Dynamic characteristics and horizontal transports of internal solitons generated at the Columbia River plume front

River plume front-generated internal solitons play an important role in the interaction between the plume and coastal waters. The internal solitons drive a non-harmonic velocity field, resulting in a horizontal transport that carries plume water seaward and redistributes nutrients and sediments. In this study, we present observations of internal solitons generated at the Columbia River plume front that separates the new, tidal plume, older plume and coastal waters. Scale analyses suggest that the plume front-generated internal solitons are highly non-linear waves, and their dynamic properties do not conform to any weakly non-linear theory. Thus, a high-order Korteweg–de Vries (KdV) theory is used to analyze the internal solitons. The comparison between theoretical values and cruise data shows that the high-order KdV model is much better than the weakly non-linear theories for prediction of the soliton dynamic parameters. Based on the model, we develop theoretical and numerical solutions of the soliton-induced upper layer horizontal transport and Lagrangian water parcel transport distance, which shows that the water particle drift, during the internal soliton passage, is as far as 1 km, and demonstrates the role of the internal solitons on the exchange between the plume and ambient coastal water. Energy fluxes caused by the internal solitons are estimated using the high-order KdV theory. The leading soliton fluxes 2.0×10³ W m⁻¹ per unit crest length, and carries energy of 4.2×10⁵ J m⁻¹. The total energy carried by the eight internal solitons is 1.6×10⁶ J m⁻¹, about 70% of the total frontal energy.     

Byproduct Formation During the Reduction of TCE by Zero-Valence Iron and Palladized Iron

Trichloroethene (TCE) was reduced with zero-valence iron and palladized iron in zero-head-space extractors. Progress of the reaction in these batch studies was monitored with purge-and-trap gas chromatography and a flame ionization detector. When a 5 ppm initial concentration of TCF. reacts with zero-valence iron, approximately 140 ppb of vinyl chloride persists for as long as 73 days. The concentration of vinyl chloride (approximately If) ppb) remaining with palladized iron is approximately an order of magnitude less than when zero-valence iron is the reductant. These data suggest that volatile byproducts may be under-represented in oilier published data regarding reduction with zero-valence metals. These results also demonstrate that the reduction of TCE with palladized iron (0.05 percent palladium) is more than an order of magnitude faster than with zero-valence iron. Wilh a 5:1 solution-to-solid ratio the TCE half-life with zero-valence iron is 7.41 hours. but is only 0.59 hours with the palladized iron.     

Geophysical Finite-Element Simulation Tool (GeoFEST): Algorithms and Validation for Quasistatic Regional Faulted Crust Problems

GeoFEST (Geophysical Finite Element Simulation Tool) is a two- and three-dimensional finite element software package for the modeling of solid stress and strain in geophysical and other continuum domain applications. It is one of the featured high-performance applications of the NASA QuakeSim project. The program is targeted to be compiled and run on UNIX systems, and is running on diverse systems including sequential and message-passing parallel systems. Solution to the elliptical partial differential equations is obtained by finite element basis sampling, resulting in a sparse linear system primarily solved by conjugate gradient iteration to a tolerance level; on sequential systems a Crout factorization for the direct inversion of the linear system is also supported. The physics models supported include isotropic linear elasticity and both Newtonian and power-law viscoelasticity, via implicit quasi-static time stepping. In addition to triangular, quadrilateral, tetrahedral and hexahedral continuum elements, GeoFEST supports split-node faulting, body forces, and surface tractions. This software and related mesh refinement strategies have been validated on a variety of test cases with rigorous comparison to analytical solutions. These include a box-shaped domain with imposed motion on one surface, a pair of strike slip faults in stepover arrangement, and two community-agreed benchmark cases: a strike slip fault in an enclosing box, and a quarter-domain circular fault problem. Scientific applications of the code include the modeling of static and transient co- and post-seismic earth deformation, Earth response to glacial, atmospheric and hydrological loading, and other scenarios involving the bulk deformation of geologic media.     

