to be acquired, including, surface deformation, temperature measurements, microseismic, well logs, pressure and saturation measurements to monitor the reservoir. Because significant changes in the reservoir density are expected, time‐lapse gravimetry is also being considered. In this paper we investigate the feasibility of gravimetric monitoring of the thermally enhanced gravity drainage process at the carbonate field in Oman. For this purpose, forward gravity modelling is performed. Based on field groundwater measurements, the estimates of the hydrological signal are considered and it is investigated under what conditions the groundwater influences can be minimized. Using regularized inversion of synthetic gravity data, we analyse the achievable accuracy of heat‐front position estimates. In case of large groundwater variations at the field, the gravity observations can be significantly affected and, consequently, the accuracy of heat‐front monitoring can be deteriorated. We show that, by applying gravity corrections based on local observations of groundwater, the hydrological influences can to a large extent be reduced and the accuracy of estimates can be improved. We conclude that gravimetric monitoring of the heat‐front evolution has a great potential.