Determination of land degradation causes in Tongyu County,Northeast China via land cover change detection

Tongyu County in Northeast China is highly prone to land degradation due to its fragile physical settings characterized by a flat topography, a semi-arid climate, and a shallow groundwater table. This study aims to determine the causes of land degradation through detecting the long-term trend of land cover changes. Degraded lands were mapped from satellite images recorded in 1992 and 2002. These land cover maps revealed that the area subject to land degradation in the form of soil salinization, waterlogging and desertification increased from 2400 to 4214 km², in sharp contrast to most severely degraded land that decreased by 122.5 km². Newly degraded land stems from productive farmland (263 km²), harvested farmland (551 km²), and grassland (468 km²). Therefore, the worsened degradation situation is attributed to excessive reclamation of grassland for farming, over cultivation, overgrazing, and deforestation. Mechanical, biological, ecological and engineering means should be adopted to rehabilitate the degraded land.     

Surveillance for previously unmonitored organic contaminants in the San Francisco Estuary

The San Francisco Estuary Regional Monitoring Program initiated surveillance monitoring to identify previously unmonitored synthetic organic contaminants in the San Francisco Estuary. Organic extracts of water samples were analyzed using gas chromatography-mass spectrometry in full scan mode. The major contaminant classes identified in the samples were fire retardants, pesticides, personal care product ingredients, and plasticizers. Evidence from the literature suggests that some of these contaminants can persist in the environment, induce toxicity, and accumulate in marine biota and in higher food chain consumers. The major sources of these contaminants into the marine environment are the discharge of municipal and industrial wastewater effluents, urban stormwater, and agricultural runoff. As a proactive effort, it is suggested that surveillance studies be used routinely in monitoring programs to identify and prevent potential problem contaminants from harming the marine environment.     

Dynamic characteristics and horizontal transports of internal solitons generated at the Columbia River plume front

River plume front-generated internal solitons play an important role in the interaction between the plume and coastal waters. The internal solitons drive a non-harmonic velocity field, resulting in a horizontal transport that carries plume water seaward and redistributes nutrients and sediments. In this study, we present observations of internal solitons generated at the Columbia River plume front that separates the new, tidal plume, older plume and coastal waters. Scale analyses suggest that the plume front-generated internal solitons are highly non-linear waves, and their dynamic properties do not conform to any weakly non-linear theory. Thus, a high-order Korteweg–de Vries (KdV) theory is used to analyze the internal solitons. The comparison between theoretical values and cruise data shows that the high-order KdV model is much better than the weakly non-linear theories for prediction of the soliton dynamic parameters. Based on the model, we develop theoretical and numerical solutions of the soliton-induced upper layer horizontal transport and Lagrangian water parcel transport distance, which shows that the water particle drift, during the internal soliton passage, is as far as 1 km, and demonstrates the role of the internal solitons on the exchange between the plume and ambient coastal water. Energy fluxes caused by the internal solitons are estimated using the high-order KdV theory. The leading soliton fluxes 2.0×10³ W m⁻¹ per unit crest length, and carries energy of 4.2×10⁵ J m⁻¹. The total energy carried by the eight internal solitons is 1.6×10⁶ J m⁻¹, about 70% of the total frontal energy.     

Byproduct Formation During the Reduction of TCE by Zero-Valence Iron and Palladized Iron

Trichloroethene (TCE) was reduced with zero-valence iron and palladized iron in zero-head-space extractors. Progress of the reaction in these batch studies was monitored with purge-and-trap gas chromatography and a flame ionization detector. When a 5 ppm initial concentration of TCF. reacts with zero-valence iron, approximately 140 ppb of vinyl chloride persists for as long as 73 days. The concentration of vinyl chloride (approximately If) ppb) remaining with palladized iron is approximately an order of magnitude less than when zero-valence iron is the reductant. These data suggest that volatile byproducts may be under-represented in oilier published data regarding reduction with zero-valence metals. These results also demonstrate that the reduction of TCE with palladized iron (0.05 percent palladium) is more than an order of magnitude faster than with zero-valence iron. Wilh a 5:1 solution-to-solid ratio the TCE half-life with zero-valence iron is 7.41 hours. but is only 0.59 hours with the palladized iron.     

Geophysical Finite-Element Simulation Tool (GeoFEST): Algorithms and Validation for Quasistatic Regional Faulted Crust Problems

GeoFEST (Geophysical Finite Element Simulation Tool) is a two- and three-dimensional finite element software package for the modeling of solid stress and strain in geophysical and other continuum domain applications. It is one of the featured high-performance applications of the NASA QuakeSim project. The program is targeted to be compiled and run on UNIX systems, and is running on diverse systems including sequential and message-passing parallel systems. Solution to the elliptical partial differential equations is obtained by finite element basis sampling, resulting in a sparse linear system primarily solved by conjugate gradient iteration to a tolerance level; on sequential systems a Crout factorization for the direct inversion of the linear system is also supported. The physics models supported include isotropic linear elasticity and both Newtonian and power-law viscoelasticity, via implicit quasi-static time stepping. In addition to triangular, quadrilateral, tetrahedral and hexahedral continuum elements, GeoFEST supports split-node faulting, body forces, and surface tractions. This software and related mesh refinement strategies have been validated on a variety of test cases with rigorous comparison to analytical solutions. These include a box-shaped domain with imposed motion on one surface, a pair of strike slip faults in stepover arrangement, and two community-agreed benchmark cases: a strike slip fault in an enclosing box, and a quarter-domain circular fault problem. Scientific applications of the code include the modeling of static and transient co- and post-seismic earth deformation, Earth response to glacial, atmospheric and hydrological loading, and other scenarios involving the bulk deformation of geologic media.     