Effects of soil layering on the characteristics of basin-edge induced surface waves

This paper presents the effects of soil layering on the characteristics of basin-edge induced surface waves and associated strain and aggravation factor. The simulated results revealed surface wave generation near the basin-edge. The first mode of induced Love wave was obtained in models having increasing velocity with depth and a large impedance contrast between the soil layers. Amplitude amplification or de-amplification of body waves was proportional to the impedance contrast between the soil layers. The average aggravation factor was inversely proportional to the impedance contrast between the soil layers in case of increasingvelocity models and proportional in case of decreasing-velocity basinedge models. On the other hand, the maximum strain was inversely proportional to the impedance contrast between the soil layers in both cases. On the average, strain was greater in case of increasing-velocity models but the average aggravation factor was greater in case of decreasingvelocity models.     

Elasticity of antigorite,seismic detection of serpentinites,and anisotropy in subduction zones

Serpentinization of the mantle wedge is an important process that influences the seismic and mechanical properties in subduction zones. Seismic detection of serpentines relies on the knowledge of elastic properties of serpentinites, which thus far has not been possible in the absence of single-crystal elastic properties of antigorite. The elastic constants of antigorite, the dominant serpentine at high-pressure in subduction zones, were measured using Brillouin spectroscopy under ambient conditions. In addition, antigorite lattice preferred orientations (LPO) were determined using an electron back-scattering diffraction (EBSD) technique. Isotropic aggregate velocities are significantly lower than those of peridotites to allow seismic detection of serpentinites from tomography. The isotropic V_P/V_S ratio is 1.76 in the Voigt–Reuss–Hill average, not very different from that of 1.73 in peridotite, but may vary between 1.70 and 1.86 between the Voigt and Reuss bonds. Antigorite and deformed serpentinites have a very high seismic anisotropy and remarkably low velocities along particular directions. V_P varies between 8.9 km s^? 1 and 5.6 km s^? 1 (46% anisotropy), and 8.3 km s^? 1 and 5.8 km s^? 1 (37%), and V_S between 5.1 km s^? 1 and 2.5 km s^? 1 (66%), and 4.7 km s^? 1 and 2.9 km s^? 1 (50%) for the single-crystal and aggregate, respectively. The V_P/V_S ratio and shear wave splitting also vary with orientation between 1.2 and 3.4, and 1.3 and 2.8 for the single-crystal and aggregate, respectively. Thus deformed serpentinites can present seismic velocities similar to peridotites for wave propagation parallel to the foliation or lower than crustal rocks for wave propagation perpendicular to the foliation. These properties can be used to detect serpentinite, quantify the amount of serpentinization, and to discuss relationships between seismic anisotropy and deformation in the mantle wedge. Regions of high V_P/V_S ratios and extremely low velocities in the mantle wedge of subduction zones (down to about 6 and 3 km.s^?1 for V_P and V_S, respectively) are difficult to explain without strong preferred orientation of serpentine. Local variations of anisotropy may result from kilometer-scale folding of serpentinites. Shear wave splittings up to 1–1.5 s can be explained with moderately thick (10–20 km) serpentinite bodies.     

Magmatism in the eastern Aleutian Arc: temporal characteristic of igneous activity on Akutan Island

Lavas from Akutan Island, located in the eastern Aleutian arc at the transition between continental and oceanic crust, show a gradual change in their petrologic and chemical characteristics over the last 4 million years. The oldest lavas exposed on the island, the Hot Springs Bay Volcanics (HSBV), range from magnesian basalt to dacite (45%–62% SiO₂). The most mafic basalts contain salitic clinopyroxene, Cr- and Al-rich spinel, and pargasitic amphibole suggesting that they were derived from relatively hydrous magmas at greater pressures than lavas from the younger Akutan Volcanics (AKV) and the modern volcano (MOD). AKV lavas also range between basalt and dacite (46%–63% SiO₂), but contain no hydrous phenocrysts and seem to have fractionated within a shallow level magma chamber. Lavas from the modern volcano are andesitic (52%–57% SiO₂) and have a mineral assemblage similar to that of AKV lavas of similar composition. With the exception of clinopyroxene and spinel in the most mafic lavas, the compositions of plagioclase (An_92?45), olivine (Fo_88?51), orthopyroxene (En_69?56), and titanomagnetite (15%–21% TiO₂) phenocrysts found in these lavas are within the range observed in lavas from other Aleutian volcanoes. Variations in the major element chemistry of the older lavas can be reproduced by fractional crystallization of the observed mineral assemblages, however closed system crystal fractionation models are inadequate to explain the trace element variations. During the last 4 million years, La/Yb ratios have decreased (6.5–3.3 for HSBV lavas and 2.9–1.9 for MOD lavas) whereas Ba/La ratios appear to have increased slightly (37–43 for HSBV and AKV, and 41–45 of MOD). The lower La/Yb ratios of MOD lavas correspond with lower total abundances of the REE and slightly higher Sr and Pb isotopic ratios. The increased⁸⁷Sr/⁸⁶Sr ratios and Pb isotopic ratios in the MOD lavas, the less enriched LREE, and the higher Ba/La ratios may result from partial melting of an arc source which has experienced previous melting events but has continued to be contaminated by a component from the subducting slab. It may also indicate a change in the degree of partial melting of the underlying mantle, which corresponds to a different percentage of a slab derived component being incorporated into the overlying mantle.     

