Analysing Pairwise Logratios Revisited

Mathematical Geosciences - Even though the logratio methodology provides a range of both generic, mostly exploratory, and purpose-built coordinate representations of compositional data, simple...     

Sensitivity analysis of a Penman–Monteith type equation to estimate reference evapotranspiration in southern Spain

Sensitivity analysis is crucial in assessing the impact of climatic variables on reference evapotranspiration estimations. The sensitivity of the standardized ASCE–Penman–Monteith evapotranspiration equation for daily estimations to climatic variables has not yet been studied in Spain. Andalusia is located in southern Spain where almost 1 million ha are irrigated under quite different conditions; it has a high inter‐annual variability in rainfall. In this study, sensitivity analyses for this equation were carried out for temperature, relative humidity, solar radiation and wind speed data from 87 automatic weather stations, including coastal and inland locations, from 1999 to 2006. Topography and Mediterranean climate characterize the heterogeneous landscape and vegetation of this region. Simulated random and systematic errors have been added to meteorological data to obtain ET₀ deviations and sensitivity coefficients for different time periods. BIAS and SEE (standard error of estimate) have been used to evaluate the effect of both types of errors. The results showed a large degree of daily and seasonal variability, especially for temperature and relative humidity. In general, the effect on ET₀ values of introduced random errors was larger than that of systematic errors. ET₀ overestimations were produced using positive errors in temperature, solar radiation and wind speed data, while these errors in relative humidity resulted in ET₀ underestimations. The sensitivity of ET₀ to the same climatic variables showed significant differences among locations. The geographical distribution of sensitivity coefficients across this region was also studied. As an example, during spring months, ET₀ equation was more sensitive to temperature in stations located along the Guadalquivir Valley. Copyright © 2009 John Wiley & Sons, Ltd.     

Redescription of the rare species Podospongia loveni (Porifera) from the Cantabrian Sea

Podospongia [du Bocage, B., 1869. Eponges siliceuses nouvelles du Portugal et de l’Île Saint-Iago (Archipel de Cap-Vert). Jornal de Sciencias mathematicas, physicas e naturais 2, 159–162], which at present includes only five species, is a rare genus generally found in deeper waters down to 600 m depth from Natal coast in South Africa, to New Caledonia, the Central and North Atlantic and the Mediterranean Sea. Species of this genus are characterised by a choanosomal skeleton composed of tracts of megascleres radiating from a centrum and stipitate body. Microscleres are spinorhabds and aciculospinorhabds packed in a vertical arrangement in the ectosome and scattered throughout choanosome.As a result of two oceanographic projects (Ecomarg, date; Cocace, date) on the continental shelf of the Cantabrian Sea, ten stipitate sponge specimens were collected and assigned to Podospongia loveni [du Bocage, B., 1869. Eponges siliceuses nouvelles du Portugal et de l’Île Saint-Iago (Archipel de Cap-Vert). Jornal de Sciencias mathematicas, physicas e naturais 2, 159–162]. Since the holotype was destroyed [Kelly, M., Samaai, T., 2002. Family Podospongiidae de Laubenfels, 1936. In: Hooper, J.N.A., Soest, RW.M., (Eds.), Systema Porifera: A Guide to the Classification of Sponges, New York, pp. 694–702] and with the existence of several specimens from a close region, we hereby redescribe this species. scanning electron microscopy pictures of the spicules and skeletal architecture of P. loveni are for the first time provided.     

Numerical analysis of wave loads for coastal structure stability

The numerical model COBRAS-UC [Losada, I.J., Lara, J.L., Guanche,R., Gonzalez-Ondina, J.M. (2008). Numerical analysis of wave overtopping of rubble mound breakwaters. Coastal Engineering, Vol 55 (1), 47–62.] is used to carry out a two-dimensional analysis of wave induced loads on coastal structures. The model calculates pressure, forces and moments for two different cross-sections corresponding to a low-mound and a conventional rubble-mound breakwater with a crown-wall under regular and irregular incident wave conditions. Predicted results are compared with experimental information provided in Losada et al. [Losada, I.J., Lara, J.L., Guanche,R., Gonzalez-Ondina, J.M. (2008). Numerical analysis of wave overtopping of rubble mound breakwaters. Coastal Engineering, Vol 55 (1), 47–62.] and Lara et al. [Lara, J.L., Losada, I.J., Guanche, R. (2008). “Wave interaction with low mound breakwaters using a RANS model”. Ocean engineering (35), pp 1388–1400; doi:10.1016/j.oceaneng.2008.05.006.] on a 1:20 scale. Good agreement is found, and the differences between both typologies are explained in detail. Additionally, numerical results are also compared with several semi-empirical formulae recommended for design at both the 1:20 model scale and two prototype cross-sections. Results suggest that COBRAS-UC is able to provide realistic stability information that can be used to complete the approach based on currently existing methods and tools.     

