Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.     

Responses of meiofauna and nematode communities to crude oil contamination in a laboratory microcosm experiment

We examined the effects of crude oil contamination on community assemblages of meiofauna and nematodes after exposure to total petroleum hydrocarbons in the laboratory. We administered a seawater solution that had been contaminated with total petroleum hydrocarbons to seven treatment groups at different concentrations, while the control group received uncontaminated filtered seawater. The average density of total meiofauna in the experimental microcosms diluted with 0.5%, 1%, 2%, and 4% contaminated seawater was higher than the density in the control. The average density of total meiofauna in the 8%, 15%, and 20% microcosms was lower than the density in the control. The density of nematodes was similar to that of the total meiofauna. Cluster analysis divided the microcosms into group 1 (control, 0.5%, 1%, 2%, and 4% microcosms) and group 2 (8%, 15%, and 20% microcosms). However, SIMPROF analysis showed no significant difference between the two groups (p > 0.05). Bolbolaimus spp. (37.1%) were dominant among the nematodes. Cluster analysis showed similar results for nematode and meiofaunal communities. The total meiofaunal density, nematode density, and number of Bolbolaimus spp. individuals were significantly negatively associated with the concentration of total petroleum hydrocarbons (Spearman correlation coefficients, p < 0.05). Within the nematodes, epistrate feeders (group 2A: 46%) were the most abundant trophic group. Among the treatment groups, the abundance of group 2A increased in low-concentration microcosms and decreased in high-concentration microcosms. Thus, our findings provide information on the effects of oil pollution on meiofauna in the intertidal zones of sandy beaches.     

An introduction to the classification of the physiognomic landscape types: methodology and results of testing in the area of Kazimierz Landscape Park (Poland)

The publication of the European Landscape Convention (2000) had a stimulating effect on the development of both new systems of landscape classification and new methods of their evaluation and mapping. As an example, a new classification of physiognomic landscape types was developed in Poland in 2014. The objectives of the paper are to (1) popularize, on the international scale, the classification of physiognomic landscape types in a new, improved version, (2) present the original method of physiognomic landscape types mapping with the use of the system of basic landscape units, and (3) present the results of testing of the method in the area of the Kazimierz Landscape Park, Poland. In the area of the Kazimierz Landscape Park, 491 basic landscape units were delimited, within which, on the basis of the leading traits of land relief and cover forms, the physiognomic landscape types were identified. Maps of this type can be important tools in implementing the recommendations of the European Landscape Convention. The total number of physiognomic landscape types identified within a specific area can be one of the key indicators of landscape diversity.     

Binary gas sorption/desorption experiments on a bituminous coal: Simultaneous measurements on sorption kinetics,volumetric strain and acoustic emission

There is still no clear understanding of the specific interactions between coal and gas molecules. In this context sorption–desorption studies of methane and carbon dioxide, both in a single gas environment and gas mixtures, are of fundamental interest. This paper presents the results of unique simultaneous measurements of sorption kinetics, volumetric strain and acoustic emission (AE) on three tetragonal coal samples subjected to sorption of carbon dioxide and methane mixtures. The coal was a high volatile bituminous C coal taken from the Budryk mine in the Upper Silesia Basin, Poland. Three different gas mixtures were used in the sorption tests, with dominant CO₂, with dominant CH₄ and a 50/50 mixture.The experimental set-up was designed specially for this study. It consisted of three individual units working together: (i) a unit for gas sorption experiments using a volumetric method, (ii) an AE apparatus for detecting, recording and analysing AE, and (iii) a strain meter for measuring strains induced in the coal sample by gas sorption/desorption. All measurements were computer aided.The experiments indicated that the coal tested showed preferential sorption of CH₄ at 2.6 MPa pressure and exhibited comparable affinities for CH₄ and CO₂ at higher pressures (4.0 MPa). The results of chromatographic analysis of the gas released on desorption suggested that the desorption of methane from the coal was favoured. The relationship between the volumetric strain and the amount of sorbed gas was found to be non-linear. These results were contrary to common opinions on the coal behaviour. Furthermore, it appeared that the swelling/shrinkage of coal was clearly influenced by the network of fractures. Besides, the AE and strain characteristics suggested common sources of sorption induced AE and strain.The present results may have implications for the sequestration of carbon dioxide in coal seams and enhanced coalbed methane recovery (ECBM).     

Exploring large wood retention and deposition in contrasting river morphologies linking numerical modelling and field observations

Large wood tends to be deposited in specific geomorphic units within rivers. Nevertheless, predicting the spatial distribution of wood deposits once wood enters a river is still difficult because of the inherent complexity of its dynamics. In addition, the lack of long‐term observations or monitored sites has usually resulted in a rather incomplete understanding of the main factors controlling wood deposition under natural conditions. In this study, the deposition of large wood was investigated in the Czarny Dunajec River, Polish Carpathians, by linking numerical modelling and field observations so as to identify the main factors influencing wood retention in rivers. Results show that wood retention capacity is higher in unmanaged multi‐thread channels than in channelized, single‐thread reaches. We also identify preferential sites for wood deposition based on the probability of deposition under different flood scenarios, and observe different deposition patterns depending on the geomorphic configuration of the study reach. In addition, results indicate that wood is not always deposited in the geomorphic units with the highest roughness, except for low‐magnitude floods. We conclude that wood deposition is controlled by flood magnitude and the elevation of flooded surfaces in relation to the low‐flow water surface. In that sense, the elevation at which wood is deposited in rivers will differ between floods of different magnitude. Therefore, together with the morphology, flood magnitude represents the most significant control on wood deposition in mountain rivers wider than the height of riparian trees. Copyright © 2015 John Wiley & Sons, Ltd.     

TraceeElements in Leccinum scabrum mushrooms and topsoils from Kłodzka Dale in Sudety Mountains, Poland

In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.     

Periglacial and Fluvial Factors Controlling the Sedimentation of Pleistocene Breccia in NW Poland

Breccias were investigated on the terrace of the Toruń‐Eberswalde ice‐marginal valley at Rozwarzyn (NW Poland). Breccia layers include soft‐sediment clasts with diameters between 2 and 256 mm and soft‐sediment megaclasts with diameters from 256 mm to 7 m. The shape of the soft‐sediment clasts and megaclasts (derived from frozen sediments) in the breccia is diverse: from angular and irregular in the case of debris‐flow breccias to slightly rounded and tabular in fluvial breccias. These two types of breccias were developed during the Late Weichselian when the periglacial climate favored extensive lateral erosion by currents of frozen braided channels in the ice‐marginal valley. The dual presence of breccias of fluvial and debris‐flow origin in channel deposits is unique for Quaternary sediments. Zones of breccias existed in the channels where scours and obstacle marks related to megaclasts developed. The study of breccias shed new light on the fluvial processes in ice‐marginal valleys during the Pleistocene and can be considered as diagnostic for fluvio‐periglacial conditions.     

Contrasting sources of Late Paleozoic rhyolite magma in the Polish Lowlands: evidence from U–Pb ages and Hf and O isotope composition in zircon

International Journal of Earth Sciences - The Polish Lowlands, located southwest of the Teisseyre–Tornquist Zone, within Trans-European Suture Zone, were affected by bimodal, but dominantly...