Prevalence and distribution of fecal indicator organisms in South Florida beach sand and preliminary assessment of health effects associated with beach sand exposure

Fecal indicator levels in nearshore waters of South Florida are routinely monitored to assess microbial contamination at recreational beaches. However, samples of sand from the surf zone and upper beach are not monitored which is surprising since sand may accumulate and harbor fecal-derived organisms. This study examined the prevalence of fecal indicator organisms in tidally-affected beach sand and in upper beach sand and compared these counts to levels in the water. Since indicator organisms were statistically elevated in sand relative to water, the study also considered the potential health risks associated with beach use and exposure to sand. Fecal coliforms, Escherichia coli, enterococci, somatic coliphages, and F(+)-specific coliphages were enumerated from sand and water at three South Florida beaches (Ft. Lauderdale Beach, Hollywood Beach, and Hobie Beach) over a 2-year period. Bacteria were consistently more concentrated in 100g samples of beach sand (2-23 fold in wet sand and 30-460 fold in dry sand) compared to 100ml samples of water. Somatic coliphages were commonly recovered from both sand and water while F(+)-specific coliphages were less commonly detected. Seeding experiments revealed that a single specimen of gull feces significantly influenced enterococci levels in some 3.1m(2) of beach sand. Examination of beach sand on a micro-spatial scale demonstrated that the variation in enterococci density over short distances was considerable. Results of multiple linear regression analysis showed that the physical and chemical parameters monitored in this study could only minimally account for the variation observed in indicator densities. A pilot epidemiological study was conducted to examine whether the length of exposure to beach water and sand could be correlated with health risk. Logistic regression analysis results provided preliminary evidence that time spent in the wet sand and time spent in the water were associated with a dose-dependent increase in gastrointestinal illness.     

Estimating Pile Set-up Using 24-h Restrike Resistance and Computed Static Capacity for PPC Piles Driven in Soft Lousiana Coastal Deposits

In this paper, the CPT-based predicted ultimate pile resistances (R_p) were compared with the measured pile resistances (R_m) at different elapsed time for the piles driven into saturated soft clays where piles displayed significant set-up effect. The measured pile resistances were based on 115 restrike records collected from 95 production piles, and 74 records of 9 tested piles. The predicted ultimate pile resistances were calculated from the LCPC, the Schmertmann, and the de Ruiter–Beringen methods, respectively. With the significant pile set-up effect taken into account, the relationship between measured resistances and predicted capacities at different times after pile installation were investigated. The ratios of the measured pile resistances to the predicted capacities scattered in a large spectrum. The ratios fluctuated and stayed within a range of 0.6–1.6 for different CPT methods since end of initial driving until more than 2 months after pile installation. Plots of the ratios versus the predicted pile capacities using different CPT methods have revealed that the ratio (R_m/R_p) presented a strong dependence on the predicted capacities. Great research efforts have been devoted to the analyses of the ratios of the 24-h measured resistance to the predicted capacity based on different CPT methods, in an attempt to find a feasible empirical correlation. It is found that a simple linear relationship exists between the quad root of the ratio and the predicted capacity. The developed empirical equations will give pile foundation engineers an insight into the ultimate resistances of driven piles demonstrating significant pile set-up effects. Pile set-up makes pile resistances grow with time, and it might be one of the reasons that cause the frequently reported large discrepancy between calculated static capacity and measured resistance at a certain time after pile installation.