The biogeographical role of Pinus forest on the Northern Spanish Meseta: a new Holocene sequence

The aim of this paper is to reconstruct the variation in the vegetation during the Holocene on the Northern Meseta through pollen analysis in order to determine the roles played by Pinus and Quercus in the vegetation dynamics. A new pollen sequence, Camporredondo, in the centre of the Duero River basin, Northern Meseta, Spain, is presented. It covers the period from ca 11,250 to 1630 cal yr BP. The Camporredondo sequence suggests that a forested landscape existed from the start of the Holocene with values of approximately 90% of arboreal pollen mainly derived from pine forests in the surroundings. Shortly after 8600 cal yr BP pine forests continued to dominate but the landscape became more open while stands of deciduous and evergreen Quercus developed. Around 4500 years ago, coinciding with the start of a period of less rainfall, the lacustrine areas in these territories began to silt up, favouring hydrophytic taxa such as Salix or Cyperaceae. A comparison with other Holocene pollen sequences from the central-eastern part of the Northern Meseta confirms the presence of pine forests in the whole region since the early Holocene. We discuss the variations of the general vegetation pattern in terms of the local or regional conditions at each site. Throughout the Holocene, Pinus forests dominated at least in the eastern half of the Duero River basin. The typical Holocene substitution of conifers by broadleaf species as recorded in other parts of the Iberian Peninsula and Europe, never takes place in the study area. The results of the present study suggest that the current view of the potential vegetation in the Spanish Northern Meseta should be reviewed.     

The combined inelastic neutron scattering and solid state DFT study of hydrogen atoms dynamics in a highly ordered kaolinite

The dynamics of the hydrogen atoms in the highly ordered kaolinite was studied by vibrational spectroscopy based on inelastic neutron scattering method with the focus on the spectral region of 100–1,250 cm⁻¹. The experimental spectrum was interpreted by means of the solid state density functional theory calculations covering both normal mode analysis and molecular dynamics going beyond the harmonic approximation. The Al–O–H bending modes were found to be spread over the large interval of 100–1,100 cm⁻¹, with the dominant contributions located between 800 and 1,100 cm^-1. The shapes of the individual hydrogen spectra depend on the strengths of the individual interlayer O–H···O hydrogen bonds involving the inner surface hydroxyl groups. The modes assigned to the in-plane movements of the respective hydrogen atoms are well-defined and always appear on the top of the intervals of energy transfer. In contrast, the modes generated by the out-of-plane movements are spread over large intervals of energies spanning down to the region of external (lattice) modes.     

Hydrogeochemistry of abandoned Pb sulphide mines: the mining district of La Carolina (southern Spain)

The impact of past mining activities on the quality of groundwater and surface water has been investigated in the mining district of La Carolina (southern Spain, province of Jaén), a region characterised by the presence of mineralisations of Pb–Ag, Cu and Fe sulphides and Ba sulphates. The chemistry of waters from flooded galleries, shafts and drainage adits has been compared with that of surface waters in the same area. Generally, waters present neutral pH, since carbonates neutralise the acidity produced by the oxidation of Fe-bearing sulphide minerals in the mine impacted water. Despite of this natural attenuation process, in most of the cases, the mine groundwater is of low quality and shows high dissolved SO₄ (up to 3.7 g/l), Fe and Mn contents (tens to hundreds mg/l), exceeding the limit established by the guidelines of the World Health Organization for drinking water. Generally, the surface waters are of the sulphate calcium–magnesium to magnesium types, with moderate mineralisation. Post-rebound mine waters caused degradation of receiving watercourses in which the Fe contents are usually high, with values close to 3 g/l, and the mineralisation is greater as the channels run down in the mining zone. During dry seasons a considerable increase of salts and metals dissolved in stream waters was found, due to the decreasing contributions by run-off in this semiarid region, whereas the abandoned mine discharges remained practically constant.     