Effects of soil layering on the characteristics of basin-edge induced surface waves

This paper presents the effects of soil layering on the characteristics of basin-edge induced surface waves and associated strain and aggravation factor. The simulated results revealed surface wave generation near the basin-edge. The first mode of induced Love wave was obtained in models having increasing velocity with depth and a large impedance contrast between the soil layers. Amplitude amplification or de-amplification of body waves was proportional to the impedance contrast between the soil layers. The average aggravation factor was inversely proportional to the impedance contrast between the soil layers in case of increasingvelocity models and proportional in case of decreasing-velocity basinedge models. On the other hand, the maximum strain was inversely proportional to the impedance contrast between the soil layers in both cases. On the average, strain was greater in case of increasing-velocity models but the average aggravation factor was greater in case of decreasingvelocity models.     

Elasticity of antigorite,seismic detection of serpentinites,and anisotropy in subduction zones

Serpentinization of the mantle wedge is an important process that influences the seismic and mechanical properties in subduction zones. Seismic detection of serpentines relies on the knowledge of elastic properties of serpentinites, which thus far has not been possible in the absence of single-crystal elastic properties of antigorite. The elastic constants of antigorite, the dominant serpentine at high-pressure in subduction zones, were measured using Brillouin spectroscopy under ambient conditions. In addition, antigorite lattice preferred orientations (LPO) were determined using an electron back-scattering diffraction (EBSD) technique. Isotropic aggregate velocities are significantly lower than those of peridotites to allow seismic detection of serpentinites from tomography. The isotropic V_P/V_S ratio is 1.76 in the Voigt–Reuss–Hill average, not very different from that of 1.73 in peridotite, but may vary between 1.70 and 1.86 between the Voigt and Reuss bonds. Antigorite and deformed serpentinites have a very high seismic anisotropy and remarkably low velocities along particular directions. V_P varies between 8.9 km s^? 1 and 5.6 km s^? 1 (46% anisotropy), and 8.3 km s^? 1 and 5.8 km s^? 1 (37%), and V_S between 5.1 km s^? 1 and 2.5 km s^? 1 (66%), and 4.7 km s^? 1 and 2.9 km s^? 1 (50%) for the single-crystal and aggregate, respectively. The V_P/V_S ratio and shear wave splitting also vary with orientation between 1.2 and 3.4, and 1.3 and 2.8 for the single-crystal and aggregate, respectively. Thus deformed serpentinites can present seismic velocities similar to peridotites for wave propagation parallel to the foliation or lower than crustal rocks for wave propagation perpendicular to the foliation. These properties can be used to detect serpentinite, quantify the amount of serpentinization, and to discuss relationships between seismic anisotropy and deformation in the mantle wedge. Regions of high V_P/V_S ratios and extremely low velocities in the mantle wedge of subduction zones (down to about 6 and 3 km.s^?1 for V_P and V_S, respectively) are difficult to explain without strong preferred orientation of serpentine. Local variations of anisotropy may result from kilometer-scale folding of serpentinites. Shear wave splittings up to 1–1.5 s can be explained with moderately thick (10–20 km) serpentinite bodies.     

Magmatism in the eastern Aleutian Arc: temporal characteristic of igneous activity on Akutan Island

Lavas from Akutan Island, located in the eastern Aleutian arc at the transition between continental and oceanic crust, show a gradual change in their petrologic and chemical characteristics over the last 4 million years. The oldest lavas exposed on the island, the Hot Springs Bay Volcanics (HSBV), range from magnesian basalt to dacite (45%–62% SiO₂). The most mafic basalts contain salitic clinopyroxene, Cr- and Al-rich spinel, and pargasitic amphibole suggesting that they were derived from relatively hydrous magmas at greater pressures than lavas from the younger Akutan Volcanics (AKV) and the modern volcano (MOD). AKV lavas also range between basalt and dacite (46%–63% SiO₂), but contain no hydrous phenocrysts and seem to have fractionated within a shallow level magma chamber. Lavas from the modern volcano are andesitic (52%–57% SiO₂) and have a mineral assemblage similar to that of AKV lavas of similar composition. With the exception of clinopyroxene and spinel in the most mafic lavas, the compositions of plagioclase (An_92?45), olivine (Fo_88?51), orthopyroxene (En_69?56), and titanomagnetite (15%–21% TiO₂) phenocrysts found in these lavas are within the range observed in lavas from other Aleutian volcanoes. Variations in the major element chemistry of the older lavas can be reproduced by fractional crystallization of the observed mineral assemblages, however closed system crystal fractionation models are inadequate to explain the trace element variations. During the last 4 million years, La/Yb ratios have decreased (6.5–3.3 for HSBV lavas and 2.9–1.9 for MOD lavas) whereas Ba/La ratios appear to have increased slightly (37–43 for HSBV and AKV, and 41–45 of MOD). The lower La/Yb ratios of MOD lavas correspond with lower total abundances of the REE and slightly higher Sr and Pb isotopic ratios. The increased⁸⁷Sr/⁸⁶Sr ratios and Pb isotopic ratios in the MOD lavas, the less enriched LREE, and the higher Ba/La ratios may result from partial melting of an arc source which has experienced previous melting events but has continued to be contaminated by a component from the subducting slab. It may also indicate a change in the degree of partial melting of the underlying mantle, which corresponds to a different percentage of a slab derived component being incorporated into the overlying mantle.