Metalliferous sediments from the H.M.S. Challenger voyage (1872-1876)

The legendary cruise of H.M.S. Challenger (1872-1876) around the globe must always occupy an eminent place in the annals of oceanography, as being the first systematic attempt made on a global scale to explore the ocean. This expedition made fundamental discoveries in biology and geology which have not been surpassed by any later scientific cruise. Sediment with high content of metals (later called “metalliferous”) was among the enigmatic findings taken onboard. Although the nature of metalliferous sediments is well known today, the very first sampled sediments of this type have not been studied to date. Motivated by the historical value of Challenger’s metalliferous sediment collection we undertook an investigation addressing two questions: (1) the composition of sediments from seafloor for which we have very limited data; (2) Sr-Nd-Pb-Fe-Zn-isotope signature of these sediments collected before the substantial human impact on the ocean during the 20th century.The SE Pacific metalliferous sediments sampled by the Challenger’s explorers are of 2 types: (1) metalliferous oozes blanketing ridge crests and flanks down to the calcite compensation depth (CCD); and (2) stripped of CaCO₃ metalliferous sediments located beneath the CCD in the deeps near the mid-ocean ridges. The abiogenic part of these sediments is composed mainly of poorly-crystalline to X-ray amorphous Fe-Mn-oxyhydroxides, and an amorphous silicate phase. These sediments have geochemical features similar to those of all the other metalliferous sediments: very high Fe and Mn content (on abiogenic basis), very low Al/(Al + Fe + Mn), and high content (on abiogenic basis) of As, Ba, Be, Bi, Cd, Co, Cu, Mo, Ni, Pb, Sb, Th, Tl, U, V, W, Y, Zn and Zr. Their REE distribution patterns are similar to that of deep seawater and show weak signs of hydrothermal imprint (weak positive or no Eu anomaly).Seawater and/or terrigenous input from South America control the Sr-Nd-Pb-isotope signature of the Challenger metalliferous sediments and have almost completely obliterated any original MORB-derived hydrothermal signal. Zn isotopes are mainly contributed from seawater although other Zn sources (hydrothermal fluid and detrital aluminosilicates, barite and volcanic glass) are necessary to fully explain Zn-isotope ratios. Fe isotopes indicate relatively slow Fe²⁺ to Fe³⁺ oxidation in the non-buoyant plume, thus producing relatively lighter Fe-isotope signature of the FeOOH particles that formed the studied metalliferous sediments.     

Climate modulation of fish populations: the role of the Western Mediterranean Oscillation (WeMO) in sardine (Sardina pilchardus) and anchovy (Engraulis encrasicolus) production in the north-western Mediterranean

This study investigates the connections between climate fluctuations and sardine and anchovy production in the NW Mediterranean, taking the Western Mediterranean Oscillation index (WeMOi) as an indicator of climate variability. The basic working hypothesis is that sardine and anchovy productivity is influenced by the WeMOi, a proxy for the local environmental conditions such as sea surface temperature (SST) and river runoff. Sardine and anchovy landings (1974–2009) in the Catalan Coast and landings per unit of effort (LPUE) were used as proxy for recruitment. The results demonstrated a clear link between climate fluctuations and sardine and anchovy production. Positive WeMOi values were significantly correlated with low SST, high river runoff and high LPUE, that is, with better-than-average recruitment of sardine and anchovy. Conversely, negative WeMOi values were associated with high SST, low river runoff and low LPUE. During the negative WeMOi phases (such as that at the end of the analyzed period), environmental conditions are unfavourable for the overall biological productivity in the NW Mediterranean and would decrease the survival, growth, condition and reproduction of sardine and anchovy during their life cycle. Despite the evidences on the appropriateness of the NAOi as an indicator of the climate in Europe and its impact on some biological variables, we suggest that using a regional index, such as the WeMOi, can provide a more accurate representation of the environmental conditions affecting small pelagic fish production in the NW Mediterranean.